Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush

Jian-hua Li; De-bin Zhang; Xing-xing Ni; Hui Zheng; Qi-qing Zhang

doi:10.1007/s10118-017-1944-3

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Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush

Papers | Updated：2021-02-18

- Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush
- Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush
- Chinese Journal of Polymer Science 2017年35卷第7期页码：809-822
- Affiliations：
  
  Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou 350001, China
- Author bio：
  
  Jian-hua Li (李建华), E-mail:jhli_2005@163.com
  Qi-qing Zhang (张其清), E-mail:zhangqiq@126.com
- Funds：
  
  the National Natural Science Foundation of China(51303028);the National Natural Science Foundation of China(31401609);Test Fund support by Test Center of Fuzhou University
- DOI：10.1007/s10118-017-1944-3
  中图分类号：
- 收稿：2016-12-15，
  
  修回：2017-2-13，
  
  录用：2017-3-2，
  
  纸质出版：2017-07
- Accepted：
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Jian-hua Li, De-bin Zhang, Xing-xing Ni, 等. Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush[J]. Chinese Journal of Polymer Science, 2017,35(7):809-822.

Jian-hua Li, De-bin Zhang, Xing-xing Ni, et al. Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush[J]. Chinese Journal of Polymer Science, 2017, 35(7): 809-822.
Jian-hua Li, De-bin Zhang, Xing-xing Ni, 等. Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush[J]. Chinese Journal of Polymer Science, 2017,35(7):809-822. DOI： 10.1007/s10118-017-1944-3.

Jian-hua Li, De-bin Zhang, Xing-xing Ni, et al. Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush[J]. Chinese Journal of Polymer Science, 2017, 35(7): 809-822. DOI： 10.1007/s10118-017-1944-3.

摘要

Abstract

A silver nanoparticles-poly(carboxybetaine methacrylate) (AgNPs-PCBMA) nanocomposite was prepared on poly(vinylidene fluoride) (PVDF) membrane surface to improve its hydrophilicity and antifouling properties. Firstly

the PVDF membranes were grafted by PCBMA

via

physisorbed free radical grafting technique. Then Ag

coordinated to the carbonyl group on PCBMA and subsequently was reduced to silver nanoparticles. The hydrophilicity of the PVDF-

-PCBMA/Ag membrane was enhanced with the increasing fixed degree (FD) of AgNPs

and the original water contact angle of membrane was reduced to 33.97°. Additionally

water flux recovery ratio (FRR) and bovine serum albumin (BSA) rejection ratio of PVDF-

-PCBMA/AgNPs membrane were improved from 52% to 93.32% and 28.12% to 91.12%

respectively. Further

the PVDF-

-PCBMA/AgNPs membranes exhibited the more pronounced inhibition zone. The study demonstrated that compared with pure AgNPs or the PCBMA polymer brush

the synergistic effect of PCBMA and AgNPs made PVDF membranes have better hydrophilicity and anti-bacterial performances.

关键词

Keywords

references

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