Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers

Tao Jia; Nan-nan Zheng; Wan-qing Cai; Jie Zhang; Lei Ying; Fei Huang; Yong Cao

doi:10.1007/s10118-017-1890-0

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Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers

Papers | Updated：2021-02-18

- Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers
- Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers
- Chinese Journal of Polymer Science 2017年35卷第2期页码：269-281
- Affiliations：
  
  Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
- Author bio：
  
  Fei Huang (黄飞), E-mail:msfhuang@scut.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21490573)
- DOI：10.1007/s10118-017-1890-0
  中图分类号：
- 收稿：2016-09-30，
  
  修回：2016-11-2，
  
  录用：2016-11-3，
  
  纸质出版：2017-02
- Accepted：
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Tao Jia, Nan-nan Zheng, Wan-qing Cai, 等. Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers[J]. Chinese Journal of Polymer Science, 2017,35(2):269-281.

Tao Jia, Nan-nan Zheng, Wan-qing Cai, et al. Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers[J]. Chinese Journal of Polymer Science, 2017, 35(2): 269-281.
Tao Jia, Nan-nan Zheng, Wan-qing Cai, 等. Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers[J]. Chinese Journal of Polymer Science, 2017,35(2):269-281. DOI： 10.1007/s10118-017-1890-0.

Tao Jia, Nan-nan Zheng, Wan-qing Cai, et al. Microwave-assisted One-pot Three-component Polymerization of Alkynes, Aldehydes and Amines toward Amino-functionalized Optoelectronic Polymers[J]. Chinese Journal of Polymer Science, 2017, 35(2): 269-281. DOI： 10.1007/s10118-017-1890-0.

摘要

Abstract

We present a microwave-assisted one-pot polymerization with three-components of alkynes

aldehydes and amines for the synthesis of new amino-functionalized optoelectronic polymers. The polymerization of diynes (

)

dialdehydes (

and

) and dibenzylamine catalyzed by InCl

was carried out smoothly within 1 h under microwave radiation

yielding four soluble polymers with high molecular weights. The resulting polymers

and

could be easily dissolved in alcohol and thus utilized as the cathode interlayer for polymer solar cells (PSCs). Compared with the control device

the PSCs with

and

as the cathode interlayer and PTB7-Th:PC

BM as the photoactive layer exhibited significantly higher power conversion efficiencies (PCEs) of 9.49% and 9.16%

respectively. These results suggest that this polycoupling reaction is an efficient approach to construct three-component polymers for the practical applications.

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references

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