Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis <italic style="font-style: italic">via</italic> Transesterification Process

Zi-qing Wang; Yuan-sheng Bai; Wei Jiang; Xian-gui Yang; Shao-ying Liu; Gong-ying Wang

doi:10.1007/s10118-017-1887-8

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Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process

PAPERS | Updated：2021-02-18

- Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process
- Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process
- Chinese Journal of Polymer Science 2017年35卷第1期页码：130-140
- Affiliations：
  
  a.Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
  c.Changzhou Institute of Chemistry, Changzhou 213164, China
- Author bio：
  
  Gong-ying Wang, E-mail:gywang@cioc.ac.cn, wanggongying1102@126.com
- Funds：
  
  the National Key Technology Pillar Program(2013BAC11B05);Key Research and Innovation Program of Jiangsu Province(BE2015055);the Science&Technology Pillar Program in Sichuan Province(2016GZ0228)
- DOI：10.1007/s10118-017-1887-8
  中图分类号：
- 收稿：2016-08-19，
  
  修回：2016-9-5，
  
  录用：2016-9-11，
  
  纸质出版：2017-01
- Accepted：
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Zi-qing Wang, Yuan-sheng Bai, Wei Jiang, 等. Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process[J]. Chinese Journal of Polymer Science, 2017,35(1):130-140. DOI: 10.1007/s10118-017-1887-8.

Zi-qing Wang, Yuan-sheng Bai, Wei Jiang, et al. Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process[J]. Chinese Journal of Polymer Science, 2017, 35(1): 130-140. DOI: 10.1007/s10118-017-1887-8.
Zi-qing Wang, Yuan-sheng Bai, Wei Jiang, 等. Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process[J]. Chinese Journal of Polymer Science, 2017,35(1):130-140. DOI: 10.1007/s10118-017-1887-8. DOI：

Zi-qing Wang, Yuan-sheng Bai, Wei Jiang, et al. Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process[J]. Chinese Journal of Polymer Science, 2017, 35(1): 130-140. DOI: 10.1007/s10118-017-1887-8. DOI：

摘要

Abstract

Mg-Al mixed oxides with different Mg/Al molar ratio were prepared by thermal decomposition of hydrotalcite-like precursors at 500℃ for 5.0 h and used as catalysts for the transesterification of diphenyl carbonate with 1

4-butanediol to synthesize high-molecular-weight poly(butylene carbonate) (PBC). The structure-activity correlations of these catalysts in this transesterification process were discussed by means of various characterization techniques. It was found that the chain growth for the formation of PBC can only be obtained through connecting-OH and-OC(C) OC

end-group upon removing the generated phenol

and the sample with Mg/Al molar ratio of 4.0 exhibited the best catalytic performance

giving PBC with

of 1.64×10

g/mol at 210℃ for 3.0 h. This excellent activity depended mainly on the specific surface area and basicity rather than pore structure or crystallite size of MgO.

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Y. Liu, , en R , M. W. , Zhang , P. W. , R.R. Zhao, , u L , B. X. . . Nat. Commun. , 2015 . 6 8594 DOI: 10.1038/ncomms9594 http://doi.org/10.1038/ncomms9594 .

Y.S. Qin, , X.H. Wang, , F.S. Wang, . . Prog. Chem. , 2011 . 23 ( 4 ): 613 .

D.D. Wu, , W. Li, , Y. Zhao, , Y.J. Deng, , H.L. Zhang, , L.S. Dong, . . Chinese J. Polym. Sci. , 2015 . 33 ( 3 ): 444 DOI: 10.1007/s10118-015-1597-z http://doi.org/10.1007/s10118-015-1597-z .

hu Z , X. W. , X. Huang, , C.C. Li, , Y.N. Xiao, , D. Zhang, , G.H. Guan, . . Polym. Int. , 2011 . 60 1060 DOI: 10.1002/pi.v60.7 http://doi.org/10.1002/pi.v60.7 .

Y.S. Qin, , L.J. Chen, , X.H. Wang, , X.J. Zhao, , F.S. Wang, . . Chinese J. Polym. Sci. , 2011 . 29 ( 5 ): 602 DOI: 10.1007/s10118-011-1073-3 http://doi.org/10.1007/s10118-011-1073-3 .

C. Obuah, , Y. Lochee, , O. Zinyemba, , J.H.L. Jordaan, , D.P. Otto, , J. Darkwa, . . J. Mol. Catal. A-Chem. , 2015 . 406 185 DOI: 10.1016/j.molcata.2015.05.021 http://doi.org/10.1016/j.molcata.2015.05.021 .

W.X. Zhu, , W. Zhou, , C.C. Li, , Y.N. Xiao, , D. Zhang, , G.H. Guan, , D.J., J. Macromol. Sci. Wang, . . Pure. Appl. Chem. , 2011 . 48 583 .

H. Park, , J.Y. Jeon, , J.J. Lee, , Y. Jang, , J.K. Varghese, , B.Y. Lee, . . Macromolecules , 2013 . 46 3301 DOI: 10.1021/ma400360w http://doi.org/10.1021/ma400360w .

F. Liu, , X.G. Yang, , J.G. Li, , S.Y. Liu, , J. Yao, , T. Chen, , G.Y. Wang, . . Acta Polymerica Sinica (in Chinese) , 2014 . ( 5 ): 628 .

C. Liu, , S.K. Zhang, , B.Y. Cai, , Z.L. Jin, . . Chin. J. Catal. , 2015 . 36 1136 DOI: 10.1016/S1872-2067(14)60309-0 http://doi.org/10.1016/S1872-2067(14)60309-0 .

Y. Yuan, , Z.M. Wang, , H.L. An, , W. Xue, , Y.J. Wang, . . Chin. J. Catal. , 2015 . 36 1142 DOI: 10.1016/S1872-2067(14)60312-0 http://doi.org/10.1016/S1872-2067(14)60312-0 .

Z.Q. Wang, , X.G. Yang, , S.Y. Liu, , J. Hu, , H. Zhang, , G.Y. Wang, . . RSC Adv. , 2015 . 5 87311 DOI: 10.1039/C5RA18275A http://doi.org/10.1039/C5RA18275A .

Z.Q. Wang, , X.G. Yang, , S.Y. Liu, , J. Hu, , G.Y. Wang, . . Acta Polymerica Sinica (in Chinese) , 2016 . ( 12 ): 1654 .

Z.Q. Wang, , X.G. Yang, , S.Y. Liu, , H. Zhang, , G.Y. Wang, . . Chem. Res. Chinese U. , 2016 . 32 512 DOI: 10.1007/s40242-016-5381-6 http://doi.org/10.1007/s40242-016-5381-6 .

M. Yin, , C.C. Li, , G.H. Guan, , D. Zhang, , Y.N. Xiao, . . J. Appl. Polym Sci. , 2010 . 115 2470 DOI: 10.1002/app.v115:4 http://doi.org/10.1002/app.v115:4 .

Y.X. Feng, , N. Yin, , Q.F. Li, , J.W. Wang, , M.Q. Kang, , X.K. Wang, . . Catal. Lett. , 2008 . 121 97 DOI: 10.1007/s10562-007-9302-7 http://doi.org/10.1007/s10562-007-9302-7 .

Z.Q. Wang, , X.G. Yang, , S.Y. Liu, , J.G. Li, , G.Y. Wang, . . J. Mol. Catal. A-Chem. , 2016 . 424 77 DOI: 10.1016/j.molcata.2016.08.017 http://doi.org/10.1016/j.molcata.2016.08.017 .

J. Zhang, , W.X. Zhu, , C.C. Li, , D. Zhang, , Y.N. Xiao, , G.H. Guan, , L.C. Zheng, . . RSC Adv. , 2015 . 5 2213 DOI: 10.1039/C4RA10466H http://doi.org/10.1039/C4RA10466H .

H.M. Zhao, , M.J. Jiang, , H.S. Tian, . . Acta Polymerica Sinica (in Chinese) , 2011 . ( 1 ): 192 .

Q. Li, , W.X. Zhu, , C.C. Li, , G.H. Guan, , D. Zhang, , Y.N. Xiao, , L.C., J. Polym. Sci. Zheng, . . Part A:Polym. Chem. , 2013 . 51 1387 DOI: 10.1002/pola.26507 http://doi.org/10.1002/pola.26507 .

K. Nakano, , R. Fujie, , R. Shintani, , K. Nozaki, . . Chem. Commun. , 2013 . 49 9332 DOI: 10.1039/c3cc45622f http://doi.org/10.1039/c3cc45622f .

L.P. Zheng, , S.X. Xia, , Z.T. Hou, , M.Y. Zhang, , Z.Y. Hou, . . Chin. J. Catal. , 2014 . 35 310 DOI: 10.1016/S1872-2067(12)60738-4 http://doi.org/10.1016/S1872-2067(12)60738-4 .

Z.M. Liu, , J.W. Wang, , M.Q. Kang, , N. Yin, , X.K. Wang, , Y.S. Tan, , Y.L. Zhu, . . J. Ind. Eng. Chem. , 2015 . 21 394 DOI: 10.1016/j.jiec.2014.02.051 http://doi.org/10.1016/j.jiec.2014.02.051 .

Serio, M. Di , R. Tesser, , A. Ferrara, , E. Santacesaria, . . J. Mole. Catal. A-Chem. , 2004 . 212 251 DOI: 10.1016/j.molcata.2003.10.032 http://doi.org/10.1016/j.molcata.2003.10.032 .

Y.X. Feng, , N. Yin, , Q.F. Li, , J.W. Wang, , M.Q. Kang, , X.K. Wang, . . Ind. Eng. Chem. Res. , 2008 . 47 ( 7 ): 2140 DOI: 10.1021/ie070759k http://doi.org/10.1021/ie070759k .

G.F. Li, , W.H. Luo, , M. Xiao, , S.J. Wang, , Y.Z. Meng, . . Chinese J. Polym. Sci. , 2016 . 34 ( 3 ): 13 .

hu Z , X. W. , C.C. Li, , Y.N. Xiao, , B. Zhang, , L.C. Zheng, . . Petrochemical Technology (in Chinese) , 2016 . 45 257 .

Z.Z. Jiang, , C. Liu, , W.C. Xie, , R.A. Gross, . . Macromolecules , 2008 . 41 4671 DOI: 10.1021/ma702868a http://doi.org/10.1021/ma702868a .

H.R. Prakruthi, , Prakash, B.S. Jai , Y.S. Bhat, . . J. Mol. Catal. A-Chem. , 2015 . 408 214 DOI: 10.1016/j.molcata.2015.07.036 http://doi.org/10.1016/j.molcata.2015.07.036 .

M. Hájek, , P. Kutálek, , L. Smoláková, , I. Troppová, , L. Čapek, , D. Kubička, , J. Kocík, , D.N. Thanh, . . Chem. Eng. J. , 2015 . 263 160 DOI: 10.1016/j.cej.2014.11.006 http://doi.org/10.1016/j.cej.2014.11.006 .

Q.H. Liu, , B.C. Wang, , C.X. Wang, , Z.J. Tian, , W. Qu, , H.J. Ma, , R.S. Xu, . . Green Chem. , 2014 . 16 2604 DOI: 10.1039/c3gc42648c http://doi.org/10.1039/c3gc42648c .

Pérez, C. Noda , C.A. Pérez, , C.A. Henriques, , J.L.F. Monteiro, . . Appl. Catal. A-Gen. , 2004 . 272 229 DOI: 10.1016/j.apcata.2004.05.045 http://doi.org/10.1016/j.apcata.2004.05.045 .

Cosimo, J.I. Di , V.K. Diez, , M. Xu, , E. Iglesia, , C.R. Apesteguia, . . J. Catal. , 1998 . 178 499 DOI: 10.1006/jcat.1998.2161 http://doi.org/10.1006/jcat.1998.2161 .

L. Capek, , P. Kutalek, , L. Smolakova, , M. Hajek, , I. Troppova, , D. Kubicka, . . Top. Catal. , 2013 . 56 586 DOI: 10.1007/s11244-013-0008-3 http://doi.org/10.1007/s11244-013-0008-3 .

F.S.H. Simanjuntak, , T.K. Kim, , S.D. Lee, , B.S. Ahn, , H.S. Kim, , H. Lee, . . Appl. Catal. A-Gen , 2011 . 401 220 DOI: 10.1016/j.apcata.2011.05.024 http://doi.org/10.1016/j.apcata.2011.05.024 .

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Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process

Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process

DOI：10.1007/s10118-017-1887-8

摘要

Abstract

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