Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning

Jing Nie; Zhi-liang Wang; Jie-fu Li; Ying Gong; Jia-xing Sun; Shu-guang Yang

doi:10.1007/s10118-017-1984-8

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Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning

Papers | Updated：2021-02-18

- Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning
- Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning
- Chinese Journal of Polymer Science 2017年35卷第8期页码：1001-1008
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  Shu-guang Yang (杨曙光), E-mail: shgyang@dhu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51373032);Science and Technology Commission of Shanghai Municipality(16JC1400700);Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1984-8.
- DOI：10.1007/s10118-017-1984-8
  中图分类号：
- 收稿：2016-12-31，
  
  修回：2017-3-23，
  
  录用：2017-3-27，
  
  纸质出版：2017-08
- Accepted：
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Jing Nie, Zhi-liang Wang, Jie-fu Li, 等. Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning[J]. Chinese Journal of Polymer Science, 2017,35(8):1001-1008.

Jing Nie, Zhi-liang Wang, Jie-fu Li, et al. Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning[J]. Chinese Journal of Polymer Science, 2017, 35(8): 1001-1008.
Jing Nie, Zhi-liang Wang, Jie-fu Li, 等. Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning[J]. Chinese Journal of Polymer Science, 2017,35(8):1001-1008. DOI： 10.1007/s10118-017-1984-8.

Jing Nie, Zhi-liang Wang, Jie-fu Li, et al. Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning[J]. Chinese Journal of Polymer Science, 2017, 35(8): 1001-1008. DOI： 10.1007/s10118-017-1984-8.

摘要

Abstract

Core-shell nanofibers were prepared by coaxial electrospinning technology

with poly(ethylene oxide) (PEO) as the core while poly(acrylic acid) (PAA) as the shell. PEO and PAA can form polymer complexes based on hydrogen bonding. In order to avoid forming strong hydrogen bonding complexes at nozzle and blocking spinning process

a polar aprotic solvent

-dimethylformamide (DMF)

was selected to dissolve PEO and PAA respectively. SEM

TEM and DSC were utilized to characterize the morphology and structure of PEO-PAA core-shell nanofibers. FTIR spectra demonstrated that hydrogen bonding was formed at the core-shell interface. In addition

the PAA shell of the nanofibers can be cross-linked by ethylene glycol (EG) under heat treatment

which increases the stability and extends the potential applications in aqueous environment.

关键词

Keywords

references

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