Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy

Sheng-tong Sun; Pei-yi Wu

doi:10.1007/s10118-017-1938-1

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Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy

Feature Articles | Updated：2021-02-18

- Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy
- Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy
- Chinese Journal of Polymer Science 2017年35卷第6期页码：700-712
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China
  b.State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science and Laboratory for Advanced Materials, Fudan University, Shanghai 200433, China
- Author bio：
  
  Sheng-tong Sun (孙胜童), E-mail: shengtongsun@gmail.com
  Pei-yi Wu (武培怡), E-mail: peiyiwu@fudan.edu.cn
- Funds：
  
  financially supported by the National Natural Science Foundation of China(21274030);financially supported by the National Natural Science Foundation of China(51473038);financially supported by the National Natural Science Foundation of China(21604024);the Natural Science Foundation of Shanghai(17ZR1440400);the Open Project of State Key Laboratory of Chemical Engineering(SKL-ChE-16C02);"Chenguang Plan"
- DOI：10.1007/s10118-017-1938-1
  中图分类号：
- 收稿：2016-12-16，
  
  修回：2017-2-9，
  
  录用：2017-2-17，
  
  纸质出版：2017-06-05
- Accepted：
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Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, 2017,35(6):700-712.

Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, 2017, 35(6): 700-712.
Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, 2017,35(6):700-712. DOI： 10.1007/s10118-017-1938-1.

Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, 2017, 35(6): 700-712. DOI： 10.1007/s10118-017-1938-1.

摘要

Abstract

Generalized two-dimensional correlation spectroscopy (2DCOS) and its derivate technique

perturbation correlation moving window (PCMW)

have found great potential in studying a series of physico-chemical phenomena in stimuli-responsive polymeric systems. By spreading peaks along a second dimension

2DCOS can significantly enhance spectral resolution and discern the sequence of group dynamics applicable to various external perturbation-induced spectroscopic changes

especially in infrared (IR)

near-infrared (NIR) and Raman spectroscopy. On the basis of 2DCOS synchronous power spectra changing

PCMW proves to be a powerful tool to monitor complicated spectral variations and to find transition points and ranges. This article reviews the recent work of our research group in the application of 2DCOS and PCMW in thermoresponsive polymers

mainly focused on liquid crystalline polymers and lower critical solution temperature (LCST)-type polymers. Details of group motions and chain conformational changes upon temperature perturbation can thus be elucidated at the molecular level

which contribute to the understanding of their phase transition nature.

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Keywords

references

I. Noda . . Bull. Am. Phys. Soc. , 1986 . 31 520 .

I. Noda . . Appl. Spectrosc. , 1993 . 47 ( 9 ): 1329 DOI: 10.1366/0003702934067694 http://doi.org/10.1366/0003702934067694 .

I. Noda , Y. Ozaki . "Two-dimensional correlation spectroscopy: Applications in vibrational, optical spectroscopy" , : Chichester Wiley , 2004 .

Y. Park , I. Noda , Y.M. Jung . . J. Mol. Struct. , 2016 . 1124 11 DOI: 10.1016/j.molstruc.2016.01.028 http://doi.org/10.1016/j.molstruc.2016.01.028 .

M.A. Czarnecki . . Appl. Spectrosc. Rev. , 2011 . 46 ( 1 ): 67 DOI: 10.1080/05704928.2010.503529 http://doi.org/10.1080/05704928.2010.503529 .

R. Dluhy , S. Shanmukh , S.I. Morita . . Surf. Interface Anal. , 2006 . 38 ( 11 ): 1481 DOI: 10.1002/(ISSN)1096-9918 http://doi.org/10.1002/(ISSN)1096-9918 .

Z. You , L. Zhuo , X. Yang , H. Hong , Z. Liu , Z. Gong , F. Cheng . . Appl. Spectrosc. Rev. , 2015 . 50 ( 10 ): 840 DOI: 10.1080/05704928.2015.1087402 http://doi.org/10.1080/05704928.2015.1087402 .

V.A. Shashilov , I.K. Lednev . . J. Raman Spectrosc. , 2009 . 40 ( 12 ): 1749 DOI: 10.1002/jrs.v40:12 http://doi.org/10.1002/jrs.v40:12 .

M.A.C. Stuart , W.T.S. Huck , J. Genzer , M. Muller , C. Ober , M. Stamm , G.B. Sukhorukov , I. Szleifer , V.V. Tsukruk , M. Urban , F. Winnik , S. Zauscher , I. Luzinov , S. Minko . . Nat. Mater. , 2010 . 9 ( 2 ): 101 DOI: 10.1038/nmat2614 http://doi.org/10.1038/nmat2614 .

D. Roy , W.L.A. Brooks , B.S. Sumerlin . . Chem. Soc. Rev. , 2013 . 42 ( 17 ): 7214 DOI: 10.1039/c3cs35499g http://doi.org/10.1039/c3cs35499g .

S. Morita , H. Shinzawa , R. Tsenkova , I. Noda , Y. Ozaki . . J. Mol. Struct. , 2006 . 799 ( 1 ): 111 .

B. Czarnik-Matusewicz , S. Pilorz , L. Ashton , E.W. Blanch . . J. Mol. Struct. , 2006 . 799 ( 1-3 ): 253 DOI: 10.1016/j.molstruc.2006.03.064 http://doi.org/10.1016/j.molstruc.2006.03.064 .

S. Sun , H. Tang , P. Wu . . Phys. Chem. Chem. Phys. , 2009 . 11 ( 35 ): 7611 DOI: 10.1039/b906773f http://doi.org/10.1039/b906773f .

S.T. Sun , H. Tang , P.Y. Wu , X.H. Wan . . Phys. Chem. Chem. Phys. , 2009 . 11 ( 42 ): 9861 DOI: 10.1039/b909914j http://doi.org/10.1039/b909914j .

M. Thomas , H.H. Richardson . . Vib. Spectrosc. , 2000 . 24 ( 1 ): 137 DOI: 10.1016/S0924-2031(00)00086-2 http://doi.org/10.1016/S0924-2031(00)00086-2 .

S. Morita , H. Shinzawa , I. Noda , Y. Ozaki . . Appl. Spectrosc. , 2006 . 60 ( 4 ): 398 DOI: 10.1366/000370206776593690 http://doi.org/10.1366/000370206776593690 .

M.Y. Wang , S.T. Sun , P.Y. Wu . . Appl. Spectrosc. , 2010 . 64 ( 12 ): 1396 DOI: 10.1366/000370210793561529 http://doi.org/10.1366/000370210793561529 .

M.A. Czarnecki , S. Okretic , H.W. Siesler . . J. Phys. Chem. B , 1997 . 101 ( 3 ): 374 DOI: 10.1021/jp961588s http://doi.org/10.1021/jp961588s .

M.A. Czarnecki , S. Okretic , H.W. Siesler . . Vib. Spectrosc. , 1998 . 18 ( 1 ): 17 DOI: 10.1016/S0924-2031(98)00036-8 http://doi.org/10.1016/S0924-2031(98)00036-8 .

X.F. Chen , Z. Shen , X.H. Wan , X.H. Fan , E.Q. Chen , Y. Ma , Q.F. Zhou . . Chem. Soc. Rev. , 2010 . 39 ( 8 ): 3072 DOI: 10.1039/b814540g http://doi.org/10.1039/b814540g .

Y. Shen , E.Q. Chen , C. Ye , H.L. Zhang , P.Y. Wu , I. Noda , Q.F. Zhou . . J. Phys. Chem. B , 2005 . 109 ( 13 ): 6089 DOI: 10.1021/jp045014w http://doi.org/10.1021/jp045014w .

Y. Jing , H. Tang , P. Wu . . Polym. Chem. , 2013 . 4 ( 24 ): 5768 DOI: 10.1039/c3py00764b http://doi.org/10.1039/c3py00764b .

S.T. Sun , H. Tang , P.Y. Wu . . J. Phys. Chem. B , 2010 . 114 ( 10 ): 3439 DOI: 10.1021/jp908951c http://doi.org/10.1021/jp908951c .

H. Tang , S.T. Sun , J.W. Wu , P.Y. Wu , X.H. Wan . . Polymer , 2010 . 51 ( 23 ): 5482 DOI: 10.1016/j.polymer.2010.09.036 http://doi.org/10.1016/j.polymer.2010.09.036 .

H.G. Schild . . Prog. Polym. Sci. , 1992 . 17 ( 2 ): 163 DOI: 10.1016/0079-6700(92)90023-R http://doi.org/10.1016/0079-6700(92)90023-R .

B. Sun , Y. Lin , P. Wu , H.W. Siesler . . Macromolecules , 2008 . 41 ( 4 ): 1512 DOI: 10.1021/ma702062h http://doi.org/10.1021/ma702062h .

H.J. Lai , P.Y. Wu . . Polymer , 2010 . 51 ( 6 ): 1404 DOI: 10.1016/j.polymer.2010.01.036 http://doi.org/10.1016/j.polymer.2010.01.036 .

S.T. Sun , P.Y. Wu . . Macromolecules , 2010 . 43 ( 22 ): 9501 DOI: 10.1021/ma1016693 http://doi.org/10.1021/ma1016693 .

Z.W. Wang , P.Y. Wu . . RSC Adv. , 2012 . 2 ( 18 ): 7099 DOI: 10.1039/c2ra01349e http://doi.org/10.1039/c2ra01349e .

S. Sun , P. Wu . . Macromolecules , 2013 . 46 ( 1 ): 236 DOI: 10.1021/ma3022376 http://doi.org/10.1021/ma3022376 .

B. Zhang , H. Tang , P. Wu . . Macromolecules , 2014 . 47 ( 14 ): 4728 DOI: 10.1021/ma500774g http://doi.org/10.1021/ma500774g .

W.X. Gu , P.Y. Wu . . Anal. Sci. , 2007 . 23 ( 7 ): 823 DOI: 10.2116/analsci.23.823 http://doi.org/10.2116/analsci.23.823 .

Y. Guo , B. Sun , P. Wu . . Langmuir , 2008 . 24 ( 10 ): 5521 DOI: 10.1021/la7038398 http://doi.org/10.1021/la7038398 .

B.J. Sun , H.J. Lai , P.Y. Wu . . J. Phys. Chem. B , 2011 . 115 ( 6 ): 1335 DOI: 10.1021/jp1066007 http://doi.org/10.1021/jp1066007 .

S. Sun , P. Wu . . J. Phys. Chem. B , 2011 . 115 ( 40 ): 11609 DOI: 10.1021/jp2071056 http://doi.org/10.1021/jp2071056 .

T. Li , H. Tang , P. Wu . . Langmuir , 2015 . 31 ( 24 ): 6870 DOI: 10.1021/acs.langmuir.5b01009 http://doi.org/10.1021/acs.langmuir.5b01009 .

W. Li , P. Wu . . Polym. Chem. , 2014 . 5 ( 19 ): 5578 DOI: 10.1039/C4PY00593G http://doi.org/10.1039/C4PY00593G .

G. Wang , P. Wu . . Soft Matter , 2015 . 11 ( 26 ): 5253 DOI: 10.1039/C5SM00603A http://doi.org/10.1039/C5SM00603A .

H.J. Lai , G.T. Chen , P.Y. Wu , Z.C. Li . . Soft Matter , 2012 . 8 ( 9 ): 2662 DOI: 10.1039/c2sm06779j http://doi.org/10.1039/c2sm06779j .

S.T. Sun , W.D. Zhang , W. Zhang , P.Y. Wu , X.L. Zhu . . Soft Matter , 2012 . 8 ( 14 ): 3980 DOI: 10.1039/c2sm06908c http://doi.org/10.1039/c2sm06908c .

Z. Wang , H. Lai , P. Wu . . Soft Matter , 2012 . 8 ( 46 ): 11644 DOI: 10.1039/c2sm26172c http://doi.org/10.1039/c2sm26172c .

Q. Wang , H. Tang , P. Wu . . Langmuir , 2015 . 31 ( 23 ): 6497 DOI: 10.1021/acs.langmuir.5b00878 http://doi.org/10.1021/acs.langmuir.5b00878 .

Y. Dai , P. Wu . . Phys. Chem. Chem. Phys. , 2016 . 18 ( 31 ): 21360 DOI: 10.1039/C6CP04286D http://doi.org/10.1039/C6CP04286D .

Q. Wang , H. Tang , P. Wu . . J. Polym. Sci.Part B: Polym. Phys. , 2016 . 54 ( 3 ): 385 DOI: 10.1002/polb.v54.3 http://doi.org/10.1002/polb.v54.3 .

L. Jia , C. Guo , L. Yang , J. Xiang , Y. Tang , C. Liu , H. Liu . . J. Colloid Interf. Sci. , 2010 . 345 ( 2 ): 332 DOI: 10.1016/j.jcis.2010.01.060 http://doi.org/10.1016/j.jcis.2010.01.060 .

Z. Ye , Y. Li , Z. An , P. Wu . . Langmuir , 2016 . 32 ( 26 ): 6691 DOI: 10.1021/acs.langmuir.6b01785 http://doi.org/10.1021/acs.langmuir.6b01785 .

T. Li , H. Tang , P. Wu . . Soft Matter , 2015 . 11 ( 15 ): 3046 DOI: 10.1039/C5SM00186B http://doi.org/10.1039/C5SM00186B .

G. Wang , P. Wu . . Langmuir , 2016 . 32 ( 15 ): 3728 DOI: 10.1021/acs.langmuir.6b00392 http://doi.org/10.1021/acs.langmuir.6b00392 .

G. Wang , P. Wu . . Soft Matter , 2016 . 12 ( 3 ): 925 DOI: 10.1039/C5SM02032H http://doi.org/10.1039/C5SM02032H .

M. Motornov , Y. Roiter , I. Tokarev , S. Minko . . Prog. Polym. Sci. , 2010 . 35 ( 1-2 ): 174 DOI: 10.1016/j.progpolymsci.2009.10.004 http://doi.org/10.1016/j.progpolymsci.2009.10.004 .

S. Sun , J. Hu , H. Tang , P. Wu . . J. Phys. Chem. B , 2010 . 114 ( 30 ): 9761 DOI: 10.1021/jp103818c http://doi.org/10.1021/jp103818c .

S. Sun , J. Hu , H. Tang , P. Wu . . Phys. Chem. Chem. Phys. , 2011 . 13 ( 11 ): 5061 DOI: 10.1039/c0cp01939a http://doi.org/10.1039/c0cp01939a .

L. Hou , K. Ma , Z. An , P. Wu . . Macromolecules , 2014 . 47 ( 3 ): 1144 DOI: 10.1021/ma4021906 http://doi.org/10.1021/ma4021906 .

B. Zhang , S. Sun , P. Wu . . Soft Matter , 2013 . 9 ( 5 ): 1678 DOI: 10.1039/C2SM27355A http://doi.org/10.1039/C2SM27355A .

Y. Zhou , H. Tang , P. Wu . . Phys. Chem. Chem. Phys. , 2015 . 17 ( 38 ): 25525 DOI: 10.1039/C5CP03676C http://doi.org/10.1039/C5CP03676C .

L. Hou , P. Wu . . RSC Adv. , 2014 . 4 ( 74 ): 39231 DOI: 10.1039/C4RA06471B http://doi.org/10.1039/C4RA06471B .

W. Sun , P. Wu . . Phys. Chem. Chem. Phys. , 2017 . 19 ( 1 ): 127 DOI: 10.1039/C6CP06862F http://doi.org/10.1039/C6CP06862F .

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