Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive

Ya-kun Guo; Han Li; Peng-xiang Zhao; Xiao-fang Wang; Didier Astruc; Mao-bing Shuai

doi:10.1007/s10118-017-1920-y

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Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive

Papers | Updated：2021-02-18

- Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive
- Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive
- Chinese Journal of Polymer Science 2017年35卷第6期页码：728-738
- Affiliations：
  
  a.Institute of Materials, China Academy of Engineering Physics, Jiangyou 621908, China
  b.Department of Materials, Southwest University of Science and Technology, Mianyang 621010, China
  c.Institut des Sciences Moleculaires, University Bordeaux, 351 Cours de la Liberation, Talence Cedex 33405, France
- Author bio：
  
  Mao-bing Shuai (帅茂兵), E-mail: shuaimaobing@caep.cn
- Funds：
  
  the National Natural Science Foundation of China(51573172);the National Natural Science Foundation of China(11405149);the National Natural Science Foundation of China(51401187);the Science and Technology Planning Project of Sichuan Province(SCXSDTR15001);Director's Funds of China Academy of Engineering Physics(SJZ201506)
- DOI：10.1007/s10118-017-1920-y
  中图分类号：
- 收稿：2016-11-15，
  
  修回：2016-12-8，
  
  录用：2016-12-15，
  
  纸质出版：2017-06-05
- Accepted：
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Ya-kun Guo, Han Li, Peng-xiang Zhao, 等. Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive[J]. Chinese Journal of Polymer Science, 2017,35(6):728-738.

Ya-kun Guo, Han Li, Peng-xiang Zhao, et al. Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive[J]. Chinese Journal of Polymer Science, 2017, 35(6): 728-738.
Ya-kun Guo, Han Li, Peng-xiang Zhao, 等. Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive[J]. Chinese Journal of Polymer Science, 2017,35(6):728-738. DOI： 10.1007/s10118-017-1920-y.

Ya-kun Guo, Han Li, Peng-xiang Zhao, et al. Thermo-reversible MWCNTs/Epoxy Polymer for Use in Self-healing and Recyclable Epoxy Adhesive[J]. Chinese Journal of Polymer Science, 2017, 35(6): 728-738. DOI： 10.1007/s10118-017-1920-y.

摘要

Abstract

A self-healing and recyclable carbon tube/epoxy adhesive was prepared by epoxy monomer with Diels-Alder (DA) bonds

diethylenetriamine and polyethyleneimine modified multi-wall carbon nanotubes (MWCNTs). The self-healing and recyclable ability was attained by thermally reversible Diels-Alder reaction between furan and maleimide in the epoxy monomer. By controlling the molar ratio of furfuryl glycidyl ether and 4

4'-methylenebis(

-phenylmaleimide)

the glass transition temperature and mechanical properties of MWCNTs/epoxy adhesives were varied. The self-healing properties of MWCNTs/epoxy polymers were evaluated by lap shear experiment and the results showed that the MWCNTs/epoxy adhesives exhibited enhanced mechanical properties and excellent self-healing ability under heat stimulus. The healing efficiency was related to the molecule mobility and the conversion of DA reaction between furan and maleimide. The MWCNTs/epoxy adhesives also displayed excellent recyclable ability by transforming into soluble polymer under heating. These materials offer a wide range of possibilities to produce materials with healing and recyclable ability and have the potential to bring great benefits to our daily lives by enhancing the safety

performance

and lifetime of products.

关键词

Keywords

references

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