Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications

Ansuman Nayak; P.S. Rama Sreekanth; Santosh Kumar Sahu; Duryodhan Sahu

doi:10.1007/s10118-017-1967-9

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Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications

Papers | Updated：2021-02-18

- Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications
- Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications
- Chinese Journal of Polymer Science 2017年35卷第9期页码：1073-1085
- Affiliations：
  
  a.Department of Chemistry, National Institute of Science and Technology, Palur Hills, Berhampur, Odisha India, 761008
  b.Department of Chemistry, Gandhi Institute of Engineering and Technology, Gunpur, Odisha India
  c.Department of Mechanical Engineering, National Institute of Science and Technology, Palur Hills, Berhampur, Odisha India, 761008
- Author bio：
  
  Duryodhan Sahu, E-mail:duryodhansahu18@gmail.com
- Funds：
  
  This work was financially supported by the National Institute of Science and Technology, Berhampur, Odisha, India;Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1967-9.
- DOI：10.1007/s10118-017-1967-9
  中图分类号：
- 收稿：2017-03-06，
  
  修回：2017-3-30，
  
  录用：2017-4-3，
  
  纸质出版：2017-09-05
- Accepted：
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Ansuman Nayak, P.S. Rama Sreekanth, Santosh Kumar Sahu, 等. Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications[J]. Chinese Journal of Polymer Science, 2017,35(9):1073-1085.

Ansuman Nayak, P.S. Rama Sreekanth, Santosh Kumar Sahu, et al. Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1073-1085.
Ansuman Nayak, P.S. Rama Sreekanth, Santosh Kumar Sahu, 等. Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications[J]. Chinese Journal of Polymer Science, 2017,35(9):1073-1085. DOI： 10.1007/s10118-017-1967-9.

Ansuman Nayak, P.S. Rama Sreekanth, Santosh Kumar Sahu, et al. Structural Tuning of Low Band Gap Intermolecular Push/Pull Side-chain Polymers for Organic Photovoltaic Applications[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1073-1085. DOI： 10.1007/s10118-017-1967-9.

摘要

Abstract

A series of novel low band gap donor-acceptor (D-A) type organic co-polymers (

BT-F-TPA

BT-CZ-TPA

and

BT-SI-TPA

) consisting of electron-deficient acceptor blocks both in main chains (

) and at the pendant (

) were polymerized with different electron rich donor (

) blocks

i.e.

9-dihexyl-9

-fluorene

-alkyl-2

7-carbazole

and 2

6-dithinosilole

respectively

via

Suzuki method. These polymers exhibited relatively low band gaps (1.65-1.88 eV) and broad absorption ranges (680-740 nm). Bulk heterojunction (BHJ) solar cells incorporating these polymers as electron donors

blended with[6

6]-phenyl-C

-butyric acid methyl ester (PC

BM) or[6

6]-phenyl-C

-butyric acid methyl ester (PC

BM) as electron-acceptors in different weight ratios were fabricated and tested under 100 mW/cm

of AM 1.5 with white-light illumination. The photovoltaic device containing donor

BT-SI-TPA

and acceptor PC

BM in 1:2 weight ratio showed the best power conversion efficiency (PCE) value of 1.88%

with open circuit voltage (

)=0.75 V

short circuit current density (

)=7.60 mA/cm

and fill factor (FF)=33.0%.

关键词

Keywords

references

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