The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization

Quan-long Li; Lei Li; Hong-song Wang; Rui Wang; Wei Wang; Yong-jing Jiang; Qian Tian; Jia-ping Liu

doi:10.1007/s10118-016-1859-4

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The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization

PAPERS | Updated：2021-02-18

- The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization
- The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization
- Chinese Journal of Polymer Science 2017年35卷第1期页码：66-77
- Affiliations：
  
  a.State Key Laboratory of High Performance Civil Engineering Materials, Jiangsu Research Institute of Building Science, Nanjing 210008, China
  b.Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China
  c.College of Materials Science and Engineering, Southeast University, Nanjing 211189, China
- Author bio：
  
  Qian Tian, E-mail:tianqian@cnjsjk.cn
  Jia-ping Liu, E-mail:liujiaping@cnjsjk.cn
- Funds：
  
  973 Program of China,under the contract(2015CB655105);the National Science Fund for Distinguished Young Scholars(51225801);the National Natural Science Foundation of China(51408275);the Provincial Science and Technology Cooperation Project of Jiangsu-Guangxi cooperation project(BM2014050)
- DOI：10.1007/s10118-016-1859-4
  中图分类号：
- 收稿：2016-06-05，
  
  修回：2016-7-14，
  
  录用：2016-7-15，
  
  纸质出版：2017-01
- Accepted：
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Quan-long Li, Lei Li, Hong-song Wang, 等. The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization[J]. Chinese Journal of Polymer Science, 2017,35(1):66-77.

Quan-long Li, Lei Li, Hong-song Wang, et al. The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization[J]. Chinese Journal of Polymer Science, 2017, 35(1): 66-77.
Quan-long Li, Lei Li, Hong-song Wang, 等. The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization[J]. Chinese Journal of Polymer Science, 2017,35(1):66-77. DOI： 10.1007/s10118-016-1859-4.

Quan-long Li, Lei Li, Hong-song Wang, et al. The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization[J]. Chinese Journal of Polymer Science, 2017, 35(1): 66-77. DOI： 10.1007/s10118-016-1859-4.

摘要

Abstract

The doubly thermo-responsive triblock copolymer nanoparticles of polystyrene-block-poly(

-isopropylacrylamide)-block-poly[

-(dimethylamino) ethyl methacrylate] (PS-

-PNIPAM-

-PDMAEMA) are successfully prepared through the seeded RAFT polymerization

in situ

by using the PS-

-PNIPAM-TTC diblock copolymer nanoparticles as the seed. The seeded RAFT polymerization undergoes a pseudo-first-order kinetics procedure

and the molecular weight increases with the monomer conversion linearly. The hydrodynamic diameter (

) of the triblock copolymer nanoparticles increases with the extension of the PDMAEMA block. In addition

the double thermo-response behavior of the PS-

-PNIPAM-

-PDMAEMA nanoparticles is detected by turbidity analysis

temperature-dependent

H-NMR analysis

and DLS analysis. The seeded RAFT polymerization is believed as a valid method to prepare triblock copolymer nanoparticles containing two thermo-responsive blocks.

关键词

Keywords

references

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