Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups

Guang-hui Nie; Wen-jun Wu; Xi Yue; Shi-jun Liao; Xiu-hua Li

doi:10.1007/s10118-017-1941-6

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Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups

Papers | Updated：2021-02-18

- Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups
- Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups
- Chinese Journal of Polymer Science 2017年35卷第7期页码：823-836
- Affiliations：
  
  School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510641, China
- Author bio：
  
  Xiu-hua Li (李秀华), E-mail: lixiuhua@scut.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51173045);Student Research Program (SRP) Funds of South China University of Technology(105612015S165);Student Research Program (SRP) Funds of South China University of Technology(105612016S198)
- DOI：10.1007/s10118-017-1941-6
  中图分类号：
- 收稿：2016-12-16，
  
  修回：2017-2-7，
  
  录用：2017-2-8，
  
  纸质出版：2017-07-05
- Accepted：
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Guang-hui Nie, Wen-jun Wu, Xi Yue, 等. Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups[J]. Chinese Journal of Polymer Science, 2017,35(7):823-836.

Guang-hui Nie, Wen-jun Wu, Xi Yue, et al. Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups[J]. Chinese Journal of Polymer Science, 2017, 35(7): 823-836.
Guang-hui Nie, Wen-jun Wu, Xi Yue, 等. Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups[J]. Chinese Journal of Polymer Science, 2017,35(7):823-836. DOI： 10.1007/s10118-017-1941-6.

Guang-hui Nie, Wen-jun Wu, Xi Yue, et al. Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups[J]. Chinese Journal of Polymer Science, 2017, 35(7): 823-836. DOI： 10.1007/s10118-017-1941-6.

摘要

Abstract

A series of hydroxide conductive polymers QTBMs carrying dense aromatic side-chain quaternary ammonium groups has been synthesized by using a new monomer of 3

3'-di(3"

5"-dimethylphenyl)-4

4'-difluorodiphenyl sulfone and other commercial monomers

via

polycondensation reaction

and subsequent bromination

quaternization and alkalization. The chemical structures of the ionomers were confirmed by

H-and

C-NMR spectroscopy. Water uptake

swelling ratio

hydroxide conductivity

the number of bonded water per ammonium group (

)

volumetric ion exchange capacity (IEC

Vwet

)

mechanical and thermal properties

and chemical stability were systematically evaluated for the series of QTBMs membranes. QTBMs showed IECs ranging from 1.02 meq·g

-1

to 2.11 meq·g

-1

; in particular

QTBM-60 membrane with the highest IEC (2.11 meq·g

-1

) had very high hydroxide ion conductivity of 131.9 mS·cm

-1

at 80℃

which was attributed to the well assembled nano-channels with distinct phase separation evidenced by small-angle X-ray scattering (SAXS). It was found that the hydrated QTBMs membranes were mechanically stable with moderate water uptakes and swelling ratios

high chemical stability under the harsh alkaline conditions. This work provides a facile way to prepare anion exchange membranes (AEMs) with high performances for the application in alkaline fuel cells.

关键词

Keywords

references

J.R. Varcoe , R.C.T. Slade . . Fuel Cells , 2005 . 5 187 DOI: 10.1002/fuce.v5:2 http://doi.org/10.1002/fuce.v5:2 .

G. Merle , M. Wessling , K. Nijmeijer . . J. Membr. Sci. , 2011 . 377 1 DOI: 10.1016/j.memsci.2011.04.043 http://doi.org/10.1016/j.memsci.2011.04.043 .

Y.J. Wang , J. Qiao , R. Baker , J. Zhang . . Chem. Soc. Rev. , 2013 . 42 5768 DOI: 10.1039/c3cs60053j http://doi.org/10.1039/c3cs60053j .

X. Li , J. Tao , G. Nie , L. Wang , L. Li , S. Liao . . RSC Adv. , 2014 . 4 41398 DOI: 10.1039/C4RA06519K http://doi.org/10.1039/C4RA06519K .

J. Wang , J. Wang , S. Li , S. Zhang . . J. Membr. Sci. , 2011 . 368 246 DOI: 10.1016/j.memsci.2010.11.058 http://doi.org/10.1016/j.memsci.2010.11.058 .

B.C. Lin , L.H. Qiu , B. Qiu , Y. Peng , F. Yan . . Macromolecules , 2011 . 44 9642 DOI: 10.1021/ma202159d http://doi.org/10.1021/ma202159d .

Q. Zhang , Q. Zhang , J. Wang , S. Zhang , S. Li . . Polymer , 2010 . 51 5407 DOI: 10.1016/j.polymer.2010.09.049 http://doi.org/10.1016/j.polymer.2010.09.049 .

D. Chen , M.A. Hickner . . Macromolecules , 2013 . 46 9270 DOI: 10.1021/ma401620m http://doi.org/10.1021/ma401620m .

S. Xu , G. Zhang , Y. Zhang , C.J. Zhao , W.J. Ma , H.C. Sun , N. Zhang , L.Y. Zhang , H. Jiang , H. Na . . J. Power Sources , 2012 . 209 228 DOI: 10.1016/j.jpowsour.2012.02.076 http://doi.org/10.1016/j.jpowsour.2012.02.076 .

Q. Li , L. Liu , Q. Miao , B. Jin , R. Bai . . Chem. Commun. , 2014 . 50 2791 DOI: 10.1039/c3cc47897a http://doi.org/10.1039/c3cc47897a .

B. Lin , H. Dong , Y. Li , Z. Si , F. Gu , F. Yan . . Chem. Mater. , 2013 . 25 1858 DOI: 10.1021/cm400468u http://doi.org/10.1021/cm400468u .

X.H. Li , Y.F. Yu , Q.F. Liu , Y.Z. Meng . . J. Membr. Sci. , 2013 . 436 202 DOI: 10.1016/j.memsci.2013.02.041 http://doi.org/10.1016/j.memsci.2013.02.041 .

X.H. Li , Q.F. Liu , Y.F. Yu , Y.Z. Meng . . J. Mater. Chem. A , 2013 . 1 4324 DOI: 10.1039/c3ta00342f http://doi.org/10.1039/c3ta00342f .

N. Li , C. Wang , S.Y. Lee , C.H. Park , Y.M. Lee , M.D. Guiver . . Angew. Chem. Int. Ed. , 2011 . 123 9324 DOI: 10.1002/ange.201102057 http://doi.org/10.1002/ange.201102057 .

B. Lafitte , P. Jannasch . . Adv. Funct. Mater. , 2007 . 17 2823 DOI: 10.1002/(ISSN)1616-3028 http://doi.org/10.1002/(ISSN)1616-3028 .

L.M. Wang , Q.F. Zhang , S.B. Zhang . . Chinese J. Polym. Sci. , 2015 . 33 ( 9 ): 1225 DOI: 10.1007/s10118-015-1671-6 http://doi.org/10.1007/s10118-015-1671-6 .

X. Li , Q. Liu , Y. Yu , Y. Meng . . J. Membr. Sci. , 2014 . 467 1 DOI: 10.1016/j.memsci.2014.05.016 http://doi.org/10.1016/j.memsci.2014.05.016 .

M. Tanaka , K. Fukasawa , E. Nishino , S. Yamaguchi , K. Yamada , H. Tanaka , B. Bae , K. Miyatake , M. Watanabe . . J. Am. Chem. Soc. , 2011 . 133 10646 DOI: 10.1021/ja204166e http://doi.org/10.1021/ja204166e .

N. Yokota , H. Ono , J. Miyake , E. Nishino , K. Asazawa , M. Watanabe , K. Miyatake . . ACS Appl. Mater. Interfaces , 2014 . 6 17044 DOI: 10.1021/am5046586 http://doi.org/10.1021/am5046586 .

G.H. Nie , X.H. Li , J.X. Tao , W.J. Wu , S.J. Liao . . J. Membr. Sci. , 2015 . 474 187 DOI: 10.1016/j.memsci.2014.09.053 http://doi.org/10.1016/j.memsci.2014.09.053 .

Z. Liu , X.B. Li , K.Z. Shen , P.J. Feng , Y.N. Zhang , X. Xu , W. Hu , Z.H. Jiang , B.J. Liu , M.D. Guiver . . J. Mater. Chem. A , 2013 . 1 6481 DOI: 10.1039/c3ta10355b http://doi.org/10.1039/c3ta10355b .

N. Li , Q. Zhang , C. Wang , Y.M. Lee , M.D. Guiver . . Macromolecules , 2012 . 45 2411 DOI: 10.1021/ma202681z http://doi.org/10.1021/ma202681z .

X. Li , G. Nie , J. Tao , W. Wu , L. Wang , S. Liao . . ACS Appl. Mater. Interfaces , 2014 . 6 7585 DOI: 10.1021/am500915w http://doi.org/10.1021/am500915w .

N. Li , D.W. Shin , D.S. Hwang , Y.M. Lee , M.D. Guiver . . Macromolecules , 2010 . 43 9810 DOI: 10.1021/ma102107a http://doi.org/10.1021/ma102107a .

J. Yan , M.A. Hickner . . Macromolecules , 2010 . 43 2349 DOI: 10.1021/ma902430y http://doi.org/10.1021/ma902430y .

C.Y. Wang , B. Shen , C. Xu , X.Y. Zhao , J. Li . . J. Membr. Sci. , 2015 . 492 281 DOI: 10.1016/j.memsci.2015.05.060 http://doi.org/10.1016/j.memsci.2015.05.060 .

M. Tanaka , M. Koike , K. Miyatake , M. Watanabe . . Polym. Chem.-UK , 2011 . 2 99 DOI: 10.1039/C0PY00238K http://doi.org/10.1039/C0PY00238K .

X. Li , Y. Yu , Q. Liu , Y. Meng . . ACS Appl. Mater. Interfaces , 2012 . 4 3627 DOI: 10.1021/am3007005 http://doi.org/10.1021/am3007005 .

B. Lin , L. Qiu , J. Lu , F. Yan . . Chem. Mater. , 2010 . 22 6718 DOI: 10.1021/cm102957g http://doi.org/10.1021/cm102957g .

M.A. Hickner , A.M. Herring , E.B. Coughlin . . J. Polym. Sci., Part B: Polym. Phys. , 2013 . 51 1727 DOI: 10.1002/polb.23395 http://doi.org/10.1002/polb.23395 .

G. Couture , A. Alaaeddine , F. Boschet , B. Ameduri . . Prog. Polym. Sci. , 2011 . 36 1521 DOI: 10.1016/j.progpolymsci.2011.04.004 http://doi.org/10.1016/j.progpolymsci.2011.04.004 .

C.X. Lin , Y.Z. Zhuo , A.N. Lai , Q.G. Zhang , A.M. Zhu , Q.L. Liu . . RSC Adv. , 2016 . 6 17269 DOI: 10.1039/C5RA22774G http://doi.org/10.1039/C5RA22774G .

Y. He , J. Si , L. Wu , S. Chen , Y. Zhu , J. Pan , X. Ge , Z. Yang , T. Xu . . J. Membr. Sci. , 2016 . 515 189 DOI: 10.1016/j.memsci.2016.05.058 http://doi.org/10.1016/j.memsci.2016.05.058 .

C.X. Lin , Y.Z. Zhuo , A.N. Lai , Q.G. Zhang , A.M. Zhu , M.L. Ye , Q.L. Liu . . J. Membr. Sci. , 2016 . 513 206 DOI: 10.1016/j.memsci.2016.04.054 http://doi.org/10.1016/j.memsci.2016.04.054 .

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