Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries

Hong-qing Liang; Ling-shu Wan; Zhi-kang Xu

doi:10.1007/s10118-016-1860-y

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Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries

Papers | Updated：2021-05-12

- Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries
- Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries
- Chinese Journal of Polymer Science 2016年34卷第12期页码：1423-1435
- Affiliations：
  
  a.MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  b.Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Zhi-kang Xu (徐志康), E-mail:xuzk@zju.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21174124);the National Natural Science Foundation of China(21534009)
- DOI：10.1007/s10118-016-1860-y
  中图分类号：
- 收稿：2016-07-25，
  
  修回：2016-9-13，
  
  录用：2016-9-13，
  
  纸质出版：2016-12
- Accepted：
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Hong-qing Liang, Ling-shu Wan, Zhi-kang Xu. Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries[J]. Chinese Journal of Polymer Science, 2016,34(12):1423-1435.

Hong-qing Liang, Ling-shu Wan, Zhi-kang Xu. Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1423-1435.
Hong-qing Liang, Ling-shu Wan, Zhi-kang Xu. Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries[J]. Chinese Journal of Polymer Science, 2016,34(12):1423-1435. DOI： 10.1007/s10118-016-1860-y.

Hong-qing Liang, Ling-shu Wan, Zhi-kang Xu. Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1423-1435. DOI： 10.1007/s10118-016-1860-y.

摘要

Abstract

Dual-asymmetric poly (vinylidene fluoride) (PVDF) separators have been fabricated by thermally induced phase separation with dimethyl sulfone (DMSO2) and glycerol as mixed diluents. The separators have a porous bulk with large interconnected pores (~1.0 μm) and two surfaces with small pores (~30 nm). This dual-asymmetric porous structure endows the separators with higher electrolyte uptake amount and rapider uptake rate

as well as better electrolyte retention ability than the commercialized Celgard 2400. The separators even maintain their dimensional stability up to 160℃

at which temperature the surface pores close up

leading to a dramatic decrease of air permeability. The electrolyte filled separators also show high ion conductivity (1.72 mS·cm

-1

) at room temperature. Lithium iron phosphate (LiFePO

)/lithium (Li) cells using these separators display superior discharge capacity and better rate performance as compared with those from the commercialized ones. The results provide new insight into the design and development of separators for high-performance lithium ion batteries with enhanced safety.

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references

M.S. Whittingham . Chem. Rev. , 2004 . 104 ( 10 ): 4271 DOI: 10.1021/cr020731c http://doi.org/10.1021/cr020731c .

A.S. Arico , P. Bruce , B. Scrosati , J.M. Tarascon , W. van Schalkwijk . Nat. Mater. , 2005 . 4 ( 5 ): 366 DOI: 10.1038/nmat1368 http://doi.org/10.1038/nmat1368 .

M. Armand , J.M. Tarascon . Nature , 2008 . 451 ( 7179 ): 652 DOI: 10.1038/451652a http://doi.org/10.1038/451652a .

P.G. Bruce , B. Scrosati , J.M. Tarascon . Angew. Chem. Int. Ed. , 2008 . 47 ( 16 ): 2930 DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

J.B. Goodenough , Y. Kim . Chem. Mater. , 2010 . 22 ( 3 ): 587 DOI: 10.1021/cm901452z http://doi.org/10.1021/cm901452z .

V. Etacheri , R. Marom , R. Elazari , G. Salitra , D. Aurbach . Energy Environ. Sci. , 2011 . 4 ( 9 ): 3243 DOI: 10.1039/c1ee01598b http://doi.org/10.1039/c1ee01598b .

P. Arora , Z. Zhang . Chem. Rev. , 2004 . 104 ( 10 ): 4419 DOI: 10.1021/cr020738u http://doi.org/10.1021/cr020738u .

S.S. Zhang . J. Power Sources , 2007 . 164 ( 1 ): 351 DOI: 10.1016/j.jpowsour.2006.10.065 http://doi.org/10.1016/j.jpowsour.2006.10.065 .

C.M. Costa , M.M. Silva , S. Lanceros-Mendez . RSC Adv. , 2013 . 3 ( 29 ): 11404 DOI: 10.1039/c3ra40732b http://doi.org/10.1039/c3ra40732b .

J. Nunes-Pereira , C.M. Costa , S. Lanceros-Méndez . J. Power Sources , 2015 . 281 378 DOI: 10.1016/j.jpowsour.2015.02.010 http://doi.org/10.1016/j.jpowsour.2015.02.010 .

V. Deimede , C. Elmasides . Energy Technol. , 2015 . 3 ( 5 ): 453 DOI: 10.1002/ente.v3.5 http://doi.org/10.1002/ente.v3.5 .

M.H. Ryou , Y.M. Lee , J.K. Park , J.W. Choi . Adv. Mater. , 2011 . 23 ( 27 ): 3066 DOI: 10.1002/adma.v23.27 http://doi.org/10.1002/adma.v23.27 .

J.L. Shi , H. Li , L.F. Fang , Z.Y. Liang , B.K. Zhu . Chinese J. Polym. Sci. , 2013 . 31 ( 2 ): 309 DOI: 10.1007/s10118-013-1222-y http://doi.org/10.1007/s10118-013-1222-y .

Q. Shi , M. Yu , X. Zhou , Y. Yan , C. Wan . J. Power Sources , 2002 . 103 ( 2 ): 286 DOI: 10.1016/S0378-7753(01)00868-0 http://doi.org/10.1016/S0378-7753(01)00868-0 .

C.M. Costa , L.C. Rodrigues , V. Sencadas , M.M. Silva , J.G. Rocha , S. Lanceros-Mendez . J. Membr. Sci. , 2012 . 407 193 .

N. Shubha , R. Prasanth , H.H. Hng , M. Srinivasan . J. Power Sources , 2014 . 267 48 DOI: 10.1016/j.jpowsour.2014.05.074 http://doi.org/10.1016/j.jpowsour.2014.05.074 .

M. Kim , J.H. Park . Adv. Energy Mater. , 2013 . 3 ( 11 ): 1417 DOI: 10.1002/aenm.v3.11 http://doi.org/10.1002/aenm.v3.11 .

J. Zhang , B. Sun , X. Huang , S. Chen , G. Wang . Sci. Rep. , 2014 . 4 6007 DOI: 10.1038/srep06007 http://doi.org/10.1038/srep06007 .

M. Kim , J.K. Kim , J.H. Park . Adv. Funct. Mater. , 2015 . 25 ( 22 ): 3399 DOI: 10.1002/adfm.v25.22 http://doi.org/10.1002/adfm.v25.22 .

W.H. Pu , X.M. He , L. Wang , C.Y. Jiang , C.R. Wan . J. Membr. Sci. , 2006 . 272 ( 1-2 ): 11 DOI: 10.1016/j.memsci.2005.12.038 http://doi.org/10.1016/j.memsci.2005.12.038 .

F. Croce , M.L. Focarete , J. Hassoun , I. Meschini , B. Scrosati . Energy Environ. Sci. , 2011 . 4 ( 3 ): 921 DOI: 10.1039/c0ee00348d http://doi.org/10.1039/c0ee00348d .

C.M. Costa , J.L. Gomez Ribelles , S. Lanceros-Mendez , G.B. Appetecchi , B. Scrosati . J. Power Sources , 2014 . 245 779 DOI: 10.1016/j.jpowsour.2013.06.151 http://doi.org/10.1016/j.jpowsour.2013.06.151 .

X. Wang , C. Gong , D. He , Z. Xue , C. Chen , Y. Liao , X. Xie . J. Membr. Sci. , 2014 . 454 298 DOI: 10.1016/j.memsci.2013.12.016 http://doi.org/10.1016/j.memsci.2013.12.016 .

J. Zhang , L. Yue , Q. Kong , Z. Liu , X. Zhou , C. Zhang , Q. Xu , B. Zhang , G. Ding , B. Qin , Y. Duan , Q. Wang , J. Yao , G. Cui , L. Chen . Sci. Rep. , 2014 . 4 3935 .

H. Matsuyama , S. Berghmans , M.T. Batarseh , D.R. Lloyd . J. Membr. Sci. , 1998 . 142 ( 1 ): 27 DOI: 10.1016/S0376-7388(97)00313-X http://doi.org/10.1016/S0376-7388(97)00313-X .

P.M. Atkinson , D.R. Lloyd . J. Membr. Sci. , 2000 . 171 ( 1 ): 1 DOI: 10.1016/S0376-7388(99)00376-2 http://doi.org/10.1016/S0376-7388(99)00376-2 .

P.M. Atkinson , D.R. Lloyd . J. Membr. Sci. , 2000 . 175 ( 2 ): 225 DOI: 10.1016/S0376-7388(00)00422-1 http://doi.org/10.1016/S0376-7388(00)00422-1 .

H. Matsuyama , M. Yuasa , Y. Kitamura , M. Teramoto , D.R. Lloyd . J. Membr. Sci. , 2000 . 179 ( 1-2 ): 91 DOI: 10.1016/S0376-7388(00)00506-8 http://doi.org/10.1016/S0376-7388(00)00506-8 .

A. Cui , Z. Liu , C. Xiao , Y. Zhang . J. Membr. Sci. , 2010 . 360 ( 1 ): 259 .

Z. Cui , N.T. Hassankiadeh , S.Y. Lee , J.M. Lee , K.T. Woo , A. Sanguineti , V. Arcella , Y.M. Lee , E. Drioli . J. Membr. Sci. , 2013 . 444 223 DOI: 10.1016/j.memsci.2013.05.031 http://doi.org/10.1016/j.memsci.2013.05.031 .

J. Lal , R. Bansil . Macromolecules , 1991 . 24 ( 1 ): 290 DOI: 10.1021/ma00001a044 http://doi.org/10.1021/ma00001a044 .

S.P. Nunes , T. Inoue . J. Membr. Sci. , 1996 . 111 ( 1 ): 93 DOI: 10.1016/0376-7388(95)00281-2 http://doi.org/10.1016/0376-7388(95)00281-2 .

Q.Y. Wu , H.Q. Liang , M. Li , B.T. Liu , Z.K. Xu . Chinese J. Polym. Sci. , 2016 . 34 ( 1 ): 23 DOI: 10.1007/s10118-016-1723-6 http://doi.org/10.1007/s10118-016-1723-6 .

H.Q. Liang , Q.Y. Wu , L.S. Wan , X.J. Huang , Z.K. Xu . J. Membr. Sci. , 2013 . 446 482 DOI: 10.1016/j.memsci.2013.07.008 http://doi.org/10.1016/j.memsci.2013.07.008 .

H.Q. Liang , Q.Y. Wu , L.S. Wan , X.J. Huang , Z.K. Xu . J. Membr. Sci. , 2014 . 465 56 DOI: 10.1016/j.memsci.2014.03.068 http://doi.org/10.1016/j.memsci.2014.03.068 .

H. Matsuyama , S. Berghmans , M.T. Batarseh , D.R. Lloyd . J. Membr. Sci. , 1998 . 142 ( 1 ): 27 DOI: 10.1016/S0376-7388(97)00313-X http://doi.org/10.1016/S0376-7388(97)00313-X .

Q.Y. Wu , B.T. Liu , M. Li , L.S. Wan , Z.K. Xu . J. Membr. Sci. , 2013 . 437 227 DOI: 10.1016/j.memsci.2013.03.018 http://doi.org/10.1016/j.memsci.2013.03.018 .

Q.Y. Wu , L.S. Wan , Z.K. Xu . J. Membr. Sci. , 2012 . 409 355 .

M.J. Park , C.K. Kim . J. Membr. Sci. , 2014 . 449 127 DOI: 10.1016/j.memsci.2013.08.004 http://doi.org/10.1016/j.memsci.2013.08.004 .

D. Shou , L. Ye , J. Fan , K. Fu . Langmuir , 2014 . 30 ( 1 ): 149 DOI: 10.1021/la4034063 http://doi.org/10.1021/la4034063 .

T. Gambaryan-Roisman . Curr. Opin. Colloid Interface Sci. , 2014 . 19 ( 4 ): 320 DOI: 10.1016/j.cocis.2014.09.001 http://doi.org/10.1016/j.cocis.2014.09.001 .

J. Chen , S. Wang , L. Ding , Y. Jiang , H. Wang . J. Membr. Sci. , 2014 . 461 22 DOI: 10.1016/j.memsci.2014.03.005 http://doi.org/10.1016/j.memsci.2014.03.005 .

J. Shi , Y. Xia , Z. Yuan , H. Hu , X. Li , H. Zhang , Z. Liu . Sci. Rep. , 2015 . 5 8255 DOI: 10.1038/srep08255 http://doi.org/10.1038/srep08255 .

Y. Zhai , N. Wang , X. Mao , Y. Si , J. Yu , S.S. Al-Deyab , M. El-Newehy , B. Ding . J. Mater. Chem. A , 2014 . 2 ( 35 ): 14511 DOI: 10.1039/C4TA02151G http://doi.org/10.1039/C4TA02151G .

M. Benz , W. B. Euler , O. J. Gregory . Macromolecules , 2002 . 35 ( 7 ): 2682 DOI: 10.1021/ma011744f http://doi.org/10.1021/ma011744f .

G.L. Ji , B.K. Zhu , Z.Y. Cui , C.F. Zhang , Y.Y. Xu . Polymer , 2007 . 48 ( 21 ): 6415 DOI: 10.1016/j.polymer.2007.08.049 http://doi.org/10.1016/j.polymer.2007.08.049 .

Z.Y. Cui , Y.Y. Xu , L.P. Zhu , J.Y. Wang , Z.Y. Xi , B.K. Zhu . J. Membr. Sci. , 2008 . 325 ( 2 ): 957 DOI: 10.1016/j.memsci.2008.09.022 http://doi.org/10.1016/j.memsci.2008.09.022 .

Z.Y. Cui , Y.Y. Xu , L.P. Zhu , J.Y. Wang , B.K. Zhu . Ionics , 2009 . 15 ( 4 ): 469 DOI: 10.1007/s11581-008-0253-9 http://doi.org/10.1007/s11581-008-0253-9 .

J. Nunes-Pereira , C.M. Costa , R.E. Sousa , A.V. Machado , M.M. Silva , S. Lanceros-Mendez . Electrochim. Acta , 2014 . 117 276 DOI: 10.1016/j.electacta.2013.11.122 http://doi.org/10.1016/j.electacta.2013.11.122 .

M. He , X. Zhang , K. Jiang , J. Wang , Y. Wang . Acs Appl. Mater. Interfaces , 2015 . 7 ( 1 ): 738 DOI: 10.1021/am507145h http://doi.org/10.1021/am507145h .

J. Zhang , L. Yue , P. Hu , Z. Liu , B. Qin , B. Zhang , Q. Wang , G. Ding , C. Zhang , X. Zhou , J. Yao , G. Cui , L. Chen . Sci. Rep. , 2014 . 4 6272 DOI: 10.1038/srep06272 http://doi.org/10.1038/srep06272 .

Y. Zhu , S. Xiao , Y. Shi , Y. Yang , Y. Wu . J. Mater. Chem. A , 2013 . 1 ( 26 ): 7790 DOI: 10.1039/c3ta00167a http://doi.org/10.1039/c3ta00167a .

Y. Zhu , S. Xiao , Y. Shi , Y. Yang , Y. Hou , Y. Wu . Adv. Energy Mater. , 2014 . 4 ( 1 ): 1300647 DOI: 10.1002/aenm.201300647 http://doi.org/10.1002/aenm.201300647 .

J. Zhang , S. Chen , X. Xie , K. Kretschmer , X. Huang , B. Sun , G. Wang . J. Membr. Sci. , 2014 . 472 133 DOI: 10.1016/j.memsci.2014.08.049 http://doi.org/10.1016/j.memsci.2014.08.049 .

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