High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer

Kai Zhang; Xiao-yu Liu; Bo-wei Xu; Yong Cui; Ming-liang Sun; Jian-hui Hou

doi:10.1007/s10118-017-1888-7

Your Location：

Home >

Browse articles >

High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer

Papers | Updated：2021-02-18

- High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer
- High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer
- Chinese Journal of Polymer Science 2017年35卷第2期页码：219-229
- Affiliations：
  
  a.Institute of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
  b.State Key Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
- Author bio：
  
  Bo-wei Xu (许博为), E-mail:xubowei2004@iccas.ac.cn
  Ming-liang Sun (孙明亮), E-mail:mlsun@ouc.edu.cn
  Jian-hui Hou (侯剑辉), E-mail:hjhzlz@iccas.ac.cn
- Funds：
  
  the National Natural Science Foundation of China(21274134)
- DOI：10.1007/s10118-017-1888-7
  中图分类号：
- 收稿：2016-08-09，
  
  修回：2016-9-13，
  
  录用：2016-9-14，
  
  纸质出版：2017-02
- Accepted：
Scan QR Code
Kai Zhang, Xiao-yu Liu, Bo-wei Xu, 等. High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer[J]. Chinese Journal of Polymer Science, 2017,35(2):219-229.

Kai Zhang, Xiao-yu Liu, Bo-wei Xu, et al. High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer[J]. Chinese Journal of Polymer Science, 2017, 35(2): 219-229.
Kai Zhang, Xiao-yu Liu, Bo-wei Xu, 等. High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer[J]. Chinese Journal of Polymer Science, 2017,35(2):219-229. DOI： 10.1007/s10118-017-1888-7.

Kai Zhang, Xiao-yu Liu, Bo-wei Xu, et al. High-performance Fullerene-free Polymer Solar Cells with Solution-processed Conjugated Polymers as Anode Interfacial Layer[J]. Chinese Journal of Polymer Science, 2017, 35(2): 219-229. DOI： 10.1007/s10118-017-1888-7.

摘要

Abstract

A series of conjugated polymers based on PFS derivatives with

-conjugated 5-(9

-fluoren-2-yl)-2

2'-bithiophene (fluorene-

alt

-bithiophene) backbones

namely PFS-3C

PFS-4C and PFS-6C

were synthesized for their use as the anode interfacial layers (AILs) in the efficient fullerene-free polymer solar cells (PSCs). Alkyl sulfonate pendants with different lengths of alkyl side chains were introduced in the three polymers in order to investigate the effect of the alkyl chain length on the anode modification. The obtained three polymers exhibited similar absorption bands and energy levels

indicating that changing the length of the alkyl side chains did not affect the optoelectronic properties of the conjugated polymers. Based on the PBDB-T:ITIC active layer

we fabricated the fullerene-free PSCs using the three polymers as the AILs. The superior performance of the fullerene-free PSC device was achieved when PFS-4C was used as the AIL

showing a power conversion efficiency (PCE) of 10.54%. The high performance of the PFS-4C-modified device could be ascribed to the high transmittance

suitable work-function (WF) and smooth surface of PFS-4C. To the best of our knowledge

the PCE obtained in the PFS-4C-modified device is among the highest PCE values in the fullerene-free PSCs at present. These results demonstrate that the PFS derivatives are promising candidates in serving as the AIL materials for high-performance fullerene-free PSCs.

关键词

Keywords

references

C. Nielsen , S. Holliday , H. Chen , S.J. Cryer , I. McCulloch . Acc. Chem. Res. , 2015 . 48 2803 DOI: 10.1021/acs.accounts.5b00199 http://doi.org/10.1021/acs.accounts.5b00199 .

Y. Lin , Q. He , F. Zhao , L. Huo , J. Mai , X. Lu , C. Su , T. Li , J. Wang , J. Zhu , Y. Sun , C. Wang , X. Zhan . J. Am. Chem. Soc. , 2016 . 138 2973 DOI: 10.1021/jacs.6b00853 http://doi.org/10.1021/jacs.6b00853 .

L. Gao , Z. Zhang , L. Xue , J. Min , J. Zhang , Z. Wei , Y. Li . Adv. Mater. , 2016 . 28 1884 DOI: 10.1002/adma.201504629 http://doi.org/10.1002/adma.201504629 .

Y. Lin , J. Wang , Z. Zhang , H. Bai , Y. Li , D. Zhu , X. Zhan . Adv. Mater. , 2015 . 27 1170 DOI: 10.1002/adma.201404317 http://doi.org/10.1002/adma.201404317 .

D. Meng , D. Sun , C. Zhong , T. Liu , B. Fan , L. Huo , Y. Li , W. Jiang , H. Choi , T. Kim , J.Y. Kim , Y. Sun , Z. Wang , A.J. Heeger . J. Am. Chem. Soc. , 2016 . 138 375 DOI: 10.1021/jacs.5b11149 http://doi.org/10.1021/jacs.5b11149 .

L. Gao , Z. Zhang , H. Bin , L. Xue , Y. Yang , C. Wang , F. Liu , T.P. Russell , Y. Li . Adv. Mater. , 2016 . DOI: 10.1002/adma.201601595 http://doi.org/10.1002/adma.201601595 .

L. Ye , X. Jiao , M. Zhou , S. Zhang , H. Yao , W. Zhao , A. Xia , H. Ade , J. Hou . Adv. Mater. , 2015 . 27 6046 DOI: 10.1002/adma.201503218 http://doi.org/10.1002/adma.201503218 .

S. Shi , J. Yuan , G. Ding , M. Ford , K. Lu , G. Shi , J. Sun , X. Ling , Y. Li , W. Ma . Adv. Funct. Mater. , 2016 . DOI: 10.1002/adfm.201601037 http://doi.org/10.1002/adfm.201601037 .

S. Zhang , Y. Qin , M.A. Uddin , B. Jang , W. Zhao , D. Liu , H.Y. Woo , J. Hou . Macromolecules , 2016 . 49 2993 DOI: 10.1021/acs.macromol.6b00248 http://doi.org/10.1021/acs.macromol.6b00248 .

H. Yao , Y. Chen , Y. Qin , R. Yu , Y. Cui , B. Yang , S. Li , K. Zhang , J. Hou . Adv. Mater. , 2016 . DOI: 10.1002/adma.201602642 http://doi.org/10.1002/adma.201602642 .

W. Zhao , D. Qian , S. Zhang , S. Li , O. Inganäs , F. Gao , J. Hou . Adv. Mater. , 2016 . 28 4734 DOI: 10.1002/adma.v28.23 http://doi.org/10.1002/adma.v28.23 .

Z. Wu , C. Sun , S. Dong , X. Jiang , S. Wu , H. Wu , H.L. Yip , F. Huang , Y. Cao . J. Am. Chem. Soc. , 2016 . 138 2004 DOI: 10.1021/jacs.5b12664 http://doi.org/10.1021/jacs.5b12664 .

H. Wu , F. Huang , T. Mo , W. Yang , D. Wang , J. Peng , Y. Cao . Adv. Mater. , 2004 . 16 1826 .

S. Liu , K. Zhang , J. Lu , J. Zhang , H.L. Yip , F. Huang , Y. Cao . J. Am. Chem. Soc. , 2013 . 135 15326 DOI: 10.1021/ja408363c http://doi.org/10.1021/ja408363c .

H. Zhou , Y. Zhang , C.K. Mai , S.D. Collins , G.C. Bazan , T. Nguyen , A.J. Heeger . Adv. Mater. , 2015 . 27 1767 DOI: 10.1002/adma.201404220 http://doi.org/10.1002/adma.201404220 .

C.K. Mai , R.A. Schlitz , G.M. Su , D. Spitzer , X. Wang , S.L. Fronk , D.G. Cahill , M.L. Chabinyc , G.C. Bazan . J. Am. Chem. Soc. , 2014 . 136 13478 DOI: 10.1021/ja504284r http://doi.org/10.1021/ja504284r .

B.H. Lee , J.H. Lee , S.Y. Jeong , S.B. Park , S.H. Lee , K. Lee . Adv. Energy Mater. , 2015 . 5 1401653 DOI: 10.1002/aenm.201401653 http://doi.org/10.1002/aenm.201401653 .

K. Yao , L. Chen , X. Chen , Y. Chen . Chem. Mater. , 2013 . 25 897 DOI: 10.1021/cm400297p http://doi.org/10.1021/cm400297p .

H. Park , J. Kong . Adv. Energy Mater. , 2014 . 4 1301280 DOI: 10.1002/aenm.201301280 http://doi.org/10.1002/aenm.201301280 .

T. Yuan , D. Yang , X. Zhu , L. Zhou , J. Zhang , G. Tu , C. Li . RSC Adv. , 2014 . 4 50988 DOI: 10.1039/C4RA08904A http://doi.org/10.1039/C4RA08904A .

F. Huang , X. Wang , D. Wang , W. Yang , Y. Cao . Polymer , 2005 . 46 12010 DOI: 10.1016/j.polymer.2005.10.034 http://doi.org/10.1016/j.polymer.2005.10.034 .

H. Zhou , Y. Zhang , C.K. Mai , J. Seifter , T. Nguyen , G.C. Bazan , A.J. Heeger . ACS Nano , 2015 . 9 371 DOI: 10.1021/nn505378m http://doi.org/10.1021/nn505378m .

C.K. Mai , H. Zhou , Y. Zhang , Z.B. Henson , T.Q. Nguyen , A.J. Heeger , G.C. Bazan . Angew. Chem. Int. Ed. , 2013 . 52 12874 DOI: 10.1002/anie.201307667 http://doi.org/10.1002/anie.201307667 .

H. Zhou , Y. Zhang , C.K. Mai , S.D. Collins , T.Q. Nguyen , G.C. Bazan , A.J. Heeger . Adv. Mater. , 2014 . 26 780 DOI: 10.1002/adma.201302845 http://doi.org/10.1002/adma.201302845 .

B. Xu , Z. Zheng , K. Zhao , J. Hou . Adv. Mater. , 2016 . 28 434 DOI: 10.1002/adma.v28.3 http://doi.org/10.1002/adma.v28.3 .

J. Hannedouche , G. Clarkson , M. Wills . J. Am. Chem. Soc. , 2004 . 126 986 DOI: 10.1021/ja0392768 http://doi.org/10.1021/ja0392768 .

D. Stay , M.C. Lonergan . Macromolecules , 2013 . 46 4361 DOI: 10.1021/ma4004693 http://doi.org/10.1021/ma4004693 .

Y. Li , Y. Cao , J. Gao , D. Wang , G. Yu , A.J. Heeger . Synthetic Met. , 1999 . 99 243 DOI: 10.1016/S0379-6779(99)00007-7 http://doi.org/10.1016/S0379-6779(99)00007-7 .

F. Wang , Q. Xu , Z. Tan , L. Li , S. Li , X. Hou , G. Sun , X. Tu , J. Hou , Y. Li . J. Mater. Chem. A , 2014 . 2 1318 DOI: 10.1039/C3TA13680A http://doi.org/10.1039/C3TA13680A .

D. Qian , L. Ye , M. Zhang , Y. Liang , L. Li , Y. Huang , X. Guo , S. Zhang , Z. Tan , J. Hou . Macromolecules , 2012 . 45 9611 DOI: 10.1021/ma301900h http://doi.org/10.1021/ma301900h .

B. Meng , Z. Wang , W. Ma , Z. Xie , J. Liu , L. Wang . Adv. Funct. Mater. , 2016 . 26 226 DOI: 10.1002/adfm.v26.2 http://doi.org/10.1002/adfm.v26.2 .

Q. Xu , F. Wang , Z. Tan , L. Li , S. Li , X. Hou , G. Sun , X. Tu , J. Hou , Y. Li . ACS Appl. Mater. Interfaces , 2013 . 5 10658 DOI: 10.1021/am402745t http://doi.org/10.1021/am402745t .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

A Bisphosphonic Acid-functionalized Carbazole for Dual Hydrophilic Interfaces toward Efficient and Stable Organic Solar Cells

Polymerizing Ladder-type Heteroheptacene-Cored Small-Molecule Acceptors for Efficient All-Polymer Solar Cells

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate