a.Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Zhejiang University, Hangzhou 310027, China
b.Shanghai Aerospace System Engineering Institute, Shanghai 201110, China
Yi-hu Song(宋义虎), E-mail:s_yh0411@zju.edu.cn
收稿:2017-04-13,
修回:2017-5-16,
录用:2017-5-27,
纸质出版:2017-11-05
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Yi-hu Song, Ling-bin Zeng, Qiang Zheng. Understanding the Reinforcement and Dissipation of Natural Rubber Compounds Filled with Hybrid Filler Composed of Carbon Black and Silica[J]. Chinese Journal of Polymer Science, 2017,35(11):1436-1446.
Yi-hu Song, Ling-bin Zeng, Qiang Zheng. Understanding the Reinforcement and Dissipation of Natural Rubber Compounds Filled with Hybrid Filler Composed of Carbon Black and Silica[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1436-1446.
Yi-hu Song, Ling-bin Zeng, Qiang Zheng. Understanding the Reinforcement and Dissipation of Natural Rubber Compounds Filled with Hybrid Filler Composed of Carbon Black and Silica[J]. Chinese Journal of Polymer Science, 2017,35(11):1436-1446. DOI: 10.1007/s10118-017-1987-5.
Yi-hu Song, Ling-bin Zeng, Qiang Zheng. Understanding the Reinforcement and Dissipation of Natural Rubber Compounds Filled with Hybrid Filler Composed of Carbon Black and Silica[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1436-1446. DOI: 10.1007/s10118-017-1987-5.
The performance of reinforced rubber compounds depends on the filler composition while the reinforcement and dissipation mechanisms still remain unclear. Herein linear and nonlinear dynamic rheological responses of carbon black/silica hybrid filler filling nature rubber compounds are investigated. The rheological contributions of dynamically retarded bulk phase and filler network are revealed to be crucial at high and low frequencies
respectively
and the bulk phase is shown to be of vital importance for the occurrence of nonlinear Payne effect at mediate frequencies. A framework for simultaneously solving reinforcement and dissipation varying with filler composition and content is suggested
providing a new perspective in understanding the filling effect for manufacturing high-performance rubber materials.
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