Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)

Zhao Yong; Li Guo-min; Liu Fang-fang; Dai Xue-min; Dong Zhi-xin; Qiu Xue-peng

doi:10.1007/s10118-017-1896-7

Your Location：

Home >

Browse articles >

Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)

Papers | Updated：2024-11-27

- Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)
- Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)
- Chinese Journal of Polymer Science 2017年35卷第3期页码：372-385
- Affiliations：
  
  a. Polymer Composites Engineering Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b. University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  Zhi-xin Dong(董志鑫), E-mail:zxdong@ciac.ac.cn
  Xue-peng Qiu(邱雪鹏), E-mail:xp_q@ciac.ac.cn
- Funds：
  
  the National Basic Research Program of China(2014CB643604);the National Natural Science Foundation of China(51373164)
- DOI：10.1007/s10118-017-1896-7
  中图分类号：
- 收稿：2016-07-15，
  
  修回：2016-8-23，
  
  录用：2016-9-11，
  
  纸质出版：2017-03-25
- Accepted：
Scan QR Code
Zhao Yong, Li Guo-min, Liu Fang-fang, 等. Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)[J]. Chinese Journal of Polymer Science, 2017,35(3):372-385.

Zhao Yong, Li Guo-min, Liu Fang-fang, et al. Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)[J]. Chinese Journal of Polymer Science, 2017, 35(3): 372-385.
Zhao Yong, Li Guo-min, Liu Fang-fang, 等. Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)[J]. Chinese Journal of Polymer Science, 2017,35(3):372-385. DOI： 10.1007/s10118-017-1896-7.

Zhao Yong, Li Guo-min, Liu Fang-fang, et al. Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)[J]. Chinese Journal of Polymer Science, 2017, 35(3): 372-385. DOI： 10.1007/s10118-017-1896-7.

摘要

Abstract

A series of polyamic acid copolymers (co-PAAs) containing phosphorous groups in the side chains were synthesized from[2

5-bis(4-aminophenoxy) phenyl] diphenylphosphine oxide (DATPPO) and 4

4'-oxydianiline (ODA) with 3

4'-biphenyltetracarboxylic dianhydride (

-BPDA) through the polycondensation in

'-dimethyacetamide (DMAc). The co-PAA solutions were spun into fibers by a dry-jet wet spinning process followed by thermal imidization to obtain co-polyimide (co-PI) fibers. FTIR spectra and elemental analysis confirmed the chemical structure of PI fibers. SEM results indicated that the resulting PI fibers had a smooth and dense surface

a uniform and circle-shape diameter. The thermogravimetric measurements showed that with the increase of DATPPO content

the resulting PI fibers possessed high decomposition temperature and residual char yield

indicating that the PI fibers had good thermal stability. The corresponding limiting oxygen index (LOI) values from the experiment results showed that the co-PI fibers possessed good flame-retardant property. Furthermore

the mechanical properties of the co-PI fibers were investigated systematically. When the DATPPO content increased

the tensile strength and initial modulus of the co-PI fibers decreased. However

the mechanical properties were improved by increasing the draw ratio of the fibers. When the draw ratio was up to 2.5

the tensile strength and initial modulus of the co-PI fibers reached up to 0.64 and 10.02 GPa

respectively. The WAXD results showed that the order degree of amorphous matter increased with increased stretching. In addition

the SAXS results displayed that valuably drawing the fibers could eliminate the voids inside and lead to better mechanical property. WAXD revealed that the orientation of the amorphous polymer influenced the mechanical properties of the fibers.

关键词

Keywords

references

1 Samuel, I.R. and Edgar, S.C., 1968, U.S. Pat., 3,415,782

S.Z.D. Cheng, , Z. Wu, , M. Eashoo, . . Hsu, S.L.C, Harris, F.W.Polymer , 1991 . 32 ( 10 ): 1803 .

M. Eashoo, , D. Shen, , Z. Wu, , C.J. Lee, , F.W Harris, , S.Z.D. Cheng, . . Polymer , 1993 . 34 ( 15 ): 3209 DOI: 10.1016/0032-3861(93)90392-N http://doi.org/10.1016/0032-3861(93)90392-N .

S.L. Koontz, , L.J. Leger, , J.T. Visentine, , D.E. Hunton, . . Cross, J.B, Hakes, C.L.J. Spacecraft Rockets , 1995 . 32 ( 3 ): 483 DOI: 10.2514/3.26641 http://doi.org/10.2514/3.26641 .

E. Grossman, , Y. Lifshitz, , J.T. Wolan, , C.K Mount, , G.B. Hoflund, . . J. Spacecraft Rockets , 1999 . 36 ( 1 ): 75 DOI: 10.2514/2.3435 http://doi.org/10.2514/2.3435 .

J. Dong, , C. Yin, . . Luo, W, Zhang, Q.J. Mater. Sci. , 2013 . 48 ( 21 ): 7594 .

G. Fang, , H. Li, , J. Liu, , H. Ni, , H Yang, , S. Yang, . . Chem. Lett. , 2015 . 44 ( 8 ): 1083 DOI: 10.1246/cl.150396 http://doi.org/10.1246/cl.150396 .

M. Eashoo, , Z. Wu, , A. Zhang, , D. Shen, , C. Tse, , F.W. Harris, , S.Z.D. Cheng, . . Gardner, K.H, Hsiao, B.S.Macromol. Chem. Phys. , 1994 . 195 ( 6 ): 2207 .

C. Yin, , J. Dong, , Z. Li, , Z Zhang, , Q. Zhang, . . Compos. Part B-Eng. , 2014 . 58 430 DOI: 10.1016/j.compositesb.2013.10.074 http://doi.org/10.1016/j.compositesb.2013.10.074 .

10 Shen, Z., Mu, Y., Ding, Y., Liu, Y. and Zhao, C., Study on the mechanical property of polyimide film in space radiation environments; proceedings of the Selected Proceedings of the Chinese Society for Optical Engineering Conferences held November 2015, International Society for Optics and Photonics, 2016.

K. Yokota, , S. Abe, , M. Tagawa, , M. Iwata, , E. Miyazaki, , J.I. Ishizawa, , Y Kimoto, , R. Yokota, . . High. Perform. Polym. , 2010 . 22 237 DOI: 10.1177/0954008308101535 http://doi.org/10.1177/0954008308101535 .

S.W. Duo, , M.M. Song, , T.Z. Liu, . . Hu, C.Y, Li, M.S.Key Eng. Mater. , 2012 . 492 521 .

R Liu, , J.D. Ma, . . Sichuan Text Technology (in Chinese) , 2004 . 4 47 .

X. Ding, , X. Qiu, , X. Ma, . . Li, G, Gao, L.Chemistry Journal of Chinese Universities (in Chinese) , 2013 . 34 2650 .

Y. Zhao, , T. Feng, , G. Li, , F. Liu, , X. Dai, , Z Dong, , X. Qiu, . . RSC Adv. , 2016 . 6 ( 48 ): 42482 DOI: 10.1039/C6RA02344D http://doi.org/10.1039/C6RA02344D .

P.M. Hergenrother, , K.A. Watson, , J.G. Smith, . . Connell, J.W, Yokota, R.Polymer , 2002 . 43 ( 19 ): 5077 .

17 Connell, J.W., Smith, J.G., Hergenrother, P.M., Watson, K.A. and Thompson, C.M., 2003, U.S. Pat., 7,109,287

18 Hergenrother, P.M., Smith, J.G., Connell, J.W. and Watson, K.A., 2005, U.S. Pat., 6,958,192

Krevelen, D.W. van . . Polymer , 1975 . 16 ( 8 ): 615 DOI: 10.1016/0032-3861(75)90157-3 http://doi.org/10.1016/0032-3861(75)90157-3 .

M. Zhang, , H. Niu, , Z. Lin, , S. Qi, , J. Chang, . . Ge, Q, Wu, D.Macromol. Mater. Eng. , 2015 . 300 ( 11 ): 1096 DOI: 10.1002/mame.v300.11 http://doi.org/10.1002/mame.v300.11 .

J. Chang, , H. Niu, , M. He, , M Sun, , D. Wu, . . J. Appl. Polym. Sci. , 2015 . 132 ( 34 ): 42474 .

M.E. Vickers, , N.P. Briggs, , R.N. Ibbett, . . Payne, J.J, Smith, S.B.Polymer , 2001 . 42 ( 19 ): 8241 .

J. Dong, , C. Yin, , Z. Zhang, , X. Wang, , H Li, , Q. Zhang, . . Macromol. Mater. Eng. , 2014 . 299 ( 10 ): 1170 DOI: 10.1002/mame.v299.10 http://doi.org/10.1002/mame.v299.10 .

C. Yin, , J. Dong, , D. Zhang, . . Lin, J, Zhang, Q.Eur. Polym. J. , 2015 . 67 88 DOI: 10.1016/j.eurpolymj.2015.03.028 http://doi.org/10.1016/j.eurpolymj.2015.03.028 .

C. Yin, , J. Dong, , Z. Zhang, , Q Zhang, , J., J. Polym. Sci. Lin, . . Part B: Polym. Phys. , 2015 . 53 ( 3 ): 183 DOI: 10.1002/polb.v53.3 http://doi.org/10.1002/polb.v53.3 .

26 Dong, J., Yin, C., Lin, J., Zhang, D. and Zhang, Q., RSC Adv., 2014, 4(84): 44666

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

AO-resistant Properties of Polyimide Fibers Containing Phosphorous Groups in Main Chains

Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers

Synthesis and AO Resistant Properties of Novel Polyimide Fibers Containing Phenylphosphine Oxide Groups in Main Chain

Comparison of Different Methods for Determining the Imidization Degree of Polyimide Fibers

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s