An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism

Jun-ru Chen; Juan Zhao; Bing-jia Xu; Zhi-yong Yang; Si-wei Liu; Jia-rui Xu; Yi Zhang; Yuan-chun Wu; Po-yen Lv; Zhen-guo Chi

doi:10.1007/s10118-017-1894-9

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An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism

Papers | Updated：2021-02-18

- An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism
- An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism
- Chinese Journal of Polymer Science 2017年35卷第2期页码：282-292
- Affiliations：
  
  a.Key Laboratory for Polymeric Composite & Functional Materials of Ministry of Education, Guangdong Provincial Key Laboratory for High Performance Polymer-based Composites, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, State Key Laboratory of Optoelectronic Material and Technologies, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
  b.Shenzhen China Star Optoelectronics Technology Co., Ltd, Shenzhen 518107, China
- Author bio：
  
  Zhi-yong Yang (杨志涌), E-mail:yangzhy29@mail.sysu.edu.cn
  Yi Zhang (张艺), E-mail:ceszy@mail.sysu.edu.cn
  Zhen-guo Chi (池振国), E-mail:chizhg@mail.sysu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51473185);the National Natural Science Foundation of China(51603233);the National Natural Science Foundation of China(21672267);863 Program(SS2015AA031701);the Fundamental Research Funds for the Central Universities(2015B090913003);Guangdong Science and Technology Plan(2015B090915003)
- DOI：10.1007/s10118-017-1894-9
  中图分类号：
- 收稿：2016-09-29，
  
  修回：2016-10-24，
  
  录用：2016-10-25，
  
  纸质出版：2017-02
- Accepted：
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Jun-ru Chen, Juan Zhao, Bing-jia Xu, 等. An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism[J]. Chinese Journal of Polymer Science, 2017,35(2):282-292.

Jun-ru Chen, Juan Zhao, Bing-jia Xu, et al. An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism[J]. Chinese Journal of Polymer Science, 2017, 35(2): 282-292.
Jun-ru Chen, Juan Zhao, Bing-jia Xu, 等. An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism[J]. Chinese Journal of Polymer Science, 2017,35(2):282-292. DOI： 10.1007/s10118-017-1894-9.

Jun-ru Chen, Juan Zhao, Bing-jia Xu, et al. An AEE-active Polymer Containing Tetraphenylethene and 9, 10-Distyrylanthracene Moieties with Remarkable Mechanochromism[J]. Chinese Journal of Polymer Science, 2017, 35(2): 282-292. DOI： 10.1007/s10118-017-1894-9.

摘要

Abstract

A polymer (poly (9

10-anthracenevinylene-

alt

-4

4'-(9

9-bis (4-(4'-(1

2'-triphenylvinyl) phenoxy) butyl)-9

-fluorene-2

7-diyl) dibenzaldehyde)

) was successfully synthesized through the Wittig-Horner reaction by employing fluorene and 9

10-distyrylanthracene moieties as building blocks for backbone and tetraphenylethenes as pendant groups. Photophysical and thermal properties of the resulting polymeric emitter were fully characterized by ultraviolet-visible (UV-Vis) absorption and photoluminescence (PL) spectra

thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). While

emits an orange-light centered at 567 nm in dilute tetrahydrofuran (THF) solution

the solid powder of the polymer exhibits strong yellow emission peaked at 541 nm. It is also found that the as-synthesized polymer shows unique property of aggregation-enhanced emission (AEE). In addition

possesses high thermal stability with a decomposition temperature (

) of 430℃ and high morphological stability with a glass transition temperature (

) of 171℃. Under the stimulus of mechanical force

the emission of

can be changed from yellow to red (Δ

max

=61 nm)

showing a remarkable mechanochromism. The results from XRD analysis suggest that such mechanochromic phenomenonof

is probably caused by the destruction of crystalline structure

which leads to the conformational planarization of the distyrylanthracene moieties forming by the polymerization and the increase of molecular conjugation of the backbone.

关键词

Keywords

references

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