Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water

Wu-cheng Fang; Ran Zhang; Ye-feng Yao; Hua-ji Liu; Yu Chen

doi:10.1007/s10118-017-1950-5

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Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water

Papers | Updated：2021-02-18

- Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water
- Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water
- Chinese Journal of Polymer Science 2017年35卷第8期页码：1035-1042
- Affiliations：
  
  a.Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Sciences, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300354, China
  b.Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, Shanghai 200062, China
- Author bio：
  
  Hua-ji Liu (刘华姬), E-mail: liuhuaji@tju.edu.cn
  Yu Chen (陈宇), E-mail: chenyu@tju.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(20804027);the National Natural Science Foundation of China(21274106);Shanghai Key Laboratory of Magnetic Resonance;Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10118-017-1950-5.
- DOI：10.1007/s10118-017-1950-5
  中图分类号：
- 收稿：2017-02-14，
  
  修回：2017-3-22，
  
  录用：2017-3-27，
  
  纸质出版：2017-08
- Accepted：
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Wu-cheng Fang, Ran Zhang, Ye-feng Yao, 等. Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water[J]. Chinese Journal of Polymer Science, 2017,35(8):1035-1042.

Wu-cheng Fang, Ran Zhang, Ye-feng Yao, et al. Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water[J]. Chinese Journal of Polymer Science, 2017, 35(8): 1035-1042.
Wu-cheng Fang, Ran Zhang, Ye-feng Yao, 等. Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water[J]. Chinese Journal of Polymer Science, 2017,35(8):1035-1042. DOI： 10.1007/s10118-017-1950-5.

Wu-cheng Fang, Ran Zhang, Ye-feng Yao, et al. Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water[J]. Chinese Journal of Polymer Science, 2017, 35(8): 1035-1042. DOI： 10.1007/s10118-017-1950-5.

摘要

Abstract

Optically active and inactive hyperbranched polymers with specific thermoresponsive behaviours in water were reported. Through two steps hyperbranched polyethylenimine (HPEI) polymers terminated with different amount of D-phenylalanine (D-Phe)

L-phenylalanine (L-Phe) or DL-phenylalanine (DL-Phe) were prepared and characterized. The analyses on the solution properties by turbidimetry

dynamic light scattering

fluorescence probe and

H-NMR demonstrated that all the polymers exhibited specific thermoresponsive behaviours in water

including:(1) In the dilute polymer concentration region

increasing the polymer concentration led to the increase of phase transition temperature; (2) The optically inactive thermoresponsive hyperbranched polymers showed a higher cloud-point temperature (

) than their corresponding optically active ones in a relatively higher polymer concentration; (3) At the same polymer concentration the hydrophobic groups of the optically inactive HPEI-DL-Phe formed more perfect hydrophobic domain than those of the optically active HPEI-L-Phe and HPEI-D-Phe.

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references

I.Y. Galaev , B. Mattiasson . . Trends Biotechnol. , 1999 . 17 335 DOI: 10.1016/S0167-7799(99)01345-1 http://doi.org/10.1016/S0167-7799(99)01345-1 .

H.J. Moon , D.Y. Ko , M.H. Park , M.K. Joo , B. Jeong . . Chem. Soc. Rev. , 2012 . 41 4860 DOI: 10.1039/c2cs35078e http://doi.org/10.1039/c2cs35078e .

C. Weber , R. Hoogenboom , U.S. Schubert . . Prog. Polym. Sci. , 2012 . 37 686 DOI: 10.1016/j.progpolymsci.2011.10.002 http://doi.org/10.1016/j.progpolymsci.2011.10.002 .

H. Feil , Y.H. Bae , J. Feijen , S.W. Kim . . Macromolecules , 1993 . 26 2496 DOI: 10.1021/ma00062a016 http://doi.org/10.1021/ma00062a016 .

N. Yan , J. Zhang , Y. Yuan , G.T. Chen , P.J. Dyson , Z.C. Li , Y. Kou . . Chem. Commun. , 2010 . 46 1631 DOI: 10.1039/b923290g http://doi.org/10.1039/b923290g .

R.C. Wang , H.J. Liu , J.G. Tong , Y. Chen . . Polym. Chem. , 2014 . 5 2417 DOI: 10.1039/c3py01388j http://doi.org/10.1039/c3py01388j .

H.W. Qin , H.J. Liu , Y. Chen . . Chinese J. Polym. Sci. , 2014 . 32 ( 10 ): 1338 DOI: 10.1007/s10118-014-1509-7 http://doi.org/10.1007/s10118-014-1509-7 .

C.M. Chopko , E.L. Lowden , A.C. Engler , L.G. Griffith , P.T. Hammond . . ACS Macro Lett. , 2012 . 1 727 DOI: 10.1021/mz300088w http://doi.org/10.1021/mz300088w .

Y. Haba , A. Harada , T. Takagishi , K. Kono . . J. Am. Chem. Soc. , 2004 . 126 12760 DOI: 10.1021/ja047755g http://doi.org/10.1021/ja047755g .

X.Y. Liu , X.R. Mu , Y. Liu , H.J. Liu , Y. Chen , F. Cheng , S.C. Jiang . . Langmuir , 2012 . 28 4867 DOI: 10.1021/la300046w http://doi.org/10.1021/la300046w .

Y. Liu , X.Y. Liu , H.J. Liu , F. Cheng , Y. Chen . . Macromol. Res. , 2012 . 20 578 DOI: 10.1007/s13233-012-0079-1 http://doi.org/10.1007/s13233-012-0079-1 .

F.D. Jochum , P. Theato . . Macromolecules , 2009 . 42 5941 DOI: 10.1021/ma900945s http://doi.org/10.1021/ma900945s .

F.D. Jochum , Borg L. zur , P.J. Roth , P. Theato . . Macromolecules , 2009 . 42 7854 DOI: 10.1021/ma901295f http://doi.org/10.1021/ma901295f .

J. Zhang , H.J. Liu , Y. Yuan , S. Jiang , Y. Yao , Y. Chen . . ACS Macro Lett. , 2013 . 2 67 DOI: 10.1021/mz300613q http://doi.org/10.1021/mz300613q .

X.R. Mu , J.G. Tong , Y. Liu , X.Y. Liu , H.J. Liu , Y. Chen . . Polymer , 2013 . 54 2341 DOI: 10.1016/j.polymer.2013.03.004 http://doi.org/10.1016/j.polymer.2013.03.004 .

J. Yan , X. Zhang , W. Li , X. Zhang , K. Liu , P. Wu , A. Zhang . . Soft Matter , 2012 . 8 6371 DOI: 10.1039/c2sm25285f http://doi.org/10.1039/c2sm25285f .

Z.X. Zhang , K.L. Liu , J. Li . . Macromolecules , 2011 . 44 1182 DOI: 10.1021/ma102196q http://doi.org/10.1021/ma102196q .

J. Yan , W. Li , K. Liu , D. Wu , F. Chen , P. Wu , A. Zhang . . Chem. Asian J. , 2011 . 6 3260 DOI: 10.1002/asia.201100528 http://doi.org/10.1002/asia.201100528 .

H.J. Liu , Y.Y. Xu , Y. Chen . . Chinese J. Polym. Sci. , 2016 . 34 ( 5 ): 585 DOI: 10.1007/s10118-016-1779-3 http://doi.org/10.1007/s10118-016-1779-3 .

W. Steinhauer , R. Hoogenboom , H. Keul , M. Moeller . . Macromolecules , 2013 . 46 1447 DOI: 10.1021/ma302606x http://doi.org/10.1021/ma302606x .

X.P. Qiu , F. Tanaka , F.M. Winnik . . Macromolecules , 2007 . 40 7069 DOI: 10.1021/ma071359b http://doi.org/10.1021/ma071359b .

J. Xu , J. Ye , S.Y. Liu . . Macromolecules , 2007 . 40 9103 DOI: 10.1021/ma0717183 http://doi.org/10.1021/ma0717183 .

J. Ye , J. Xu , J. Hu , X. Wang , G. Zhang , S. Liu , C. Wu . . Macromolecules , 2008 . 41 4416 DOI: 10.1021/ma702196g http://doi.org/10.1021/ma702196g .

S.H. Lahasky , X. Hu , D. Zhang . . ACS Macro Lett. , 2012 . 1 580 DOI: 10.1021/mz300017y http://doi.org/10.1021/mz300017y .

Q. Li , C. Gao , S. Li , F. Huo , W. Zhang . . Polym. Chem. , 2014 . 5 2961 DOI: 10.1039/C3PY01699D http://doi.org/10.1039/C3PY01699D .

T. Aoki , M. Muramatsu , T. Torii , K. Sanui , N. Ogata . . Macromolecules , 2001 . 34 3118 DOI: 10.1021/ma001866s http://doi.org/10.1021/ma001866s .

Y. Seto , T. Aoki , S. Kunugi . . Colloid Polym. Sci. , 2005 . 283 1137 DOI: 10.1007/s00396-005-1270-0 http://doi.org/10.1007/s00396-005-1270-0 .

X. Huang , F. Du , D. Liang , S.S. Lin , Z. Li . . Macromolecules , 2008 . 41 5433 DOI: 10.1021/ma800783v http://doi.org/10.1021/ma800783v .

P. Liu , L. Xiang , Q. Tan , H. Tang , H. Zhang . . Polym. Chem. , 2013 . 4 1068 DOI: 10.1039/C2PY20773G http://doi.org/10.1039/C2PY20773G .

Y. Tono , C. Kojima , Y. Haba , T. Takahashi , A. Harada , S. Yagi , K. Kono . . Langmuir , 2006 . 22 4920 DOI: 10.1021/la060066t http://doi.org/10.1021/la060066t .

M.S. Kerr , Alaniz J.R. de , T. Rovis . . J. Org. Chem. , 2005 . 70 5725 DOI: 10.1021/jo050645n http://doi.org/10.1021/jo050645n .

H. Wang , S. Sun , P. Wu . . J. Phys. Chem. B , 2011 . 115 8832 .

M.A. Boerman , der Laan H.L. van , J.C.M.E. Bender , R. Hoogenboom , J.A. Jansen , S.C. Leeuwenburgh , Hest J.C.M. van . . J. Polym. Sci., Part A:Polym. Chem. , 2016 . 54 1573 .

S. Sun , H. Wang , P. Wu . . Soft Matter , 2013 . 9 2878 DOI: 10.1039/c2sm27544a http://doi.org/10.1039/c2sm27544a .

X. Liu , F. Cheng , H. Liu , Y. Chen . . Soft Matter , 2008 . 4 1991 DOI: 10.1039/b811012n http://doi.org/10.1039/b811012n .

Y. Maeda , T. Nakamura , I. Ikeda . . Macromolecules , 2002 . 35 217 DOI: 10.1021/ma011034+ http://doi.org/10.1021/ma011034+ .

G.B. Ray , I. Chakraborty , S.P. Moulik . . J. Colloid Interface Sci. , 2006 . 294 248 DOI: 10.1016/j.jcis.2005.07.006 http://doi.org/10.1016/j.jcis.2005.07.006 .

H.J. Liu , R.H. Dong , Y. Chen . . Chinese J. Polym. Sci. , 2014 . 32 ( 7 ): 961 DOI: 10.1007/s10118-014-1471-4 http://doi.org/10.1007/s10118-014-1471-4 .

M.R. Radowski , A. Shukla , H. von Berlepsch , C. Bottcher , G. Pickaert , H. Rehage , R. Haag . . Angew. Chem. Int. Ed. , 2007 . 46 1265 DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

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