A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer

Quan-you Feng; Ye-long Han; Meng-na Yu; Bin Li; Ying Wei; Ling-hai Xie; Wei Huang

doi:10.1007/s10118-016-1856-7

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A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer

PAPERS | Updated：2021-02-18

- A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer
- A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer
- Chinese Journal of Polymer Science 2017年35卷第1期页码：87-97
- Affiliations：
  
  a.Center for Molecular Systems and Organic Devices(CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
  b.Key Laboratory of Flexible Electronics(KLOFE) & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing Tech University(NanjingTech), Nanjing 211816, China
- Author bio：
  
  Ling-hai Xie, E-mail:iamlhxie@njupt.edu.cn
  Wei Huang, E-mail:iamwhuang@njupt.edu.cn
- Funds：
  
  the National Natural Science Funds for Excellent Young Scholar(21322402);the National Natural Science Foundation of China(21274064;21504041;21504047;61136003);Excellent Science and Technology Innovation Team of Jiangsu Higher Education Institutions(2013);Synergetic Innovation Center for Organic Electronics and Information Displays,the Natural Science Foundation of Jiangsu Province(BK20150834;BM2012010);Open Project from State Key Laboratory of Supramolecular Structure and Materials at Jilin University(klssm201612);Project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and Nanjing University of Posts and Telecommunications Scientific Foundation (NUPTSF)(NY214179)
- DOI：10.1007/s10118-016-1856-7
  中图分类号：
- 收稿：2016-05-16，
  
  修回：2016-6-22，
  
  录用：2016-6-23，
  
  纸质出版：2017-01
- Accepted：
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Quan-you Feng, Ye-long Han, Meng-na Yu, 等. A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer[J]. Chinese Journal of Polymer Science, 2017,35(1):87-97.

Quan-you Feng, Ye-long Han, Meng-na Yu, et al. A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer[J]. Chinese Journal of Polymer Science, 2017, 35(1): 87-97.
Quan-you Feng, Ye-long Han, Meng-na Yu, 等. A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer[J]. Chinese Journal of Polymer Science, 2017,35(1):87-97. DOI： 10.1007/s10118-016-1856-7.

Quan-you Feng, Ye-long Han, Meng-na Yu, et al. A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer[J]. Chinese Journal of Polymer Science, 2017, 35(1): 87-97. DOI： 10.1007/s10118-016-1856-7.

摘要

Abstract

Shape persistent conformations reduce the complexity of polymer materials. Herein

we propose a concept on the nanopolymer that is a nanoscale polymer chain with the repeat units of nanomonomers. In this article

a soluble organic nanopolymer of wide bandgap semiconductors was synthesized by the Yamamoto polymerization of nanogrid monomer as the repeat units with the rectangle size of ~1.7 nm×1.2 nm. The alkyl side chain substituent at 9-position of fluorenes guarantees the polygrid with excellent solubility. Tetrafluorenes in the conjugation-interrupted backbones of polygrid acts as the active light-emitting centers without obvious green band in the fluorescence spectra of the films after 10 h annealing at 180℃

indicating this nanopolymer exhibits excellent spectral stability. Such soluble nanopolymers will be the fifth-generation of macromolecular materials with a potential character of overall performance improvement.

关键词

Keywords

references

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