A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities

Kun-yuan Luo; Zheng-zhong Shao

doi:10.1007/s10118-017-1910-0

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A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities

Papers | Updated：2021-02-18

- A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities
- A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities
- Chinese Journal of Polymer Science 2017年35卷第4期页码：515-523
- Affiliations：
  
  State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Advanced Materials and Department of Macromolecular Science, Fudan University, Shanghai 200433, China
- Author bio：
  
  Zheng-zhong Shao (邵正中), E-mail: zzshao@fudan.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21574024)
- DOI：10.1007/s10118-017-1910-0
  中图分类号：
- 收稿：2016-09-07，
  
  修回：2016-10-10，
  
  录用：2016-10-11，
  
  纸质出版：2017-04
- Accepted：
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Kun-yuan Luo, Zheng-zhong Shao. A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities[J]. Chinese Journal of Polymer Science, 2017,35(4):515-523.

Kun-yuan Luo, Zheng-zhong Shao. A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities[J]. Chinese Journal of Polymer Science, 2017, 35(4): 515-523.
Kun-yuan Luo, Zheng-zhong Shao. A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities[J]. Chinese Journal of Polymer Science, 2017,35(4):515-523. DOI： 10.1007/s10118-017-1910-0.

Kun-yuan Luo, Zheng-zhong Shao. A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities[J]. Chinese Journal of Polymer Science, 2017, 35(4): 515-523. DOI： 10.1007/s10118-017-1910-0.

摘要

Abstract

A simple and facile synthetic methodology for fabricating the regenerated silk fibroin (RSF)-based hydrogel which consisted of the

in situ

generated magnetic ferriferous oxide (Fe

) was developed. Using the co-precipitation of Fe

and Fe

within the RSF-based hydrogel with 90% RSF and 10% HPMC (hydroxypropyl methyl cellulose)

the as-prepared RSF/Fe

hydrogel not only showed high strength of saturation magnetization

but also exhibited excellent catalytic activities. For example

with the assistant of 3

5'-tetramethylbenzidine (TMB)

the RSF/Fe

hydrogel could detect H

at a concentration as low as 1×10

-6

mol·L

-1

. In addition

the catalytic activities were able to be maintained for a long term under various conditions. These findings suggest that the RSF-based materials can be endowed with interesting properties

and have great potential for the applications in the fields of biotechnology and environmental chemistry.

关键词

Keywords

references

A.S. Hoffman . . Adv. Drug. Deliver. Rev. , 2012 . 64 18 DOI: 10.1016/j.addr.2012.09.010 http://doi.org/10.1016/j.addr.2012.09.010 .

Q.G. Wang , Z.M. Yang , L. Wang , M.L. Ma , B. Xu . . Chem. Commun. , 2007 . ( 10 ): 1032 DOI: 10.1039/b615223f http://doi.org/10.1039/b615223f .

B. Krajewska . . Enzyme. Microb. Tech. , 2004 . 35 ( 2-3 ): 126 DOI: 10.1016/j.enzmictec.2003.12.013 http://doi.org/10.1016/j.enzmictec.2003.12.013 .

R.A. Sheldon . . Adv. Synth. Catal. , 2007 . 349 ( 8-9 ): 1289 DOI: 10.1002/(ISSN)1615-4169 http://doi.org/10.1002/(ISSN)1615-4169 .

C.X. Yang , C.H. Choi , C.S. Lee , H.M. Yi . . ACS Nano , 2013 . 7 ( 6 ): 5032 DOI: 10.1021/nn4005582 http://doi.org/10.1021/nn4005582 .

Y. Wang , R. Yan , J.Z. Zhang , W.Q. Zhang . . J. Mol. Catal. A-Chem. , 2010 . 17 ( 1-2 ): 81 .

Y.M. Mohan , T. Premkumar , K. Lee , K.E. Geckeler . . Macromol. Rapid Commun. , 2006 . 27 ( 16 ): 1346 DOI: 10.1002/(ISSN)1521-3927 http://doi.org/10.1002/(ISSN)1521-3927 .

Y. Li , L. Cao , L. Li , C. Yang . . J. Hazard. Mater. , 2015 . 289 140 DOI: 10.1016/j.jhazmat.2015.02.051 http://doi.org/10.1016/j.jhazmat.2015.02.051 .

N. Sahiner , H. Ozay , O. Ozay , N. Aktas . . Appl. Catal. B-Environ. , 2010 . 101 ( 1-2 ): 137 DOI: 10.1016/j.apcatb.2010.09.022 http://doi.org/10.1016/j.apcatb.2010.09.022 .

T.N. Narayanan , B.K. Gupta , S.A. Vithayathil , R.R. Aburto , S.A. Mani , J. Taha-Tijerina , B. Xie , B.A. Kaipparettu , S.V. Torti , P.M. Ajayan . . Adv. Mater. , 2012 . 24 ( 22 ): 2992 DOI: 10.1002/adma.v24.22 http://doi.org/10.1002/adma.v24.22 .

B. Samanta , H. Yan , N.O. Fischer , J. Shi , D.J. Jerry , V.M. Rotello . . J. Mater. Chem. , 2008 . 18 ( 11 ): 1204 DOI: 10.1039/b718745a http://doi.org/10.1039/b718745a .

Y.H. Lee , H. Lee , Y.B. Kim , J.Y. Kim , T. Hyeon , H. Park , P.B. Messersmith , T.G. Park . . Adv. Mater. , 2008 . 20 ( 21 ): 4154 .

Y. Liu , L. Zhou , Y. Hu , C.F. Guo , H.S. Qian , F.M. Zhang , X.W. Lou . . J. Mater. Chem. , 2011 . 21 ( 45 ): 18359 DOI: 10.1039/c1jm13789a http://doi.org/10.1039/c1jm13789a .

L.Z. Gao , J. Zhuang , L. Nie , J.B. Zhang , Y. Zhang , N. Gu , T.H. Wang , J. Feng , D.L. Yang , S. Perrett , X. Yan . . Nat. Nanotechnol. , 2007 . 2 ( 9 ): 577 DOI: 10.1038/nnano.2007.260 http://doi.org/10.1038/nnano.2007.260 .

W.F. Zhao , K. Odelius , U. Edlund , C.S. Zhao , A.C. Albertsson . . Biomacromolecules , 2015 . 16 ( 8 ): 2522 DOI: 10.1021/acs.biomac.5b00801 http://doi.org/10.1021/acs.biomac.5b00801 .

Y. Gao , Z. Wei , F. Li , Z.M. Yang , Y.M. Chen , M. Zrinyi , Y. Osada . . Green Chem. , 2014 . 16 ( 3 ): 1255 DOI: 10.1039/C3GC41535J http://doi.org/10.1039/C3GC41535J .

M.R. Guilherme , R.S. Oliveira , M.R. Mauricio , T.S.P. Cellet , G.M. Pereira , M.H. Kunita , E.C. Muniz , A.F. Rubira . . Soft Matter , 2012 . 8 ( 24 ): 6629 DOI: 10.1039/c2sm25638j http://doi.org/10.1039/c2sm25638j .

A.L. Daniel-da-Silva , J. Moreira , R. Neto , A.C. Estrada , A.M. Gil , T. Trindade . . Carbohyd. Polym. , 2012 . 87 ( 1 ): 328 DOI: 10.1016/j.carbpol.2011.07.051 http://doi.org/10.1016/j.carbpol.2011.07.051 .

A. Pourjavadi , S.H. Hosseini , F. Seidi , R. Soleyman . . Polym. Int. , 2013 . 62 ( 7 ): 1038 .

K. Katagiri , K. Ohta , K. Sako , K. Inumaru , K. Hayashi , Y. Sasaki , K. Akiyoshi . . ChemPlusChem , 2014 . 79 ( 11 ): 1631 DOI: 10.1002/cplu.v79.11 http://doi.org/10.1002/cplu.v79.11 .

X.F. Sun , B.C. Liu , Z.X. Jing , H.H. Wang . . Carbohyd. Polym. , 2015 . 118 16 DOI: 10.1016/j.carbpol.2014.11.013 http://doi.org/10.1016/j.carbpol.2014.11.013 .

M. Fathi , A.A. Entezami , S. Arami , M.R. Rashidi . . Int. J. Polym. Mater. Po. , 2015 . 64 ( 10 ): 541 DOI: 10.1080/00914037.2014.996703 http://doi.org/10.1080/00914037.2014.996703 .

E.P. da Silva , D.L.A. Sitta , V.H. Fragal , T.S.P. Cellet , M.R. Mauricio , F.P. Garcia , C.V. Nakamura , M.R. Guilherme , A.F. Rubira , M.H. Kunita . . Int. J. Biol. Macromol. , 2014 . 67 43 DOI: 10.1016/j.ijbiomac.2014.02.035 http://doi.org/10.1016/j.ijbiomac.2014.02.035 .

G.H. Altman , F. Diaz , C. Jakuba , T. Calabro , R.L. Horan , J.S. Chen , H. Lu , J. Richmond , D.L. Kaplan . . Biomaterials , 2003 . 24 ( 3 ): 401 DOI: 10.1016/S0142-9612(02)00353-8 http://doi.org/10.1016/S0142-9612(02)00353-8 .

Y.Z. Wang , H.J. Kim , G. Vunjak-Novakovic , D.L. Kaplan . . Biomaterials , 2006 . 27 ( 36 ): 6064 DOI: 10.1016/j.biomaterials.2006.07.008 http://doi.org/10.1016/j.biomaterials.2006.07.008 .

S.L. McNamara , J. Rnjak-Kovacina , D.F. Schmidt , T.J. Lo , D.L. Kaplan . . Biomaterials , 2014 . 35 ( 25 ): 6941 DOI: 10.1016/j.biomaterials.2014.05.013 http://doi.org/10.1016/j.biomaterials.2014.05.013 .

C. Kantipuly , S. Katragadda , A. Chow , H.D. Gesser . . Talanta , 1990 . 37 ( 5 ): 491 DOI: 10.1016/0039-9140(90)80075-Q http://doi.org/10.1016/0039-9140(90)80075-Q .

Y. Kawamura , M. Mitsuhashi , H. Tanibe , H. Yoshida . . Ind. Eng. Chem. Res. , 1993 . 32 ( 2 ): 386 DOI: 10.1021/ie00014a015 http://doi.org/10.1021/ie00014a015 .

W.S.W. Ngah , L.C. Teong , M.A.K.M. Hanafiah . . Carbohyd. Polym. , 2011 . 83 ( 4 ): 1446 DOI: 10.1016/j.carbpol.2010.11.004 http://doi.org/10.1016/j.carbpol.2010.11.004 .

H.L. Carrell , J.P. Glusker , E.A. Piercy , W.C. Stallings , D.E. Zacharias , R.L. Davis , C. Astbury , C.H.L. Kennard . . J. Am. Chem. Soc. , 1987 . 109 ( 26 ): 8067 DOI: 10.1021/ja00260a019 http://doi.org/10.1021/ja00260a019 .

Z.G. Gong , Y.H. Yang , Q.G. Ren , X. Chen , Z.Z. Shao . . Soft Matter , 2012 . 8 ( 10 ): 2875 DOI: 10.1039/c2sm06984a http://doi.org/10.1039/c2sm06984a .

K.Y. Luo , Y.H. Yang , Z.Z. Shao . . Adv. Funct. Mater. , 2016 . 26 ( 6 ): 872 DOI: 10.1002/adfm.v26.6 http://doi.org/10.1002/adfm.v26.6 .

M. Helminger , B.H. Wu , T. Kollmann , D. Benke , D. Schwahn , V. Pipich , D. Faivre , D. Zahn , H. Colfen . . Adv. Funct. Mater. , 2014 . 24 ( 21 ): 3187 DOI: 10.1002/adfm.201303547 http://doi.org/10.1002/adfm.201303547 .

O.N. Shebanova , P. Lazor . . J. Raman Spectrosc. , 2003 . 34 ( 11 ): 845 DOI: 10.1002/(ISSN)1097-4555 http://doi.org/10.1002/(ISSN)1097-4555 .

Y.L. Wang , B.Q. Li , Y. Zhou , D.C. Jia . . Nanoscale Res. Lett. , 2009 . 4 ( 9 ): 1041 DOI: 10.1007/s11671-009-9355-1 http://doi.org/10.1007/s11671-009-9355-1 .

S.K. Samal , M. Dash , T. Shelyakova , H.A. Declercq , M. Uhlarz , M. Banobre-Lopez , P. Dubruel , M. Cornelissen , T. Herrmannsdorfer , J. Rivas , G. Padeletti , S. de Smedt , K. Braeckmans , D.L. Kaplan , V.A. Dediu . . ACS Appl. Mate. Interfaces , 2015 . 7 ( 11 ): 6282 DOI: 10.1021/acsami.5b00529 http://doi.org/10.1021/acsami.5b00529 .

G.X. Chen , C.D. Qiao , Y. Wang , J.S. Yao . . Ind. Eng. Chem. Res. , 2014 . 53 ( 40 ): 15576 DOI: 10.1021/ie502709u http://doi.org/10.1021/ie502709u .

H. Wei , C.G. Chen , B.Y. Han , E.K. Wang . . Anal. Chem. , 2008 . 80 ( 18 ): 7051 DOI: 10.1021/ac801144t http://doi.org/10.1021/ac801144t .

F. He , Y.L. Tang , M.H. Yu , S. Wang , Y.L. Li , D.B. Zhu . . Adv. Funct. Mater. , 2006 . 16 ( 1 ): 91 DOI: 10.1002/(ISSN)1616-3028 http://doi.org/10.1002/(ISSN)1616-3028 .

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