Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes

Ya-hui Chang; Wen Zhou; Gao-yi Han; Yun-zhen Chang; Yao-ming Xiao; Wen-hui Ma

doi:10.1007/s10118-017-1957-y

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Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes

Papers | Updated：2021-02-18

- Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes
- Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes
- Chinese Journal of Polymer Science 2017年35卷第8期页码：961-973
- Affiliations：
  
  The Institute of Molecular Science, Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Shanxi University, Taiyuan 030006, China
- Author bio：
  
  Gao-yi Han (韩高义), E-mail:han_gaoyis@sxu.edu.cn
  Yao-ming Xiao (肖尧明), E-mail:ymxiao@sxu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21574076);the National Natural Science Foundation of China(U1510121);the National Natural Science Foundation of China(21501113);the National Natural Science Foundation of China(61504076);the National Natural Science Foundation of China(21407100);the Science Foundation of Shanxi province(2014011016-1);the Science Foundation of Shanxi province(2015021129);the Program for the Top Young and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(020352901014);Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1957-y.
- DOI：10.1007/s10118-017-1957-y
  中图分类号：
- 收稿：2017-01-12，
  
  修回：2017-3-28，
  
  录用：2017-3-29，
  
  纸质出版：2017-08
- Accepted：
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Ya-hui Chang, Wen Zhou, Gao-yi Han, 等. Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes[J]. Chinese Journal of Polymer Science, 2017,35(8):961-973.

Ya-hui Chang, Wen Zhou, Gao-yi Han, et al. Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes[J]. Chinese Journal of Polymer Science, 2017, 35(8): 961-973.
Ya-hui Chang, Wen Zhou, Gao-yi Han, 等. Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes[J]. Chinese Journal of Polymer Science, 2017,35(8):961-973. DOI： 10.1007/s10118-017-1957-y.

Ya-hui Chang, Wen Zhou, Gao-yi Han, et al. Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes[J]. Chinese Journal of Polymer Science, 2017, 35(8): 961-973. DOI： 10.1007/s10118-017-1957-y.

摘要

Abstract

Flexible electrochemical capacitors (ECs) are vitally important as the emerging flexible electronics. We have prepared polypyrrole doped with counter ion of Cl

on carbon fibers (PPy-Cl/CFs)

via

the simple electrochemical deposition method. The flexible ECs based on PPy-Cl/CFs electrodes have been assembled by using H

/poly(vinyl alcohol) (PVA)

/PVA

LiClO

/PVA

KCl/PVA and LiCl/PVA as gel electrolytes. The capacitive properties of ECs have been systematically evaluated with electrochemical methods. The results show that the cells with H

/PVA electrolyte exhibit good cyclic stability (91.5% retention after 15000 cycles) although PPy-Cl/CFs has moderate specific capacitance in H

/PVA (41.6 mF·cm

-1

or 52.0 F·cm

-3

). However

the ECs in other electrolytes have poor cyclic stability. Further electrochemical analysis reveals that the doping/dedoping processes of PPy-Cl/CFs are different in the five electrolytes

and X-ray photoelectron spectra demonstrate that the ratios of counter anions in PPy's oxidized states to those in reduced states are obviously different when PPy-Cl/CFs are kept in reduced or oxidized states in the five electrolytes. The results also illustrate why the capacitors using H

/PVA as electrolyte exhibit good cyclic stability. Furthermore

a light emitting diode (LED) with a threshold voltage of 2.5 V can be lighted by three ECs connected in series.

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Keywords

references

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