Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate

Zi-xu Gu; Jun Cheng; Ming-zu Zhang; Jin-lin He; Pei-hong Ni

doi:10.1007/s10118-017-1966-x

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Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate

Papers | Updated：2021-02-18

- Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate
- Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate
- Chinese Journal of Polymer Science 2017年35卷第9期页码：1061-1072
- Affiliations：
  
  College of Chemistry, Chemical Engineering and Materials Science, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Soochow University, Suzhou 215123, China
- Author bio：
  
  Pei-hong Ni (倪沛红), E-mail:phni@suda.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21374066);the National Natural Science Foundation of China(20474041);the Major Program of the Natural Science Project of Jiangsu Higher Education Institutions(15KJA150007);the Natural Science Foundation of Jiangsu Province(BK20151263);the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions;Soochow-Waterloo University Joint Project for Nanotechnology from Suzhou Industrial Park;Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1966-x.
- DOI：10.1007/s10118-017-1966-x
  中图分类号：
- 收稿：2017-03-08，
  
  修回：2017-4-18，
  
  录用：2017-4-20，
  
  纸质出版：2017-09-05
- Accepted：
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Zi-xu Gu, Jun Cheng, Ming-zu Zhang, 等. Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate[J]. Chinese Journal of Polymer Science, 2017,35(9):1061-1072.

Zi-xu Gu, Jun Cheng, Ming-zu Zhang, et al. Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1061-1072.
Zi-xu Gu, Jun Cheng, Ming-zu Zhang, 等. Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate[J]. Chinese Journal of Polymer Science, 2017,35(9):1061-1072. DOI： 10.1007/s10118-017-1966-x.

Zi-xu Gu, Jun Cheng, Ming-zu Zhang, et al. Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1061-1072. DOI： 10.1007/s10118-017-1966-x.

摘要

Abstract

Due to the non-crystalline properties of short chain perfluoroalkyl groups

using short chain perfluoroalkyl to stabilize low surface free energy polymers has been a challenging task. In this study

we prepare a series of random copolymers poly(perfluorohexylethyl methacrylate)-

-poly(stearyl acrylate) (P13FMA-

-PSA) and block copolymers poly(perfluorohexylethyl methacrylate)-

-poly(stearyl acrylate) (P13FMA-

-PSA)

and systematically investigate the effects of the sequence structure and the content of 13FMA of the fluorinated copolymers on surface free energy and surface reorganization. Static/dynamic contact angle goniometry and water/oil repellency analyses demonstrate that the random polymer P13FMA-

-PSA could not achieve low surface free energy and low surface reorganization at the same time. In contrast

for the block copolymer P13FMA-

-PSA

both low surface free energy and low surface reorganization are acquired simultaneously. The results of X-ray photoelectron spectroscopy (XPS)

dynamic contact angle goniometry and differential scanning calorimetry (DSC) reveal the above-mentioned properties. The consecutive 13FMA segments improve the surface fluorine density

while the consecutive SA chains enhance the crystallinity of the SA segments

and further hinder the surface reorganization of the perfluoroalkyl groups. Therefore

P13FMA-

-PSA exhibits a higher utilization efficiency of fluorine atoms and a better structural stability than P13FMA-

-PSA.

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references

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