Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties

Xiao-ying Liu; Ming Zhong; Fu-kuan Shi; Hao Xu; Xu-ming Xie

doi:10.1007/s10118-017-1971-0

Your Location：

Home >

Browse articles >

Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties

Papers | Updated：2021-02-18

- Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties
- Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties
- Chinese Journal of Polymer Science 2017年35卷第10期页码：1253-1267
- Affiliations：
  
  Laboratory of Advanced Materials (Ministry of Education), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Xu-ming Xie (谢续明), E-mail:xxm-dce@mail.tsinghua.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51633003);the National Natural Science Foundation of China(21474058);State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University(LK1404);Tsinghua University Scientific Research Project(2014Z22069);State Key Laboratory of Organic-Inorganic Composites,Beijing University of Chemical Technology(OIC-201601006);Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1971-0.
- DOI：10.1007/s10118-017-1971-0
  中图分类号：
- 收稿：2017-04-09，
  
  修回：2017-5-5，
  
  录用：2017-5-8，
  
  纸质出版：2017-10-05
- Accepted：
Scan QR Code
Xiao-ying Liu, Ming Zhong, Fu-kuan Shi, 等. Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties[J]. Chinese Journal of Polymer Science, 2017,35(10):1253-1267.

Xiao-ying Liu, Ming Zhong, Fu-kuan Shi, et al. Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1253-1267.
Xiao-ying Liu, Ming Zhong, Fu-kuan Shi, 等. Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties[J]. Chinese Journal of Polymer Science, 2017,35(10):1253-1267. DOI： 10.1007/s10118-017-1971-0.

Xiao-ying Liu, Ming Zhong, Fu-kuan Shi, et al. Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1253-1267. DOI： 10.1007/s10118-017-1971-0.

摘要

Abstract

Multi-bond network (MBN) which contains a single network with hierarchical cross-links is a suggested way to fabricate robust hydrogels. In order to reveal the roles of different cross-links with hierarchical bond energy in the MBN

here we fabricate poly(acrylic acid) physical hydrogels with dual bond network composed of ionic cross-links between carboxyl-Fe

interactions and hydrogen bonds

and compare these dually cross-linked hydrogels with singly and ternarily cross-linked hydrogels. Simple models are employed to predict the tensile property

and the results confirm that the multi-bond network with hierarchical distribution in the bond energy of cross-links endows hydrogel with effective energy-dissipating mechanism. Moreover

the dually cross-linked MBN gels exhibit excellent mechanical properties (tensile strength up to 500 kPa

elongation at break~2400%) and complete self-healing after being kept at 50℃ for 48 h. The factors on promoting self-healing are deeply explored and the dynamic multi-bonds are regarded to trigger the self-healing along with the mutual diffusion of long polymer chains and ferric ions.

关键词

Keywords

references

T. Vermonden , R. Censi , W.E. Hennink . Chem. Rev. , 2012 . 112 ( 5 ): 2853 DOI: 10.1021/cr200157d http://doi.org/10.1021/cr200157d .

J.H. Collier . Soft Matter , 2008 . 4 ( 12 ): 2310 DOI: 10.1039/b805563g http://doi.org/10.1039/b805563g .

P.Y.W. Dankers , M.C. Harmsen , L.A. Brouwer , M.J.A. van Luyn , E.W. Meijer . Nat. Mater. , 2005 . 4 ( 7 ): 568 DOI: 10.1038/nmat1418 http://doi.org/10.1038/nmat1418 .

K.Y. Lee , D.J. Mooney . Chem. Rev. , 2001 . 101 ( 7 ): 1869 DOI: 10.1021/cr000108x http://doi.org/10.1021/cr000108x .

D. Buenger , F. Topuz , J. Groll . Prog. Polym. Sci. , 2012 . 37 ( 12 ): 1678 DOI: 10.1016/j.progpolymsci.2012.09.001 http://doi.org/10.1016/j.progpolymsci.2012.09.001 .

D. Liang , A.K. Agarwal , D.J. Beebe , J. Hongrui . Nature , 2006 . 442 ( 7102 ): 551 DOI: 10.1038/nature05024 http://doi.org/10.1038/nature05024 .

G. Erdodi , J.P. Kennedy . Prog. Polym. Sci. , 2006 . 31 ( 1 ): 1 DOI: 10.1016/j.progpolymsci.2005.11.001 http://doi.org/10.1016/j.progpolymsci.2005.11.001 .

T. Sakai , T. Matsunaga , Y. Yamamoto , C. Ito , R. Yoshida , S. Suzuki , N. Sasaki , M. Shibayama , U. Chung . Macromolecules , 2008 . 41 ( 14 ): 5379 DOI: 10.1021/ma800476x http://doi.org/10.1021/ma800476x .

Y. Okumura , K. Ito . Adv. Mater. , 2001 . 13 ( 7 ): 485 DOI: 10.1002/(ISSN)1521-4095 http://doi.org/10.1002/(ISSN)1521-4095 .

H.J. Naghash , O. Okay . J. Appl. Polym. Sci. , 1996 . 60 ( 7 ): 971 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

J.P. Gong . Soft Matter , 2010 . 6 ( 12 ): 2583 DOI: 10.1039/b924290b http://doi.org/10.1039/b924290b .

M. Malkoch , R. Vestberg , N. Gupta , L. Mespouille , P. Dubois , A.F. Mason , J.L. Hedrick , Q. Liao , C.W. Frank , K. Kingsbury , C.J. Hawker . Chem. Commun. , 2006 . ( 26 ): 2774 DOI: 10.1039/b603438a http://doi.org/10.1039/b603438a .

K. Ito . Polym. J. , 2007 . 39 ( 6 ): 489 DOI: 10.1295/polymj.PJ2006239 http://doi.org/10.1295/polymj.PJ2006239 .

J.P. Gong , Y. Katsuyama , T. Kurokawa , Y. Osada . Adv. Mater. , 2003 . 15 ( 14 ): 1155 DOI: 10.1002/adma.200304907 http://doi.org/10.1002/adma.200304907 .

K. Haraguchi , T. Takehisa , S. Fan . Macromolecules , 2002 . 35 ( 27 ): 10162 DOI: 10.1021/ma021301r http://doi.org/10.1021/ma021301r .

J. Yang , X.P. Wang , X.M. Xie . Soft Matter , 2012 . 8 ( 4 ): 1058 DOI: 10.1039/C1SM06647A http://doi.org/10.1039/C1SM06647A .

J.Q. Liu , C.F. Chen , C.C. He , J. Zhao , X.J. Yang , H.L. Wang . ACS Nano , 2012 . 6 ( 9 ): 8194 DOI: 10.1021/nn302874v http://doi.org/10.1021/nn302874v .

F.K. Shi , X.P. Wang , R.H. Guo , M. Zhong , X.M. Xie . J. Mater. Chem. B , 2015 . 3 ( 7 ): 1187 DOI: 10.1039/C4TB01654H http://doi.org/10.1039/C4TB01654H .

M. Zhong , X.Y. Liu , F.K. Shi , L.Q. Zhang , X.P. Wang , A.G. Cheetham , H.G. Cui , X.M. Xie . Soft Matter , 2015 . 11 ( 21 ): 4235 DOI: 10.1039/C5SM00493D http://doi.org/10.1039/C5SM00493D .

D.C. Tuncaboylu , A. Argun , M. Sahin , M. Sari , O. Okay . Polymer , 2012 . 53 ( 24 ): 5513 DOI: 10.1016/j.polymer.2012.10.015 http://doi.org/10.1016/j.polymer.2012.10.015 .

T. Huang , H.G. Xu , K.X. Jiao , L.P. Zhu , H.R. Brown , H.L. Wang . Adv. Mater. , 2007 . 19 ( 12 ): 1622 DOI: 10.1002/(ISSN)1521-4095 http://doi.org/10.1002/(ISSN)1521-4095 .

J. Sun , X. Zhao , W.R.K. Illeperuma , O. Chaudhuri , K.H. Oh , D.J. Mooney , J.J. Vlassak , Z. Suo . Nature , 2012 . 489 ( 7414 ): 133 DOI: 10.1038/nature11409 http://doi.org/10.1038/nature11409 .

M. Zhong , F.K. Shi , Y.T. Liu , X.Y. Liu , X.M. Xie . Chinese Chem. Lett. , 2016 . 27 ( 3 ): 312 DOI: 10.1016/j.cclet.2015.12.020 http://doi.org/10.1016/j.cclet.2015.12.020 .

F.K. Shi , M. Zhong , L.Q. Zhang , X.Y. Liu , X.M. Xie . J. Mater. Chem. B , 2016 . 4 ( 37 ): 6221 DOI: 10.1039/C6TB01606E http://doi.org/10.1039/C6TB01606E .

L.Q. Zhang , L.W. Chen , M. Zhong , F.K. Shi , X.Y. Liu , X.M. Xie . Chinese J. Polym. Sci. , 2016 . 34 ( 10 ): 1261 DOI: 10.1007/s10118-016-1848-7 http://doi.org/10.1007/s10118-016-1848-7 .

F.K. Shi , M. Zhong , L.Q. Zhang , X.Y. Liu , X.M. Xie . Acta Polymerica Sinica (in Chinese) , 2017 . ( 3 ): 491 http://pubs.rsc.org/en/content/articlepdf/2016/tb/c6tb01606e http://pubs.rsc.org/en/content/articlepdf/2016/tb/c6tb01606e , .

M. Zhong , Y.T. Liu , X.M. Xie . J. Mater. Chem. B , 2015 . 3 ( 19 ): 4001 DOI: 10.1039/C5TB00075K http://doi.org/10.1039/C5TB00075K .

M. Zhong , Y.T. Liu , X.Y. Liu , F.K. Shi , L.Q. Zhang , M. Zhu , X.M. Xie . Soft Matter , 2016 . 12 ( 24 ): 5420 DOI: 10.1039/C6SM00242K http://doi.org/10.1039/C6SM00242K .

D.L. Taylor , M.I.H. Panhuis . Adv. Mater. , 2016 . 28 ( 41 ): 9060 DOI: 10.1002/adma.201601613 http://doi.org/10.1002/adma.201601613 .

A. Phadke , C. Zhang , B. Arman , C. Hsu , R.A. Mashelkar , A.K. Lele , M.J. Tauber , G. Arya , S. Varghese . Proc. Natl. Acad. Sci. , 2012 . 109 ( 12 ): 4383 DOI: 10.1073/pnas.1201122109 http://doi.org/10.1073/pnas.1201122109 .

X.Y. Dai , Y.Y. Zhang , L.N. Gao , T. Bai , W. Wang , Y.L. Cui , W.G. Liu . Adv. Mater. , 2015 . 27 ( 23 ): 3566 DOI: 10.1002/adma.v27.23 http://doi.org/10.1002/adma.v27.23 .

D.C. Tuncaboylu , M. Sahin , A. Argun , W. Oppermann , O. Okay . Macromolecules , 2012 . 45 ( 4 ): 1991 DOI: 10.1021/ma202672y http://doi.org/10.1021/ma202672y .

K. Haraguchi , K. Uyama , H. Tanimoto . Macromol. Rapid Commun. , 2011 . 32 ( 16 ): 1253 DOI: 10.1002/marc.v32.16 http://doi.org/10.1002/marc.v32.16 .

G.R. Gao , G.L. Du , Y.N. Sun , J. Fu . ACS Appl. Mater. Interfaces , 2015 . 7 ( 8 ): 5029 DOI: 10.1021/acsami.5b00704 http://doi.org/10.1021/acsami.5b00704 .

J.Q. Liu , G.S. Song , C.C. He , H.L. Wang . Macromol. Rapid Commun. , 2013 . 34 ( 12 ): 1002 DOI: 10.1002/marc.v34.12 http://doi.org/10.1002/marc.v34.12 .

H.J. Zhang , H.S. Xia , Y. Zhao . ACS Macro Lett. , 2012 . 1 ( 11 ): 1233 DOI: 10.1021/mz300451r http://doi.org/10.1021/mz300451r .

P. Bera , S.K. Saha . Polymer , 1998 . 39 ( 6 ): 1461 http://www.sciencedirect.com/science/article/pii/S0032386197003595 http://www.sciencedirect.com/science/article/pii/S0032386197003595 , .

S. Yoshizawa , Z. Takehara , Z. Ogumi , C. Nagai . J. Appl. Electrochem. , 1976 . 6 ( 2 ): 147 DOI: 10.1007/BF00615380 http://doi.org/10.1007/BF00615380 .

Z. Wei , J. He , T. Liang , H. Oh , J. Athas , Z. Tong , C. Wang , Z. Nie . Polym. Chem. , 2013 . 4 ( 17 ): 4601 DOI: 10.1039/c3py00692a http://doi.org/10.1039/c3py00692a .

S. Hernandez , J.K. Papp , D. Bhattacharyya . Ind. Eng. Chem. Res. , 2014 . 53 ( 3 ): 1130 DOI: 10.1021/ie403353g http://doi.org/10.1021/ie403353g .

S.Y. Zheng , H. Ding , J. Qian , J. Yin , Z.L. Wu , Y. Song , Q. Zheng . Macromolecules , 2016 . 49 ( 24 ): 9637 DOI: 10.1021/acs.macromol.6b02150 http://doi.org/10.1021/acs.macromol.6b02150 .

X.H. Zhao . Soft Matter , 2014 . 10 ( 5 ): 672 DOI: 10.1039/C3SM52272E http://doi.org/10.1039/C3SM52272E .

T.L. Sun , T. Kurokawa , S. Kuroda , A.B. Ihsan , T. Akasaki , K. Sato , M.A. Haque , T. Nakajima , J.P. Gong . Nat. Mater. , 2013 . 12 ( 10 ): 932 DOI: 10.1038/nmat3713 http://doi.org/10.1038/nmat3713 .

F. Deplace , M.A. Rabjohns , T. Yamaguchi , A.B. Foster , C. Carelli , C. Lei , K. Ouzineb , J.L. Keddie , P.A. Lovell , C. Creton . Soft Matter , 2009 . 5 ( 7 ): 1440 DOI: 10.1039/b815292f http://doi.org/10.1039/b815292f .

浏览量

494

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Highly Stretchable and Self-healing Hydrogels Based on Poly(acrylic acid) and Functional POSS

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)

Multifunctional Polyurethane with High Strength, Toughness, and Self-healing Capacity via Tannic Acid-modified Cellulose Nanocrystals

Advancing the Thin-film Mechanics of Conjugated Polymers: Characterization, Modulation, and Innovation