Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?

Your Location：

Home >

Browse articles >

Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?

Papers | Updated：2021-02-18

- Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?
- Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?
- Chinese Journal of Polymer Science 2017年35卷第6期页码：773-781
- Affiliations：
  
  a.Department of Polymer and Processing, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
  b.College of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, China
- Author bio：
  
  Lan Xie (谢兰), E-mail: mm.lanxie@gzu.edu.cn
  Yu-zhu Xiong (熊玉竹), E-mail: 932271187@qq.com
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China(21604016);National Undergraduate Innovation Training Program(201610657004)
- DOI：10.1007/s10118-017-1929-2
  中图分类号：
- 收稿：2016-10-09，
  
  修回：2016-12-20，
  
  录用：2016-12-28，
  
  纸质出版：2017-06-05
- Accepted：
Scan QR Code
Lan Xie, Xu-juan Li, Yu-zhu Xiong, 等. Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?[J]. Chinese Journal of Polymer Science, 2017,35(6):773-781.

Lan Xie, Xu-juan Li, Yu-zhu Xiong, et al. Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?[J]. Chinese Journal of Polymer Science, 2017, 35(6): 773-781.
Lan Xie, Xu-juan Li, Yu-zhu Xiong, 等. Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?[J]. Chinese Journal of Polymer Science, 2017,35(6):773-781. DOI： 10.1007/s10118-017-1929-2.

Lan Xie, Xu-juan Li, Yu-zhu Xiong, et al. Can Classic Avrami Theory Describe the Isothermal Crystallization Kinetics for Stereocomplex Poly(lactic acid)?[J]. Chinese Journal of Polymer Science, 2017, 35(6): 773-781. DOI： 10.1007/s10118-017-1929-2.

摘要

Abstract

Classic Avrami model and its modifications have found diverse applications in describing the thermal and phase behaviors of inorganic metals and organic polymers. The direct introduction of classic Avrami equation to offer quantitative analyses of crystallization kinetic parameters for enantiomeric poly(lactic acid) (PLA) blends may

however

lead to contradictory conclusions. As revealed by this study

during the characterization of isothermal melt and cold crystallization for stereocomplex PLA containing equal-weight poly(L-lactic acid) and poly(D-lactic acid)

the kinetic parameters yielded by Avrami equation are not in line with the classic crystallization hypotheses or the direct morphological observations. The underlying mechanisms

to some extent

lie in the generation of stereocomplex crystals (SCs) during the cooling/heating which affects the subsequent crystallization dynamics. The huge gap between the melting enthalpies of 100% crystalline SCs (142 J/g) and homo-crystals (HCs

93 J/g) is most likely responsible for the confusing kinetic parameters acquired from the deduction of Avrami equation

which is based on the integration of enthalpies as a function of crystallization time. This prompts for great care that the classic Avrami equation is not applicable to accurately describe the crystallization kinetics of stereocomplex PLA

given the generation of SCs prior to crystallization and the coexistence of HCs and SCs during crystallization.

关键词

Keywords

references

H. Xu , C.Y. Liu , C. Chen , B.S. Hsiao , G.J. Zhong , Z.M. Li . . Biopolymers , 2012 . 97 825 DOI: 10.1002/bip.v97.10 http://doi.org/10.1002/bip.v97.10 .

L. Xie , H. Xu , B. Niu , X. Ji , J. Chen , Z.M. Li , B.S. Hsiao , G.J. Zhong . . Biomacromolecules , 2014 . 15 4054 DOI: 10.1021/bm5010993 http://doi.org/10.1021/bm5010993 .

H. Xu , L. Xie , J.B. Chen , X. Jiang , B.S. Hsiao , G.J. Zhong , Q. Fu , Z.M. Li . . Mater. Horiz. , 2014 . 1 546 DOI: 10.1039/C4MH00085D http://doi.org/10.1039/C4MH00085D .

X. Sun , A. Tokuda , Y. Oji , T. Nakatani , H. Tsuji , Y. Ozaki , S. Yan , I. Takahashi . . Macromolecules , 2012 . 45 2485 DOI: 10.1021/ma202543s http://doi.org/10.1021/ma202543s .

Y. Ikada , K. Jamshidi , H. Tsuji , S.H. Hyon . . Macromolecules , 1987 . 20 904 DOI: 10.1021/ma00170a034 http://doi.org/10.1021/ma00170a034 .

J. Zhang , Y. Duan , H. Sato , H. Tsuji , I. Noda , S. Yan , Y. Ozaki . . Macromolecules , 2005 . 38 8012 DOI: 10.1021/ma051232r http://doi.org/10.1021/ma051232r .

H. Tsuji , M. Hosokawa , Y. Sakamoto . . ACS Macro Lett. , 2012 . 1 687 DOI: 10.1021/mz300155f http://doi.org/10.1021/mz300155f .

B.R. Sveinbjörnsson , G.M. Miyake , A. El-Batta , R.H. Grubbs . . ACS Macro Lett. , 2014 . 3 26 DOI: 10.1021/mz400568j http://doi.org/10.1021/mz400568j .

Y. Sun , C. He . . ACS Macro Lett. , 2012 . 1 709 DOI: 10.1021/mz300131u http://doi.org/10.1021/mz300131u .

S.R. Andersson , M. Hakkarainen , A.C. Albertsson . . Polymer , 2013 . 54 4105 DOI: 10.1016/j.polymer.2013.06.008 http://doi.org/10.1016/j.polymer.2013.06.008 .

S.R. Andersson , M. Hakkarainen , S. Inkinen , A. Södergård , A.C. Albertsson . . Biomacromolecules , 2010 . 11 1067 DOI: 10.1021/bm100029t http://doi.org/10.1021/bm100029t .

S.R. Andersson , M. Hakkarainen , S. Inkinen , A. Södergård , A.C. Albertsson . . Biomacromolecules , 2012 . 13 1212 DOI: 10.1021/bm300196h http://doi.org/10.1021/bm300196h .

S. Inkinen , M. Hakkarainen , A.C. Albertsson , A. Södergård . . Biomacromolecules , 2011 . 12 523 DOI: 10.1021/bm101302t http://doi.org/10.1021/bm101302t .

N. Sugai , T. Yamamoto , Y. Tezuka . . ACS Macro Lett. , 2012 . 1 902 DOI: 10.1021/mz300086v http://doi.org/10.1021/mz300086v .

H. Xu , D. Wu , X. Yang , L. Xie , M. Hakkarainen . . Macromolecules , 2015 . 48 2127 DOI: 10.1021/ma502603j http://doi.org/10.1021/ma502603j .

N. Rahman , T. Kawai , G. Matsuba , K. Nishida , T. Kanaya , H. Watanabe , H. Okamoto , M. Kato , A. Usuki , M. Matsuda , K. Nakajima , N. Honma . . Macromolecules , 2009 . 42 4739 DOI: 10.1021/ma900004d http://doi.org/10.1021/ma900004d .

B.A. Lotz . . ACS Macro Lett. , 2015 . 4 602 DOI: 10.1021/acsmacrolett.5b00205 http://doi.org/10.1021/acsmacrolett.5b00205 .

P. Zhang , R. Tian , B. Na , R. Lv , Q. Liu . . Polymer , 2015 . 60 221 DOI: 10.1016/j.polymer.2015.01.049 http://doi.org/10.1016/j.polymer.2015.01.049 .

L. Bouapao , H. Tsuji . . Macromol. Chem. Phys. , 2009 . 210 993 DOI: 10.1002/macp.v210:12 http://doi.org/10.1002/macp.v210:12 .

Y. He , Y. Xu , J. Wei , Z. Fan , S. Li . . Polymer , 2008 . 49 5670 DOI: 10.1016/j.polymer.2008.10.028 http://doi.org/10.1016/j.polymer.2008.10.028 .

H. Marubayashi , T. Nobuoka , S. Iwamoto , A. Takemura , T. Iwata . . ACS Macro Lett. , 2013 . 2 355 DOI: 10.1021/mz400014s http://doi.org/10.1021/mz400014s .

S.C. Schmidt , M.A. Hillmyer . . J.Polym. Sci., Part B: Polym. Phys. , 2001 . 39 300 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

K.S. Anderson , M.A. Hillmyer . . Polymer , 2006 . 47 2030 DOI: 10.1016/j.polymer.2006.01.062 http://doi.org/10.1016/j.polymer.2006.01.062 .

R.Y. Bao , W. Yang , W.R. Jiang , Z.Y. Liu , B.H. Xie , M.B. Yang . . J. Phys. Chem. B , 2013 . 117 3667 DOI: 10.1021/jp311878f http://doi.org/10.1021/jp311878f .

S. Saeidlou , M.A. Huneault , H. Li , C.B. Park . . Polymer , 2013 . 54 5762 DOI: 10.1016/j.polymer.2013.08.031 http://doi.org/10.1016/j.polymer.2013.08.031 .

X.F. Wei , R.Y. Bao , Z.Q. Cao , L.Q. Zhang , Z.Y. Liu , W. Yang , B.H. Xie , M.B. Yang . . Colloid Polym. Sci. , 2014 . 292 163 DOI: 10.1007/s00396-013-3067-x http://doi.org/10.1007/s00396-013-3067-x .

X.F. Wei , R.Y. Bao , Z.Q. Cao , W. Yang , B.H. Xie , M.B. Yang . . Macromolecules , 2014 . 47 1439 DOI: 10.1021/ma402653a http://doi.org/10.1021/ma402653a .

B. Na , J. Zhu , R. Lv , Y. Ju , R. Tian , B. Chen . . Macromolecules , 2014 . 47 347 DOI: 10.1021/ma402405c http://doi.org/10.1021/ma402405c .

S. Saeidlou , M.A. Huneault , H. Li , P. Sammut , C.B. Park . . Polymer , 2012 . 53 5816 DOI: 10.1016/j.polymer.2012.10.030 http://doi.org/10.1016/j.polymer.2012.10.030 .

H. Xu , Z.X. Feng , L. Xie , M. Hakkarainen . . ACS Sustainable Chem. Eng. , 2016 . 4 334 DOI: 10.1021/acssuschemeng.5b01273 http://doi.org/10.1021/acssuschemeng.5b01273 .

H. Xu , G. Hua , K. Odelius , M. Hakkarainen . . Macromol. Chem. Phys. , 2016 . 217 2567 DOI: 10.1002/macp.201600364 http://doi.org/10.1002/macp.201600364 .

T. Pradell , D. Crespo , N. Clavaguera , M. Clavaguera-Mora . . J. Phys.: Condens. Matter , 1998 . 10 3833 DOI: 10.1088/0953-8984/10/17/014 http://doi.org/10.1088/0953-8984/10/17/014 .

S.Z. Cheng , B. Wunderlich . . Macromolecules , 1988 . 21 3327 DOI: 10.1021/ma00189a031 http://doi.org/10.1021/ma00189a031 .

H. Xu , L. Xie , X. Jiang , X.J. Li , Y. Li , Z.J. Zhang , G.J. Zhong , Z.M. Li . . J. Phys. Chem. B , 2014 . 118 812 DOI: 10.1021/jp409021q http://doi.org/10.1021/jp409021q .

H. Xu , L. Xie , X. Jiang , M. Hakkarainen , J.B. Chen , G.J. Zhong , Z.M. Li . . Biomacromolecules , 2014 . 15 1676 DOI: 10.1021/bm500100z http://doi.org/10.1021/bm500100z .

J.F. Mano , Y. Wang , J.C. Viana , Z. Denchev , M.J. Oliveira . . Macromol. Mater. Eng. , 2004 . 289 910 DOI: 10.1002/(ISSN)1439-2054 http://doi.org/10.1002/(ISSN)1439-2054 .

H. Xu , G.J. Zhong , Q. Fu , J. Lei , W. Jiang , B.S. Hsiao , Z.M. Li . . ACS Appl. Mater. Interfaces , 2012 . 4 6774 DOI: 10.1021/am3019756 http://doi.org/10.1021/am3019756 .

H. Xu , L. Xie , M. Hakkarainen . . ACS Sustainable Chem. Eng. , 2015 . 3 1443 DOI: 10.1021/acssuschemeng.5b00320 http://doi.org/10.1021/acssuschemeng.5b00320 .

H. Xu , X. Yang , L. Xie , M. Hakkarainen . . Biomacromolecules , 2016 . 17 985 DOI: 10.1021/acs.biomac.5b01636 http://doi.org/10.1021/acs.biomac.5b01636 .

H. Xu , L. Xie , D. Wu , M. Hakkarainen . . ACS Sustainable Chem. Eng. , 2016 . 4 2211 DOI: 10.1021/acssuschemeng.5b01703 http://doi.org/10.1021/acssuschemeng.5b01703 .

J. Zhang , H. Sato , H. Tsuji , I. Noda , Y. Ozaki . . Macromolecules , 2005 . 38 1822 DOI: 10.1021/ma047872w http://doi.org/10.1021/ma047872w .

P. Pan , J. Yang , G. Shan , Y. Bao , Z. Weng , A. Cao , K. Yazawa , Y. Inoue . . Macromolecules , 2012 . 45 189 DOI: 10.1021/ma201906a http://doi.org/10.1021/ma201906a .

E. Fischer , H.J. Sterzel , G. Wegner . . Colloid Polym. Sci. , 1973 . 251 980 .

0

浏览量

4

Downloads

0

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

相关文章

Fractionated Crystallization Kinetics and Polymorphic Homocrystalline Structure of Poly(L-lactic acid)/Poly(D-lactic acid) Blends: Effect of Blend Ratio

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

Special Topic: Chirality in Polymers

相关作者

Wang-Kai Xiang

Qing Xie

Shan-Shan Xu

Chen-Xuan Sun

Cheng-Tao Yu

Ying Zheng

Peng-Ju Pan

Zi-Xiang Dai

相关机构

State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University

Institute of Zhejiang University-, Quzhou

Institute of Polymer Materials, School of Materials Science and Engineering, Jiangsu University

Key Laboratory of Green Preparation and Application for Functional Materials of Ministry of Education, Hubei Key Laboratory of Polymer Materials, School of Material Science and Engineering, Hubei University

Department of Chemistry and Chemical Engineering, SBA School of Science and Engineering, Lahore University of Management Sciences (LUMS), DHA

⁰