Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties

Xi-hua Cui; Jing Jin; Jie Cui; Gui-yan Zhao; Wei Jiang

doi:10.1007/s10118-017-1964-z

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Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties

Papers | Updated：2021-02-18

- Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties
- Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties
- Chinese Journal of Polymer Science 2017年35卷第9期页码：1086-1096
- Affiliations：
  
  a.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.University of Science and Technology of China, Hefei 230026, China
- Author bio：
  
  Gui-yan Zhao (赵桂艳), E-mail:gyzh@ciac.ac.cn
  Wei Jiang (姜伟), E-mail:wjiang@ciac.ac.cn
- Funds：
  
  the National Natural Science Foundation of China(51673195);Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1964-z.
- DOI：10.1007/s10118-017-1964-z
  中图分类号：
- 收稿：2017-02-27，
  
  修回：2017-3-27，
  
  录用：2017-3-29，
  
  纸质出版：2017-09-05
- Accepted：
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Xi-hua Cui, Jing Jin, Jie Cui, 等. Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties[J]. Chinese Journal of Polymer Science, 2017,35(9):1086-1096.

Xi-hua Cui, Jing Jin, Jie Cui, et al. Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1086-1096.
Xi-hua Cui, Jing Jin, Jie Cui, 等. Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties[J]. Chinese Journal of Polymer Science, 2017,35(9):1086-1096. DOI： 10.1007/s10118-017-1964-z.

Xi-hua Cui, Jing Jin, Jie Cui, et al. Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1086-1096. DOI： 10.1007/s10118-017-1964-z.

摘要

Abstract

Poly(propylene carbonate) (PPC)

the copolymerization product of carbon dioxide and propylene oxide

was chlorinated for the first time in our laboratory. Nuclear magnetic resonance (NMR) spectroscopy and ion chromatography test showed that chlorine atoms were successfully introduced onto the polymer chains of PPC. We named this newborn polymer material as chlorinated poly(propylene carbonate) (CPPC). It is worth noting that the reaction conditions of the chlorination of PPC were quite mild

which could be easily and simply realized at industrial level. What is more important is that CPPC possessed many more distinguished properties in solubility

wettability

adhesiveness

and gas barrier compared with PPC. For example

the bonding strength of CPPC as thermal adhesive is nearly four times higher than that of PPC for wood

stainless steel and glass. The oxygen permeability coefficient of CPPC exhibits a decrease of 33% compared with that of PPC. Moreover

CPPC is quite stable in air

whereas it could be well biodegraded in soil compared with PPC. These results indicated that CPPC could be widely used in the fields of coating

adhesive

barrier materials and so on

which could greatly promote the development of PPC industry.

关键词

Keywords

references

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