Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films

Wei Wan-chu; Feng Shuo; Zheng Cai-xia; Liang Guo-dong; Zhu Fang-ming

doi:10.1007/s10118-017-1884-y

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Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films

Papers | Updated：2024-11-27

- Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films
- Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films
- Chinese Journal of Polymer Science 2017年35卷第3期页码：400-406
- Affiliations：
  
  a. Guangdong Provincial Key Laboratory for High Performance Polymeric Composites, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
  b. Key Laboratory for Polymer Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
- Author bio：
  
  Fang-ming Zhu(祝方明), E-mail:ceszfm@mail.sysu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21174167 and 51573212);the Natural Science Foundation of Guangdong Province(S2013030013474 and 2014A030313178)
- DOI：10.1007/s10118-017-1884-y
  中图分类号：
- 收稿：2016-08-20，
  
  修回：2016-9-20，
  
  录用：2016-9-28，
  
  纸质出版：2017-03-25
- Accepted：
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Wei Wan-chu, Feng Shuo, Zheng Cai-xia, 等. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films[J]. Chinese Journal of Polymer Science, 2017,35(3):400-406.

Wei Wan-chu, Feng Shuo, Zheng Cai-xia, et al. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films[J]. Chinese Journal of Polymer Science, 2017, 35(3): 400-406.
Wei Wan-chu, Feng Shuo, Zheng Cai-xia, 等. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films[J]. Chinese Journal of Polymer Science, 2017,35(3):400-406. DOI： 10.1007/s10118-017-1884-y.

Wei Wan-chu, Feng Shuo, Zheng Cai-xia, et al. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films[J]. Chinese Journal of Polymer Science, 2017, 35(3): 400-406. DOI： 10.1007/s10118-017-1884-y.

摘要

Abstract

The fluorescently labelled polymers including pyrene-labelled polystyrene (PyPS) and pyrene-labelled poly(methyl methacrylate) (PyPMMA) with narrow molecular weight distributions were synthesized by the atom transfer radical copolymerization (ATRCP) of styrene or methyl methacrylate with 1-pyrenemethyl methacrylate (PyMMA). The ultrathin PyPS and PyPMMA films with the thickness ranging from 30 nm to 400 nm supported on the quartz slides were prepared by spin-coating. The fluorescent quantum yield (QY) of the pyrene probe in the ultrathin polymer films was investigated by the photoluminescence spectrometer using an integrating sphere detector. The QY decreased with the reduction of film thickness in the sub-200 nm range.

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