Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution

Zhi-da Wang; Chang-feng Yan; Ying Huang; Li-qi Yi

doi:10.1007/s10118-017-1927-4

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Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution

Papers | Updated：2021-02-18

- Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution
- Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution
- Chinese Journal of Polymer Science 2017年35卷第5期页码：641-648
- Affiliations：
  
  a.Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
  b.Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
  c.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  Zhi-da Wang (王志达), E-mail:wangzd@ms.giec.ac.cn
- Funds：
  
  This work was financially supported by the Key Laboratory of Renewable Energy Foundation of Chinese Academy of Sciences(No. Y609JK1001);the National Natural Science Foundation of China(No. 51576201);Natural Science Foundation of Guangdong province(Nos. 2015A030312007 and 2015A030313716);Guangdong Science and Technology Project(No. 2013B050800007);and Guangzhou Science and Technology Project(No. 2016201604030010)
- DOI：10.1007/s10118-017-1927-4
  中图分类号：
- 收稿：2016-09-13，
  
  修回：2016-10-10，
  
  录用：2016-10-11，
  
  纸质出版：2017-05
- Accepted：
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Zhi-da Wang, Chang-feng Yan, Ying Huang, 等. Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution[J]. Chinese Journal of Polymer Science, 2017,35(5):641-648.

Zhi-da Wang, Chang-feng Yan, Ying Huang, et al. Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution[J]. Chinese Journal of Polymer Science, 2017, 35(5): 641-648.
Zhi-da Wang, Chang-feng Yan, Ying Huang, 等. Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution[J]. Chinese Journal of Polymer Science, 2017,35(5):641-648. DOI： 10.1007/s10118-017-1927-4.

Zhi-da Wang, Chang-feng Yan, Ying Huang, et al. Dependence of Size and Morphology on Shear Flow for PS-based Amphiphilic Block Copolymer Micelles in Aqueous Solution[J]. Chinese Journal of Polymer Science, 2017, 35(5): 641-648. DOI： 10.1007/s10118-017-1927-4.

摘要

Abstract

This contribution focuses on the impact of shear flow on size and nanostructure of PS-based amphiphilic block copolymer (BC) micelles by varying the stirring rate and copolymer composition. The results show that the vesicles formed from diblock copolymer (di-BC) of PS-

-PAA remain with vesicular morphology

although the average size decreases

with the increase of stirring rate. However

the multi-compartment micelles (MCMs) formed from tri-block copolymer (tri-BC) of PS-

-P2VP-

-PEO are quite intricate

in which the copolymer first self-assembles into spheres

then to clusters

to large compound micelles (LCMs)

and finally back to spheres

as stirring rate increases from 100 r/min to 2200 r/min. Formation mechanism studies manifest that vesicles form simultaneously as water is added to the di-BC solution

termed as directassembly

and remain with vesicular structure in the flowing process. While for the PS-

-P2VP-

-PEO copolymer

spherical micelles at initial stage can further assemble into clusters and LCMs

termed as second-assembly

due to the speeding-upaggregation of the favorable stirring. As a result

an invert V-relationship between tri-BC micelle dimension and stirring rate is observed in contrast to the non-linear decreasing curve of di-BC vesicles. It is by investigating these various amphiphilic BCs that the understanding of shear dependence of size and morphology of micelles is improved from self-assembly to second-assembly process.

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references

H. Liu , J. Luo , W. Shan , D. Guo , J. Wang , C.H. Hsu , M. Huang , W. Zhang , B. Lotz , W.B. Zhang , T. Liu , K. Yue , S.Z.D. Cheng . . ACS Nano , 2016 . 10 ( 7 ): 6585 DOI: 10.1021/acsnano.6b01336 http://doi.org/10.1021/acsnano.6b01336 .

X.D. Ye , J.Y. Fei , K. Xu , R.K. Bai , Polym. Sci. J. . . Part B:Polym. Phys. , 2010 . 48 ( 11 ): 1168 DOI: 10.1002/polb.v48:11 http://doi.org/10.1002/polb.v48:11 .

L. Sheng , H. Chen , W.X. Fu , Z.B. Li . . Langmuir , 2015 . 31 ( 44 ): 11964 DOI: 10.1021/acs.langmuir.5b02417 http://doi.org/10.1021/acs.langmuir.5b02417 .

Y.J. Su , J.H. Huang . . Chinese J. Polym. Sci. , 2016 . 34 ( 7 ): 838 DOI: 10.1007/s10118-016-1803-7 http://doi.org/10.1007/s10118-016-1803-7 .

Z. Yu , K. Lu , Z.X. Wei . . Sci. China Chem. , 2012 . 55 ( 11 ): 2283 DOI: 10.1007/s11426-012-4734-3 http://doi.org/10.1007/s11426-012-4734-3 .

S. Roland , C. Pellerin , C.G. Bazuin , R.E. Prud'homme . . Macromolecules , 2012 . 45 ( 19 ): 7964 DOI: 10.1021/ma301383v http://doi.org/10.1021/ma301383v .

Z.N. Wu , J.L. Liu , Y.C. Li , Z.Y. Cheng , T.T. Li , H. Zhang , Z.Y. Lu , B. Yang . . ACS Nano , 2015 . 9 ( 6 ): 6315 DOI: 10.1021/acsnano.5b01823 http://doi.org/10.1021/acsnano.5b01823 .

S.Y. Ma , Y. Hu , R. Wang . . Macromolecules , 2016 . 49 ( 9 ): 3535 DOI: 10.1021/acs.macromol.5b02778 http://doi.org/10.1021/acs.macromol.5b02778 .

C.Y. Yang , Q. Li , C.H. Cai , J.P. Lin . . Langmuir , 2016 . 32 ( 27 ): 6917 DOI: 10.1021/acs.langmuir.6b01484 http://doi.org/10.1021/acs.langmuir.6b01484 .

G.M. Liu , L.C. Zheng , X.Q. Zhang , C.C. Li , D.J. Wang . . Macromolecules , 2014 . 47 ( 21 ): 7533 DOI: 10.1021/ma501832z http://doi.org/10.1021/ma501832z .

K. Cao , J.T. Xu , X.S. Wang . . Chinese J. Polym. Sci. , 2012 . 30 ( 5 ): 674 DOI: 10.1007/s10118-012-1161-z http://doi.org/10.1007/s10118-012-1161-z .

J. Yuan , A. Hajebifard , C. George , P. Berini , S. Zou . . J. Colloid Interf. Sci. , 2013 . 410 1 DOI: 10.1016/j.jcis.2013.07.070 http://doi.org/10.1016/j.jcis.2013.07.070 .

S.H. Kim , F. Nederberg , L. Zhang , C.G. Wade , R.M. Waymouth , J.L. Hedrick . . Nano Lett. , 2008 . 8 ( 1 ): 294 DOI: 10.1021/nl0726813 http://doi.org/10.1021/nl0726813 .

A. Nazemi , C.E. Boott , D.J. Lunn , J. Gwyther , D.W. Hayward , R.M. Richardson , M.A. Winnik , I. Manners . . J. Am. Chem. Soc. , 2016 . 138 ( 13 ): 4484 DOI: 10.1021/jacs.5b13416 http://doi.org/10.1021/jacs.5b13416 .

B. Guo , X.Y. Sun , Y.F. Zhou , D.Y. Yan . . Sci. China Chem. , 2010 . 53 ( 3 ): 487 DOI: 10.1007/s11426-010-0083-2 http://doi.org/10.1007/s11426-010-0083-2 .

Z.Y. Deng , Y.F. Qian , Y.Q. Yu , G.H. Liu , J.M. Hu , G.Y. Zhang , S.Y. Liu . . J. Am. Chem. Soc. , 2016 . 138 ( 33 ): 10452 DOI: 10.1021/jacs.6b04115 http://doi.org/10.1021/jacs.6b04115 .

N. Wang , W.H. Niu , L.G. Li , J. Liu , Z.H. Tang , W.J. Zhou , S.W. Chen . . Chem. Commun. , 2015 . 51 ( 53 ): 10620 DOI: 10.1039/C5CC02808F http://doi.org/10.1039/C5CC02808F .

T. Huang , H.M. Li , L. Huang , S.L. Li , K. Li , Y.F. Zhou . . Langmuir , 2016 . 32 ( 4 ): 991 DOI: 10.1021/acs.langmuir.5b04478 http://doi.org/10.1021/acs.langmuir.5b04478 .

Y.M. Wan , Z.N. Wang , J. Sun , Z.B. Li . . Langmuir , 2016 . 32 ( 20 ): 7512 .

X.G. Cao , L.S. Zhang , J.B. Gu , L.Q. Wang , J.P. Lin . . Polymer , 2015 . 72 10 DOI: 10.1016/j.polymer.2015.07.007 http://doi.org/10.1016/j.polymer.2015.07.007 .

I. Wyman , G.J. Liu . . Sci. China Chem. , 2013 . 56 ( 8 ): 1040 DOI: 10.1007/s11426-013-4951-4 http://doi.org/10.1007/s11426-013-4951-4 .

T.Y. Lo , A. Dehghan , P. Georgopanos , A. Avgeropoulos , A.C. Shi , R.M. Ho . . Macromolecules , 2016 . 49 ( 2 ): 624 DOI: 10.1021/acs.macromol.5b02685 http://doi.org/10.1021/acs.macromol.5b02685 .

J. Yan , L.X. Zhao , C. Li , Z. Hu , G.F. Zhang , Z.Q. Chen , T. Chen , Z.L. Huang , J.T. Zhu , M.Q. Zhu . . J. Am. Chem. Soc , 2015 . 137 ( 7 ): 2436 DOI: 10.1021/ja512189a http://doi.org/10.1021/ja512189a .

J. Wang , G.X. Chen , J.L. Sun , Q.F. Li . . J. Phys. Chem. B , 2011 . 115 ( 12 ): 2824 DOI: 10.1021/jp111115x http://doi.org/10.1021/jp111115x .

G. Zardalidis , K. Gatsouli , S. Pispas , M. Mezger , G. Floudas . . Macromolecules , 2015 . 48 ( 19 ): 7164 DOI: 10.1021/acs.macromol.5b01596 http://doi.org/10.1021/acs.macromol.5b01596 .

G. Polymeropoulos , G. Zapsas , N. Hadjichristidis , A. Avgeropoulos . . ACS Macro Lett. , 2015 . 4 ( 12 ): 1392 DOI: 10.1021/acsmacrolett.5b00795 http://doi.org/10.1021/acsmacrolett.5b00795 .

Z. Geng , Z.K. Cheng , Y.T. Zhu , W. Jiang , Polym. Sci. J. . . Part B:Polym. Phys. , 2016 . 120 ( 24 ): 5527 .

X.Y. Liu , J. Wu , J.S. Kim , A. Eisenberg . . Langmuir , 2006 . 22 ( 1 ): 419 DOI: 10.1021/la0519610 http://doi.org/10.1021/la0519610 .

Z.D. Wang , Y. Gan , C.F. Yan , Y. Huang , W. Jiang . . Polymer , 2016 . 90 276 DOI: 10.1016/j.polymer.2016.03.036 http://doi.org/10.1016/j.polymer.2016.03.036 .

R. Vyhnalkova , A.H.E. Muller , A. Eisenberg . . Langmuir , 2014 . 30 ( 17 ): 5031 DOI: 10.1021/la500712b http://doi.org/10.1021/la500712b .

C. Tian , J. Ling , Y.Q. Shen . . Chinese J. Polym. Sci. , 2015 . 33 ( 8 ): 1186 DOI: 10.1007/s10118-015-1669-0 http://doi.org/10.1007/s10118-015-1669-0 .

S.Q. Li , L. Liu , J.B. Hu . . Sci. China Chem. , 2012 . 55 ( 9 ): 1940 DOI: 10.1007/s11426-012-4510-4 http://doi.org/10.1007/s11426-012-4510-4 .

Z.D. Wang , F.M. Sun , S.L. Huang , C.F. Yan , Polym. Sci. J. . . Part B:Polym. Phys. , 2016 . 54 ( 15 ): 1450 DOI: 10.1002/polb.v54.15 http://doi.org/10.1002/polb.v54.15 .

K. Wang , S.M. Jin , J.P. Xu , R.J. Liang , S. Khurram , Z.G. Xue , X.L. Xie , E.L. Lee , J.T. Zhu . . ACS Nano , 2016 . 10 ( 5 ): 4954 DOI: 10.1021/acsnano.6b00487 http://doi.org/10.1021/acsnano.6b00487 .

D. Jia , T. Zuo , S. Rogers , H. Cheng , B. Hammouda , C.C. Han . . Macromolecules , 2016 . 49 ( 14 ): 5152 DOI: 10.1021/acs.macromol.6b00785 http://doi.org/10.1021/acs.macromol.6b00785 .

K.M. Zepon , I. Otsuka , C. Bouilhac , E.C. Muniz , V. Soldi , R. Borsali . . Langmuir , 2016 . 32 ( 18 ): 4538 DOI: 10.1021/acs.langmuir.6b00212 http://doi.org/10.1021/acs.langmuir.6b00212 .

P. He , C.W. Zhao , C.S. Xiao , Z.H. Tang , X.S. Chen . . Chinese J. Polym. Sci. , 2013 . 31 ( 2 ): 318 DOI: 10.1007/s10118-013-1226-7 http://doi.org/10.1007/s10118-013-1226-7 .

J.H. Wu , Z.Y. Yang , N. Chen , W.Y. Zhu , J.L. Hong , C.G. Huang , X.M. Zhou . . J. Colloid Interf. Sci. , 2015 . 442 22 DOI: 10.1016/j.jcis.2014.11.025 http://doi.org/10.1016/j.jcis.2014.11.025 .

R. Pasquino , D. Panariello , N. Grizzuti . . J. Colloid Interf. Sci. , 2013 . 394 49 DOI: 10.1016/j.jcis.2012.11.035 http://doi.org/10.1016/j.jcis.2012.11.035 .

J.M. McMullan , N.J. Wagner . . J. Rheol. , 2009 . 53 ( 3 ): 575 DOI: 10.1122/1.3088848 http://doi.org/10.1122/1.3088848 .

H.Z. Yu , W. Jiang . . Macromolecules , 2009 . 42 ( 9 ): 3399 DOI: 10.1021/ma900107r http://doi.org/10.1021/ma900107r .

J.T. Zhu , W. Jiang . . Macromolecules , 2005 . 38 ( 22 ): 9315 DOI: 10.1021/ma051258i http://doi.org/10.1021/ma051258i .

Z.D. Wang , W. Jiang . . Chem. Phys. Lett. , 2010 . 487 ( 1-3 ): 84 DOI: 10.1016/j.cplett.2010.01.012 http://doi.org/10.1016/j.cplett.2010.01.012 .

K.Z. Zhu , R. Pamies , A.L. Kjoniksen , B. Nystrom . . Langmuir , 2008 . 24 ( 24 ): 14227 DOI: 10.1021/la8030073 http://doi.org/10.1021/la8030073 .

R. Vyhnalkova , A.H.E. Muller , A. Eisenberg . . Langmuir , 2014 . 30 ( 44 ): 13152 DOI: 10.1021/la5028527 http://doi.org/10.1021/la5028527 .

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