a.Chinese Academy of Sciences Key Laboratory of Nanosystem and Hierarchical Fabrication, Chinese Academy of Sciences Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
b.Department of Environmental Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China
Kun Lu (吕琨), E-mail:lvk@nanoctr.cn
Wei Yan (延卫), E-mail:yanwei@mail.xjtu.edu.cn
Zhi-xiang Wei (魏志祥), E-mail:weizx@nanoctr.cn
收稿:2016-09-17,
修回:2016-10-14,
录用:2016-10-15,
纸质出版:2017-02
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Yi-fan Zhao, Wen-jun Zou, Huan Li, 等. Large-area, Flexible Polymer Solar Cell Based on Silver Nanowires as Transparent Electrode by Roll-to-Roll Printing[J]. Chinese Journal of Polymer Science, 2017,35(2):261-268.
Yi-fan Zhao, Wen-jun Zou, Huan Li, et al. Large-area, Flexible Polymer Solar Cell Based on Silver Nanowires as Transparent Electrode by Roll-to-Roll Printing[J]. Chinese Journal of Polymer Science, 2017, 35(2): 261-268.
Yi-fan Zhao, Wen-jun Zou, Huan Li, 等. Large-area, Flexible Polymer Solar Cell Based on Silver Nanowires as Transparent Electrode by Roll-to-Roll Printing[J]. Chinese Journal of Polymer Science, 2017,35(2):261-268. DOI: 10.1007/s10118-017-1875-z.
Yi-fan Zhao, Wen-jun Zou, Huan Li, et al. Large-area, Flexible Polymer Solar Cell Based on Silver Nanowires as Transparent Electrode by Roll-to-Roll Printing[J]. Chinese Journal of Polymer Science, 2017, 35(2): 261-268. DOI: 10.1007/s10118-017-1875-z.
Conventional organic solar cell's (OSC) architectures
including rigid transparent substrate (Glass)
conductive electrode (Indium tin oxide
ITO) and small working areas
are widely utilized in organic photovoltaic fields. However
such a structure as well as conventional spin-coating method obviously restrict their industrial application. In this article
we report the deposition of silver nanowires (AgNWs) on the flexible substrate by slot-die printing. The obtained AgNWs films exhibited a high transmittance and a low resistance
and were further used as the transparent conductive electrode of OSCs. A typical conjugated polymer
poly[(2
5-bis (2-hexyldecyloxy) phenylene)-
alt
-(5
6-difluoro-4
7-di (thiophen-2-yl) benzo[c] [1
2
5]
thiadiazole)] (PPDT2FBT)
was used as the active material to fabricate large-area (7 cm
2
) solar cells by a slot-die coating process. The power conversion efficiency (PCE) could reach 1.87% initially and further increased to 3.04% by thermal annealing. Compared to the performance of reference cell on ITO substrate
the result indicated that the AgNWs could be developed as an alternative substitute of conductive electrode to fabricate the large-area flexible OSCs by roll-to-roll printing.
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