Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate

Liu Ya-lan; Wang Zheng-ke; Qin Wei; Hu Qiao-ling; Zhong Tang Ben

doi:10.1007/s10118-017-1876-y

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Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate

Papers | Updated：2024-11-27

- Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate
- Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate
- Chinese Journal of Polymer Science 2017年35卷第3期页码：365-371
- Affiliations：
  
  a. Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  b. Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Hangzhou 310027, China
  c. Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong, China
- Author bio：
  
  Zheng-ke Wang(王征科), E-mail:wangzk@zju.edu.cn
  Qiao-ling Hu(胡巧玲), E-mail:huql@zju.edu.cn
  Ben Zhong Tang(唐本忠), E-mail:tangbenz@ust.hk
- Funds：
  
  the Key Science Technology Innovation Team of Zhejiang Province(2013TD02);the National Natural Science Foundation of China(21104067, 21274127, 21374099 and 51473144)
- DOI：10.1007/s10118-017-1876-y
  中图分类号：
- 收稿：2016-07-30，
  
  修回：2016-9-17，
  
  录用：2016-9-30，
  
  纸质出版：2017-03-25
- Accepted：
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Liu Ya-lan, Wang Zheng-ke, Qin Wei, 等. Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate[J]. Chinese Journal of Polymer Science, 2017,35(3):365-371.

Liu Ya-lan, Wang Zheng-ke, Qin Wei, et al. Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate[J]. Chinese Journal of Polymer Science, 2017, 35(3): 365-371.
Liu Ya-lan, Wang Zheng-ke, Qin Wei, 等. Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate[J]. Chinese Journal of Polymer Science, 2017,35(3):365-371. DOI： 10.1007/s10118-017-1876-y.

Liu Ya-lan, Wang Zheng-ke, Qin Wei, et al. Fluorescent Detection of Cu(Ⅱ) by Chitosan-based AIE Bioconjugate[J]. Chinese Journal of Polymer Science, 2017, 35(3): 365-371. DOI： 10.1007/s10118-017-1876-y.

摘要

Abstract

Detection of Cu(Ⅱ) is very important in disease diagnose

biological system detection and environmental monitoring. Previously

we found that the product TPE-CS prepared by attaching the chromophores of tetraphenylethylene (TPE) to the chitosan (CS) chains showed excellent fluorescent properties. In this study

we tried to use TPE-CS for detecting Cu(Ⅱ) because of the stable complexation of CS with heavy metals and the luminosity mechanism of the Restriction of Intramolecular Rotations (RIR) for aggregation-induced emission (AIE)-active materials. The fluorescence intensity changed when TPE-CS was contacted with different metal ions

to be specific

no change for Na

slightly increase for Hg

due to the RIR caused by the complexation between CS and metal ions. However

for Cu

an obvious fluorescence decrease was observed because of the Photoinduced-Electron-Transfer (PET). Moreover

we found that the quenched FL intensity of TPE-CS was proportional to the concentration of Cu(Ⅱ) in the range of 5 μmol/L to 100 μmol/L

which provided a new way to quantitatively detect Cu(Ⅱ). Besides

TPE-CS has excellent water-solubility as well as absorbability (the percentage of removal

=84%)

which is an excellent detection probe and remover for Cu(Ⅱ).

关键词

Keywords

references

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