Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation

Xiao-peng Xu; Guang-jun Zhang; Yun-zhe Zhao; Jiang Liu; Ying Li; Qiang Peng

doi:10.1007/s10118-017-1877-x

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Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation

Papers | Updated：2021-02-18

- Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation
- Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation
- Chinese Journal of Polymer Science 2017年35卷第2期页码：249-260
- Affiliations：
  
  a.Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610064, China
  b.Chengdu Green Energy and Green Manufacturing Technology R & D Center, Chengdu 610207, China
- Author bio：
  
  Jiang Liu (刘江), E-mail:546jiang@163.com
  Qiang Peng (彭强), E-mail:qiangpengjohnny@yahoo.com
- Funds：
  
  the National Natural Science Foundation of China(51573107);the National Natural Science Foundation of China(21432005);the Youth Science and Technology Foundation of Sichuan Province(2013JQ0032);the Foundation of State Key Laboratory of Polymer Materials Engineering(sklpme2014-3-05);the Synergistic Innovation Joint Foundation of CAEP-SCU(XTCX2014008);the Fundamental Research Funds for the Central Universities(2012SCU04B01);the Fundamental Research Funds for the Central Universities(YJ2011025)
- DOI：10.1007/s10118-017-1877-x
  中图分类号：
- 收稿：2016-08-20，
  
  修回：2016-9-18，
  
  录用：2016-9-20，
  
  纸质出版：2017-02
- Accepted：
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Xiao-peng Xu, Guang-jun Zhang, Yun-zhe Zhao, 等. Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation[J]. Chinese Journal of Polymer Science, 2017,35(2):249-260.

Xiao-peng Xu, Guang-jun Zhang, Yun-zhe Zhao, et al. Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation[J]. Chinese Journal of Polymer Science, 2017, 35(2): 249-260.
Xiao-peng Xu, Guang-jun Zhang, Yun-zhe Zhao, 等. Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation[J]. Chinese Journal of Polymer Science, 2017,35(2):249-260. DOI： 10.1007/s10118-017-1877-x.

Xiao-peng Xu, Guang-jun Zhang, Yun-zhe Zhao, et al. Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced Absorption and Molecular Aggregation[J]. Chinese Journal of Polymer Science, 2017, 35(2): 249-260. DOI： 10.1007/s10118-017-1877-x.

摘要

Abstract

A series of copolymers

based on benzo[1

2-b:4

5-b']dithiophene (BDT) as the electron donor and 2

3-benzothiadiazole (BT)/diketopyrrolo[3

4-c]

pyrrole (DPP) as the electron acceptors

were synthesized for highly efficient polymer solar cells. By changing the BT/DPP ratio in the conjugated backbone

the absorption

energy levels

molecular aggregation and carrier mobility could be finely tuned. With increased DPP content

the absorption range was extended to the longer wavelength region with narrower bandgaps. The highest occupied molecular orbital (HOMO) levels were also raised up and the molecular aggregation was enhanced. The balance of these factors would afford a remarkable device performance enhancement. Polymer P3 with BT:DPP=0.7:0.3 (molar ratio) exhibited the highest power conversion efficiency (PCE) of 9.01%

with open circuit voltage (

)=0.73 V

short current density (

)=18.45 mA·cm

-2

and fill factor (FF)=66.9%. The PCE value was improved by 48.7% compared to P1 and by 117.6% compared to P7

respectively

indicating a great potential in photovoltaic application.

关键词

Keywords

references

J.W. Chen , Y. Cao . Acc. Chem. Res. , 2009 . 42 1709 DOI: 10.1021/ar900061z http://doi.org/10.1021/ar900061z .

L.Y. Lu , L.P. Yu . Adv. Mater. , 2014 . 26 4413 DOI: 10.1002/adma.v26.26 http://doi.org/10.1002/adma.v26.26 .

B.C. Thompson , J.M.J. Fréchet . Angew. Chem. Int. Ed. , 2008 . 47 58 DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

Y.F. Li . Acc. Chem. Res. , 2012 . 45 723 DOI: 10.1021/ar2002446 http://doi.org/10.1021/ar2002446 .

J.B. Zhao , Y. Li , G.F. Yang , K. Jiang , H.R. Lin , H. Ade , W. Ma , H. Yan . Nat. Energy , 2016 . 1 15027 DOI: 10.1038/nenergy.2015.27 http://doi.org/10.1038/nenergy.2015.27 .

Y. Yang , W. Chen , L.T. Dou , W.H. Chang , H.S. Duan , B. Bob , G. Li , Y. Yang . Nat. Photon. , 2015 . 9 190 DOI: 10.1038/nphoton.2015.9 http://doi.org/10.1038/nphoton.2015.9 .

J.M. Jiang , H.C. Chen , H.K. Lin , C.M. Yu , S.C. Lan , C.M. Liu , K.H. Wei . Polym. Chem. , 2013 . 4 5321 DOI: 10.1039/c3py00132f http://doi.org/10.1039/c3py00132f .

K. Li , Z.J. Li , K. Feng , X.P. Xu , L.Y. Wang , Q. Peng . J. Am. Chem. Soc. , 2013 . 135 13549 DOI: 10.1021/ja406220a http://doi.org/10.1021/ja406220a .

J.Y. Kim , K. Lee , N.E. Coates , D. Moses , T.Q. Nguyen , M. Dante , A.J. Heeger . Science , 2007 . 317 222 DOI: 10.1126/science.1141711 http://doi.org/10.1126/science.1141711 .

A.R.B.M. Yusoff , D. Kim , H.P. Kim , F.K. Shneider , W.J. Da Silva , J. Jang . Energy Environ. Sci. , 2015 . 8 303 DOI: 10.1039/C4EE03048F http://doi.org/10.1039/C4EE03048F .

Z. Zheng , S.Q. Zhang , M.J. Zhang , K. Zhao , L. Ye , Y. Chen , B. Yang , J.H. Hou . Adv. Mater. , 2015 . 27 1189 DOI: 10.1002/adma.201404525 http://doi.org/10.1002/adma.201404525 .

K. Zhang , K. Gao , R. Xia , Z. Wu , C. Sun , J. Cao , L. Qian , W. Li , S. Liu , F. Huang , X. Peng , L. Ding , H.L. Yip , Y. Cao . Adv. Mater. , 2016 . 28 4817 DOI: 10.1002/adma.v28.24 http://doi.org/10.1002/adma.v28.24 .

J.W. Jung , F. Liu , T.P. Russell , W.H. Jo . Energy Environ. Sci. , 2013 . 6 3301 DOI: 10.1039/c3ee40689j http://doi.org/10.1039/c3ee40689j .

S.H. Liu , P. You , J. Li , J. Li , C.S. Lee , B.S. Ong , C. Surya , F. Yan . Energy Environ. Sci. , 2015 . 8 1463 DOI: 10.1039/C5EE00090D http://doi.org/10.1039/C5EE00090D .

L.Y. Lu , T. Xu , W. Chen , E.S. Landry , L.P. Yu . Nat. Photon. , 2014 . 8 716 DOI: 10.1038/nphoton.2014.172 http://doi.org/10.1038/nphoton.2014.172 .

L.Y. Lu , W. Chen , T. Xu , L.P. Yu . Nat. Commun. , 2015 . 6 7327 DOI: 10.1038/ncomms8327 http://doi.org/10.1038/ncomms8327 .

X.P. Xu , Z.J. Li , Z.G. Wang , K. Li , K. Feng , Q. Peng . Nano Energy , 2016 . 25 170 DOI: 10.1016/j.nanoen.2016.04.048 http://doi.org/10.1016/j.nanoen.2016.04.048 .

N. Gasparini , M. Salvador , S. Fladischer , A. Katsouras , A. Avgeropoulos , E. Spiecker , C.L. Chochos , C.J. Brabec , T. Ameri . Adv. Energy Mater. , 2015 . 5 1501527 DOI: 10.1002/aenm.201501527 http://doi.org/10.1002/aenm.201501527 .

P. Cheng , Y.F. Li , X.W. Zhan . Energy Environ. Sci. , 2014 . 7 2005 DOI: 10.1039/c3ee44202k http://doi.org/10.1039/c3ee44202k .

J. Zhang , Y. Zhang , J. Fang , K. Lu , Z. Wang , W. Ma , Z. Wei . J. Am. Chem. Soc. , 2015 . 137 8176 DOI: 10.1021/jacs.5b03449 http://doi.org/10.1021/jacs.5b03449 .

Q.S. An , F.J. Zhang , Q.Q. Sun , M. Zhang , J. Zhang , W.H. Tang , X.X. Yin , Z.B. Deng . Nano Energy , 2016 . 26 180 DOI: 10.1016/j.nanoen.2016.05.018 http://doi.org/10.1016/j.nanoen.2016.05.018 .

V. Tamilavan , K.H. Roh , R. Agneeswari , D.Y. Lee , S. Cho , Y. Jin , S.H. Park , M.H. Hyun . J. Mater. Chem. A , 2014 . 2 20126 DOI: 10.1039/C4TA05086J http://doi.org/10.1039/C4TA05086J .

Y.S. Huang , M. Zhang , H.J. Chen , F. Wu , Z.C. Cao , L.J. Zhang , S.T. Tan . J. Mater. Chem. A , 2014 . 2 5218 DOI: 10.1039/c4ta00020j http://doi.org/10.1039/c4ta00020j .

T.E. Kang , K.H. Kim , B.J. Kim . J. Mater. Chem. A , 2014 . 2 15252 DOI: 10.1039/C4TA02426E http://doi.org/10.1039/C4TA02426E .

H. Tan , J.T. Yu , Y.F. Wang , J.H. Chen , Q. Tao , Y. Liu , J. Huang , W.G. Zhu . Org. Electron. , 2013 . 14 1510 DOI: 10.1016/j.orgel.2013.03.018 http://doi.org/10.1016/j.orgel.2013.03.018 .

Q.P. Fan , Y. Liu , M.J. Xiao , W.Y. Su , H.S. Gao , J.H. Chen , H. Tan , Y.F. Wang , R.Q. Yang , W.G. Zhu . J. Mater. Chem. C , 2015 . 3 6240 DOI: 10.1039/C5TC00785B http://doi.org/10.1039/C5TC00785B .

H.F. Yao , L. Ye , H. Zhang , S.S. Li , S.Q. Zhang , J.H. Hou . Chem. Rev. , 2016 . 116 7397 DOI: 10.1021/acs.chemrev.6b00176 http://doi.org/10.1021/acs.chemrev.6b00176 .

P. Liu , K. Zhang , F. Liu , Y.C. Jin , S.J. Liu , T.P. Russell , H.L. Yip , F. Huang , Y. Cao . Chem. Mater. , 2014 . 26 3009 DOI: 10.1021/cm500953e http://doi.org/10.1021/cm500953e .

K.H. Hendriks , G.H. Heintges , V.S. Gevaerts , M.M. Wienk , R.A. Janssen . Angew. Chem. Int. Ed. , 2013 . 52 8341 DOI: 10.1002/anie.v52.32 http://doi.org/10.1002/anie.v52.32 .

T. Jiang , J. Yang , Y.T. Tao , C. Fan , L.W. Xue , Z.G. Zhang , H. Li , Y.F. Li , W. Huang . Polym. Chem. , 2016 . 7 926 DOI: 10.1039/C5PY01771H http://doi.org/10.1039/C5PY01771H .

W.H. Chang , J. Gao , L.T. Dou , C.C. Chen , Y.S. Liu , Y. Yang . Adv. Energy Mater. , 2014 . 4 1300864 DOI: 10.1002/aenm.201300864 http://doi.org/10.1002/aenm.201300864 .

J.W. Lee , H. Ahn , W. H. Jo . Macromolecules , 2015 . 48 7836 DOI: 10.1021/acs.macromol.5b01826 http://doi.org/10.1021/acs.macromol.5b01826 .

C. Kanimozhi , N. Yaacobi-Gross , K.W. Chou , A. Amassian , T.D. Anthopoulos , S. Patil . J. Am. Chem. Soc. , 2012 . 134 16532 DOI: 10.1021/ja308211n http://doi.org/10.1021/ja308211n .

W.W. Li , K.H. Hendriks , M.M. Wienk , R.A.J. Janssen . Acc. Chem. Res. , 2016 . 49 78 DOI: 10.1021/acs.accounts.5b00334 http://doi.org/10.1021/acs.accounts.5b00334 .

Y.H. Liu , G.W. Li , Z. Zhang , L.L. Wu , J.Y. Chen , X.J. Xu , X.B. Chen , W. Ma , Z.S. Bo . J. Mater. Chem. A , 2016 . 4 13265 DOI: 10.1039/C6TA05471D http://doi.org/10.1039/C6TA05471D .

H.X. Zhou , L.Q. Yang , A.C. Stuart , S.C. Price , S.B. Liu , W. You . Angew. Chem. Int. Ed. , 2011 . 50 2995 DOI: 10.1002/anie.201005451 http://doi.org/10.1002/anie.201005451 .

Q. Peng , X.J. Liu , D. Su , G.W. Fu , J. Xu , L.M. Dai . Adv. Mater. , 2011 . 23 4554 DOI: 10.1002/adma.201101933 http://doi.org/10.1002/adma.201101933 .

J. Lee , M. Kim , B. Kang , S.B. Jo , H.G. Kim , J. Shin , K. Cho . Adv. Energy Mater. , 2014 . 4 1400087 DOI: 10.1002/aenm.201400087 http://doi.org/10.1002/aenm.201400087 .

J. Lee , S.B. Jo , M. Kim , H.G. Kim , J. Shin , H. Kim , K. Cho . Adv. Mater. , 2014 . 26 6706 DOI: 10.1002/adma.v26.39 http://doi.org/10.1002/adma.v26.39 .

N. Wang , Z. Chen , W. Wei , Z.H. Jiang . J. Am. Chem. Soc. , 2013 . 135 17060 DOI: 10.1021/ja409881g http://doi.org/10.1021/ja409881g .

X.P. Xu , Y. Li , M.M. Luo , Q. Peng . Chin. Chem. Lett. , 2016 . DOI: 10.1016/j.cclet.2016.05.006 http://doi.org/10.1016/j.cclet.2016.05.006 .

L.X. Wang , D.D. Cai , Q.D. Zheng , C.Q. Tang , S.C. Chen , Z.G. Yin . ACS Macro Lett. , 2013 . 2 605 DOI: 10.1021/mz400185k http://doi.org/10.1021/mz400185k .

C.H. Woo , P.M. Beaujuge , T.W. Holcombe , O.P. Lee , J.M.J. Fréchet . J. Am. Chem. Soc. , 2010 . 132 15547 DOI: 10.1021/ja108115y http://doi.org/10.1021/ja108115y .

X.P. Xu , K. Feng , K. Li , Q. Peng . J. Mater. Chem. A , 2015 . 3 23149 DOI: 10.1039/C5TA07205K http://doi.org/10.1039/C5TA07205K .

Z.G. Wang , Z.J. Li , X.P. Xu , Y. Li , K. Li , Q. Peng . Adv. Funct. Mater. , 2016 . 26 4643 DOI: 10.1002/adfm.v26.26 http://doi.org/10.1002/adfm.v26.26 .

Q. Peng , Z.Y. Lu , Y. Huang , M.G. Xie , S.H. Han , J.B. Peng , Y. Cao . Macromolecules , 2004 . 37 260 DOI: 10.1021/ma0355397 http://doi.org/10.1021/ma0355397 .

K. Li , Z.J. Li , K. Feng , X.P. Xu , L.Y. Wang , Q. Peng . J. Am. Chem. Soc. , 2013 . 135 13549 DOI: 10.1021/ja406220a http://doi.org/10.1021/ja406220a .

Y.C. Yang , R.M. Wu , X. Wang , X.P. Xu , Z.J. Li , K. Li , Q. Peng . Chem. Commun. , 2014 . 50 439 DOI: 10.1039/C3CC47677D http://doi.org/10.1039/C3CC47677D .

J.B. Zhao , Y.K. Li , H.R. Lin , Y.H. Liu , K. Jiang , C. Mu , T.X. Ma , L.J.Y. Lin , H.W. Hu , D.M. Yu , H. Yan . Energy Environ. Sci. , 2015 . 8 520 DOI: 10.1039/C4EE02990A http://doi.org/10.1039/C4EE02990A .

V.D. Mihailetchi , L.J.A. Koster , P.W.M. Blom , C. Melzer , B. De Boer , J.K.J. van Duren , R.A.J. Janssen . Adv. Funct. Mater. , 2005 . 15 795 DOI: 10.1002/(ISSN)1616-3028 http://doi.org/10.1002/(ISSN)1616-3028 .

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