Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties

Fang-Lan Guan; Fei An; Jing Yang; Xiaofeng Li; Xing-Hua Li; Zhong-Zhen Yu

doi:10.1007/s10118-017-1972-z

Your Location：

Home >

Browse articles >

Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties

Papers | Updated：2021-02-18

- Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties
- Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties
- Chinese Journal of Polymer Science 2017年35卷第11期页码：1381-1390
- Affiliations：
  
  a.Beijing Key Laboratory of Advanced Functional Polymer Composites, Beijing University of Chemical Technology, Beijing 100029, China
  b.Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  Xiaofeng Li(李晓锋), E-mail:xfli@mail.buct.edu.cn
  Zhong-Zhen Yu(于中振), E-mail:yuzz@mail.buct.edu.cn
- Funds：
  
  the National Key Research and Development Program of China(016YFC0801302);the National Natural Science Foundation of China(51403016);the National Natural Science Foundation of China(51533001);the National Natural Science Foundation of China(51521062);Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1972-z.
- DOI：10.1007/s10118-017-1972-z
  中图分类号：
- 收稿：2017-03-21，
  
  修回：2017-5-3，
  
  录用：2017-5-8，
  
  纸质出版：2017-11-05
- Accepted：
Scan QR Code
Fang-Lan Guan, Fei An, Jing Yang, 等. Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties[J]. Chinese Journal of Polymer Science, 2017,35(11):1381-1390.

Fang-Lan Guan, Fei An, Jing Yang, et al. Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1381-1390.
Fang-Lan Guan, Fei An, Jing Yang, 等. Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties[J]. Chinese Journal of Polymer Science, 2017,35(11):1381-1390. DOI： 10.1007/s10118-017-1972-z.

Fang-Lan Guan, Fei An, Jing Yang, et al. Fiber-reinforced Three-dimensional Graphene Aerogels for Electrically Conductive Epoxy Composites with Enhanced Mechanical Properties[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1381-1390. DOI： 10.1007/s10118-017-1972-z.

摘要

Abstract

To enhance the mechanical properties of three-dimensional graphene aerogels with aramid fibers

graphene/organic fiber aerogels are prepared by chemical reduction of graphene oxide in the presence of organic fibers of poly(

-phenylene terephthalamide) (PPTA) and followed by freeze-drying. Thermal annealing of the composite aerogels at 1300℃ is adopted not only to restore the conductivity of the reduced graphene oxide component but also to convert the insulating PPTA organic fibers to conductive carbon fibers by the carbonization. The resultant graphene/carbon fiber aerogels (GCFAs) exhibit high electrical conductivities and enhanced compressive properties

which are highly efficient in improving both mechanical and electrical performances of epoxy composites. Compared to those of neat epoxy

the compressive modulus

compressive strength and energy absorption of the electrically conductive GCFA/epoxy composite are significantly increased by 60%

59% and 131%

respectively.

关键词

Keywords

references

J. Yang , E. Zhang , X. Li , Y. Yu , J. Qu , Z.Z. Yu . ACS Appl. Mater. Interfaces , 2016 . 8 ( 3 ): 2297 DOI: 10.1021/acsami.5b11337 http://doi.org/10.1021/acsami.5b11337 .

Z.Y. Sui , Y. Cui , J.H. Zhu , B.H. Han . ACS Appl. Mater. Interfaces , 2013 . 5 ( 18 ): 9172 DOI: 10.1021/am402661t http://doi.org/10.1021/am402661t .

Y.J. Wan , W.H. Yang , S.H. Yu , R. Sun , C.P. Wong , W.H. Liao . Compos. Sci. Technol. , 2016 . 122 27 DOI: 10.1016/j.compscitech.2015.11.005 http://doi.org/10.1016/j.compscitech.2015.11.005 .

F. Lin , Z. Zhu , X. Zhou , W. Qiu , C. Niu , J. Hu , K. Dahal , Y. Wang , Z. Zhao , Z. Ren , D. Litvinov , Z. Liu , Z.M. Wang , J. Bao . Adv. Mater. , 2017 . 29 ( 1 ): 1604453 DOI: 10.1002/adma.201604453 http://doi.org/10.1002/adma.201604453 .

G. Tang , Z.G. Jiang , X. Li , H.B. Zhang , Z.Z. Yu . Chinese J. Polym. Sci. , 2014 . 32 ( 8 ): 975 DOI: 10.1007/s10118-014-1488-8 http://doi.org/10.1007/s10118-014-1488-8 .

Y.J. Huang , Y.W. Qin , Y. Zhou , H. Niu , Z.Z. Yu , J.Y. Dong . Chem. Mater. , 2010 . 22 ( 13 ): 4096 DOI: 10.1021/cm100998e http://doi.org/10.1021/cm100998e .

W. Yan , L. Wang , C. Chen , D. Zhang , A.J. Li , Z. Yao , L.Y. Shi . Electrochim. Acta , 2016 . 188 230 DOI: 10.1016/j.electacta.2015.11.146 http://doi.org/10.1016/j.electacta.2015.11.146 .

P. Zhang , L. Lv , Z. Cheng , Y. Liang , Q. Zhou , Y. Zhao , L. Qu . Chem. Asian J. , 2016 . 11 ( 7 ): 1071 DOI: 10.1002/asia.201600038 http://doi.org/10.1002/asia.201600038 .

Y. Shen , T. Jing , W. Ren , J. Zhang , Z.G. Jiang , Z.Z. Yu , A. Dasari . Compos. Sci. Technol. , 2012 . 72 ( 12 ): 1430 DOI: 10.1016/j.compscitech.2012.05.018 http://doi.org/10.1016/j.compscitech.2012.05.018 .

H.L. Ma , H.B. Zhang , Q.H. Hu , W.J. Li , Z.G. Jiang , Z.Z. Yu , A. Dasari . ACS Appl. Mater. Interfaces , 2012 . 4 ( 4 ): 1948 DOI: 10.1021/am201654b http://doi.org/10.1021/am201654b .

X. Lin , X. Shen , Q. Zheng , N. Yousefi , L. Ye , Y.W. Mai , J.K. Kim . ACS Nano , 2012 . 6 ( 12 ): 10708 DOI: 10.1021/nn303904z http://doi.org/10.1021/nn303904z .

H. Kim , A.A. Abdala , C.W. Macosko . Macromolecules , 2010 . 43 ( 16 ): 6515 DOI: 10.1021/ma100572e http://doi.org/10.1021/ma100572e .

P. Lv , X.W. Tan , K.H. Yu , R.L. Zheng , J.J. Zheng , W. Wei . Carbon , 2016 . 99 222 DOI: 10.1016/j.carbon.2015.12.026 http://doi.org/10.1016/j.carbon.2015.12.026 .

T. Liu , M. Huang , X. Li , C. Wang , C.X. Gui , Z.Z. Yu . Carbon , 2016 . 100 456 DOI: 10.1016/j.carbon.2016.01.038 http://doi.org/10.1016/j.carbon.2016.01.038 .

S. Liao , T. Zhai , H. Xia . J. Mater. Chem. A , 2016 . 4 ( 3 ): 1068 DOI: 10.1039/C5TA09540A http://doi.org/10.1039/C5TA09540A .

X. Li , T. Zhao , K. Wang , Y. Yang , J. Wei , F. Kang , D. Wu , H. Zhu . Langmuir , 2011 . 27 ( 19 ): 12164 DOI: 10.1021/la202380g http://doi.org/10.1021/la202380g .

Y.B. Luo , B.F. Yuan , Q.W. Yu , Y.Q. Feng . J. Chromatogr. A , 2012 . 1268 9 DOI: 10.1016/j.chroma.2012.10.035 http://doi.org/10.1016/j.chroma.2012.10.035 .

T. Huang , B. Zheng , L. Kou , K. Gopalsamy , Z. Xu , C. Gao , Y. Meng , Z. Wei . RSC Adv. , 2013 . 3 ( 46 ): 23957 DOI: 10.1039/c3ra44935a http://doi.org/10.1039/c3ra44935a .

H. Cheng , Y. Hu , F. Zhao , Z. Dong , Y. Wang , N. Chen , Z. Zhang , L. Qu . Adv. Mater. , 2014 . 26 ( 18 ): 2909 DOI: 10.1002/adma.v26.18 http://doi.org/10.1002/adma.v26.18 .

Z. Chen , T. Ming , M.M. Goulamaly , H. Yao , D. Nezich , M. Hempel , M. Hofmann , J. Kong . Adv. Funct. Mater. , 2016 . 26 ( 28 ): 5061 DOI: 10.1002/adfm.v26.28 http://doi.org/10.1002/adfm.v26.28 .

J.Y. Jeong , K.M. Lee , R. Shrestha , K. Horne , S. Das , W. Choi , M. Kim , T.Y. Choi . Mater. Res. Express , 2016 . 3 ( 5 ): 055004 DOI: 10.1088/2053-1591/3/5/055004 http://doi.org/10.1088/2053-1591/3/5/055004 .

Z. Du , R. Dou , M. Zu , X. Liu , W. Yin , Y. Zhao , J. Chen , L. Yan , Z. Gu . Biomater. Sci. , 2016 . 4 ( 6 ): 938 DOI: 10.1039/C6BM00074F http://doi.org/10.1039/C6BM00074F .

H. Cheng , M. Ye , F. Zhao , C. Hu , Y. Zhao , Y. Liang , N. Chen , S. Chen , L. Jiang , L. Qu . Adv. Mater. , 2016 . 28 ( 17 ): 3305 DOI: 10.1002/adma.201505431 http://doi.org/10.1002/adma.201505431 .

K. Hu , X. Xie , T. Szkopek , M. Cerruti . Chem. Mater. , 2016 . 28 ( 6 ): 1756 DOI: 10.1021/acs.chemmater.5b04713 http://doi.org/10.1021/acs.chemmater.5b04713 .

S.L. Marasso , P. Rivolo , R. Giardi , D. Mombello , A. Gigot , M. Serrapede , S. Benetto , A. Enrico , M. Cocuzza , E. Tresso . Mater. Res. Express , 2016 . 3 ( 6 ): 065001 DOI: 10.1088/2053-1591/3/6/065001 http://doi.org/10.1088/2053-1591/3/6/065001 .

J. Zhang , Y. Cao , J. Feng , P. Wu . J. Phys. Chem. C , 2012 . 116 ( 14 ): 8063 DOI: 10.1021/jp2109237 http://doi.org/10.1021/jp2109237 .

H. Li , L. Liu , F. Yang . J. Mater. Chem. A , 2013 . 1 ( 10 ): 3446 DOI: 10.1039/c3ta00166k http://doi.org/10.1039/c3ta00166k .

C. Li , G. Shi . Nanoscale , 2012 . 4 ( 18 ): 5549 DOI: 10.1039/c2nr31467c http://doi.org/10.1039/c2nr31467c .

X.H. Liu , C.Z. Guan , D. Wang , L.J. Wan . Adv. Mater. , 2014 . 26 ( 40 ): 6912 DOI: 10.1002/adma.v26.40 http://doi.org/10.1002/adma.v26.40 .

Z. Li , X. Cheng , S. He , X. Shi , L. Gong , H. Zhang . Compos. Part A Appl. Sci. Manuf. , 2016 . 84 316 DOI: 10.1016/j.compositesa.2016.02.014 http://doi.org/10.1016/j.compositesa.2016.02.014 .

W. Chen , S. Li , C. Chen , L. Yan . Adv. Mater. , 2011 . 23 ( 47 ): 5679 DOI: 10.1002/adma.v23.47 http://doi.org/10.1002/adma.v23.47 .

Z. Wang , X. Shen , M. Akbari Garakani , X. Lin , Y. Wu , X. Liu , X. Sun , J.K. Kim . ACS Appl. Mater. Interfaces , 2015 . 7 ( 9 ): 5538 DOI: 10.1021/acsami.5b00146 http://doi.org/10.1021/acsami.5b00146 .

Z. Li , L. Gong , X. Cheng , S. He , C. Li , H. Zhang . Mater. Design , 2016 . 99 349 DOI: 10.1016/j.matdes.2016.03.063 http://doi.org/10.1016/j.matdes.2016.03.063 .

Z.G. Xie , H.T. Niu , T. Lin . RSC Adv. , 2015 . 5 ( 20 ): 15147 DOI: 10.1039/C4RA16247A http://doi.org/10.1039/C4RA16247A .

F. Agend , N. Naderi , R. Fareghi-Alamdari1 . J. Appl. Polym. Sci. , 2007 . 107 ( 1 ): 255 http://onlinelibrary.wiley.com/doi/10.1002/app.26476/full http://onlinelibrary.wiley.com/doi/10.1002/app.26476/full , .

M.A. Worsley , P.J. Pauzauskie , T.Y. Olson , J. Biener , Jr J.H. Satcher , T.F. Baumann . J. Am. Chem. Soc. , 2010 . 132 ( 40 ): 14067 DOI: 10.1021/ja1072299 http://doi.org/10.1021/ja1072299 .

D.C. Marcano , D.V. Kosynkin , J.M. Berlin , A. Sinitskii , Z. Sun , A. Slesarev , L.B. Alemany , W. Lu , J.M. Tour . ACS Nano , 2010 . 4 ( 8 ): 4806 DOI: 10.1021/nn1006368 http://doi.org/10.1021/nn1006368 .

G. Tang , Z.G. Jiang , X. Li , H.B. Zhang , A. Dasari , Z.Z. Yu . Carbon , 2014 . 77 592 DOI: 10.1016/j.carbon.2014.05.063 http://doi.org/10.1016/j.carbon.2014.05.063 .

Y. Xu , Q. Wu , Y. Sun , H. Bai , G. Shi . ACS Nano , 2010 . 4 ( 12 ): 7358 DOI: 10.1021/nn1027104 http://doi.org/10.1021/nn1027104 .

A. Castro-Muñiz , F. Suárez-García , A. Martínez-Alonso , J.M.D. Tascón . J. Colloid Interf. Sci. , 2011 . 361 ( 1 ): 307 DOI: 10.1016/j.jcis.2011.05.064 http://doi.org/10.1016/j.jcis.2011.05.064 .

I. Karacan , L. Erzurumluoğlu . Fiber Polym. , 2015 . 16 ( 5 ): 961 DOI: 10.1007/s12221-015-0961-5 http://doi.org/10.1007/s12221-015-0961-5 .

F. Suárez-Garcıa , A. Martınez-Alonso , J.M.D. Tascón . Carbon , 2004 . 42 ( 8 ): 1419 http://www.sciencedirect.com/science/article/pii/S0008622303005669 http://www.sciencedirect.com/science/article/pii/S0008622303005669 , .

S. Pei , J. Zhao , J. Du , W. Ren , H.M. Cheng . Carbon , 2010 . 48 ( 15 ): 4466 DOI: 10.1016/j.carbon.2010.08.006 http://doi.org/10.1016/j.carbon.2010.08.006 .

S. Pei , H.M. Cheng . Carbon , 2012 . 50 ( 9 ): 3210 DOI: 10.1016/j.carbon.2011.11.010 http://doi.org/10.1016/j.carbon.2011.11.010 .

M.G. Northolt , J.J. van Aartsen . J. Polym. Sci. C, Polym. Lett. , 1973 . 11 ( 5 ): 333 DOI: 10.1002/pol.1973.130110508 http://doi.org/10.1002/pol.1973.130110508 .

D.T. Pham , T.H. Lee , D.H. Luong , F. Yao , A. Ghosh , V.T. Le , T.H. Kim , B. Li , J. Chang , Y.H. Lee . ACS Nano , 2015 . 9 ( 2 ): 2018 DOI: 10.1021/nn507079x http://doi.org/10.1021/nn507079x .

Y. Bin , K. Oishi , A. Koganemaru , D. Zhu , M. Matsuo . Carbon , 2005 . 43 ( 8 ): 1617 DOI: 10.1016/j.carbon.2005.01.037 http://doi.org/10.1016/j.carbon.2005.01.037 .

X. Zhang , Z. Sui , B. Xu , S. Yue , Y. Luo , W. Zhan , B. Liu . J. Mater. Chem. , 2011 . 21 ( 18 ): 6494 DOI: 10.1039/c1jm10239g http://doi.org/10.1039/c1jm10239g .

L. Qiu , J.Z. Liu , S.L.Y. Chang , Y. Wu , D. Li . Nat. Commun. , 2012 . 3 1241 DOI: 10.1038/ncomms2251 http://doi.org/10.1038/ncomms2251 .

Y. Xu , K. Sheng , C. Li , G. Shi . ACS Nano , 2010 . 4 ( 7 ): 4324 DOI: 10.1021/nn101187z http://doi.org/10.1021/nn101187z .

Z.S. Wu , W. Ren , L. Gao , J. Zhao , Z. Chen , B. Liu , D. Tang , B. Yu , C. Jiang , H.M. Cheng . ACS Nano , 2009 . 3 ( 2 ): 411 DOI: 10.1021/nn900020u http://doi.org/10.1021/nn900020u .

C. Vallés , J.D. Núñez , A.M. Benito , W.K. Maser . Carbon , 2012 . 50 ( 3 ): 835 DOI: 10.1016/j.carbon.2011.09.042 http://doi.org/10.1016/j.carbon.2011.09.042 .

N. Yousefi , X. Sun , X. Lin , X. Shen , J. Jia , B. Zhang , B. Tang , M. Chan , J.K. Kim . Adv. Mater. , 2014 . 26 ( 31 ): 5480 DOI: 10.1002/adma.201305293 http://doi.org/10.1002/adma.201305293 .

J. Jia , X. Sun , X. Lin , X. Shen , Y.W. Mai , J.K. Kim . ACS Nano , 2014 . 8 ( 6 ): 5774 DOI: 10.1021/nn500590g http://doi.org/10.1021/nn500590g .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)

Advancing the Thin-film Mechanics of Conjugated Polymers: Characterization, Modulation, and Innovation

Enhanced Mechanical Properties and Prolonged Recovery Onset Period of Timed Shape Memory Hydrogels via Hydrophobic Interaction

A Phosphorus/Nitrogen-containing Phosphaphenanthrene Derivative as Flame Retardant for Poly(lactic acid)