Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit

Lv Wei; Wang Wen; Zhang Chun-lei; Zhao Yan; Zhen Hong-yu; Ling Qi-dan

doi:10.1007/s10118-017-1909-6

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Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit

Papers | Updated：2024-11-27

- Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit
- Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit
- Chinese Journal of Polymer Science 2017年35卷第3期页码：342-353
- Affiliations：
  
  College of Chemistry and Chemical Engineering, College of Materials Science and Engineering, Fujian Normal University, Fujian Key Laboratory of Polymer Materials, Fuzhou 350007, China
- Author bio：
  
  Wen Wang, E-mail:wangwen@fjnu.edu.cn
  Qi-dan Ling, E-mail:qdling@fjnu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21574021 and 51573026);the Natural Science Foundation of Fujian Province(2015J01189);the Program for Innovative Research Team in Science and Technology in Fujian Province (IRTSTFJ) and the Program of the Education Department of Fujian Province(JA14078)
- DOI：10.1007/s10118-017-1909-6
  中图分类号：
- 收稿：2016-07-29，
  
  修回：2016-9-28，
  
  录用：2016-9-28，
  
  纸质出版：2017-03-25
- Accepted：
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Lv Wei, Wang Wen, Zhang Chun-lei, 等. Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit[J]. Chinese Journal of Polymer Science, 2017,35(3):342-353.

Lv Wei, Wang Wen, Zhang Chun-lei, et al. Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit[J]. Chinese Journal of Polymer Science, 2017, 35(3): 342-353.
Lv Wei, Wang Wen, Zhang Chun-lei, 等. Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit[J]. Chinese Journal of Polymer Science, 2017,35(3):342-353. DOI： 10.1007/s10118-017-1909-6.

Lv Wei, Wang Wen, Zhang Chun-lei, et al. Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit[J]. Chinese Journal of Polymer Science, 2017, 35(3): 342-353. DOI： 10.1007/s10118-017-1909-6.

摘要

Abstract

A series of novel praseodymium (Pr)-bonded polymers were successfully synthesized

via

the coordination reaction and palladium-catalyzed Suzuki coupling reaction of 2

7-dibromo-9

9'-dioctylfluorene and different amounts of 5

5'-dibromo-2

2'-bipyridine. The resulting polymers were characterized by

H-NMR and GPC. The photoluminescence (PL) and electroluminescence (EL) properties of the resulting polymers were studied to explore the effects of the Pr triisopropyloxide. The results showed that the incorporation of Pr into the polymers caused better coplanarity and effective intermolecular or intramolecular interaction

leading to the higher emission intensity at long-wavelength. Further

it was also found that the emission light color could be tuned from blue to green by introduction of a small amount of Pr into the polymer main chain. A single-layer green emitting EL device based on PF(BipyPr)

with 6 mol% Pr content was fabricated. The device had a low turn-on voltage of 6 V

a brightness of 705.3 cd·m

-2

the maximum luminous efficiency of 1.53 cd·A

-1

and the maximum power efficiency of 0.69 lm·W

-1

关键词

Keywords

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