An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study

He-xin Zhang; Min-Jeong Park; Young-Kwon Moon; Eun-Bin Ko; Xue-quan Zhang; Keun-Byoung Yoon

doi:10.1007/s10118-017-1901-1

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An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study

Papers | Updated：2021-02-18

- An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study
- An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study
- Chinese Journal of Polymer Science 2017年35卷第4期页码：547-557
- Affiliations：
  
  a.Department of Polymer Science and Engineering, Kyungpook National University, Daegu 702-701, Korea
  b.Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  Keun-Byoung Yoon, E-mail:kbyoon@knu.ac.kr
- Funds：
- DOI：10.1007/s10118-017-1901-1
  中图分类号：
- 收稿：2016-09-01，
  
  修回：2016-10-17，
  
  录用：2016-10-18，
  
  纸质出版：2017-04
- Accepted：
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He-xin Zhang, Min-Jeong Park, Young-Kwon Moon, 等. An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study[J]. Chinese Journal of Polymer Science, 2017,35(4):547-557.

He-xin Zhang, Min-Jeong Park, Young-Kwon Moon, et al. An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study[J]. Chinese Journal of Polymer Science, 2017, 35(4): 547-557.
He-xin Zhang, Min-Jeong Park, Young-Kwon Moon, 等. An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study[J]. Chinese Journal of Polymer Science, 2017,35(4):547-557. DOI： 10.1007/s10118-017-1901-1.

He-xin Zhang, Min-Jeong Park, Young-Kwon Moon, et al. An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study[J]. Chinese Journal of Polymer Science, 2017, 35(4): 547-557. DOI： 10.1007/s10118-017-1901-1.

摘要

Abstract

Three types of organic compounds-two carboxylic acids and an anhydride

were used as additives for polyketone (PK). The effect of the additive structure and their feed ratios on the melting temperature

crystallization temperature

and crystallization rate of PK were studied. We found that the crystallization temperature could be reduced significantly by introducing a small quantity of organic additive

in particular

an anhydride. On addition of 1 phr of anhydride

the crystallization temperature was reduced by 10.7¦. Therefore

the non-isothermal crystallization kinetics of aliphatic PK/anhydride blends with various feed ratios was investigated using DSC. The results were analyzed by various theoretical models

such as Avrami

Ozawa and combined Avrami-Ozawa models.

关键词

Keywords

references

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