The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process

Min-fang An; Hao-jun Xu; You Lv; Li Zhang; Qun Gu; Feng Tian; Zong-bao Wang

doi:10.1007/s10118-016-1843-z

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The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process

PAPERS | Updated：2021-05-12

- The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process
- The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process
- Chinese Journal of Polymer Science 2016年34卷第11期页码：1373-1385
- Affiliations：
  
  a.Ningbo Key Laboratory of Specialty Polymers, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
  b.College of Material Engineering, Ningbo University of Technology, Ningbo 3151006, China
  c.Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China
- Author bio：
  
  Zong-bao Wang(王宗宝),E-mail:wangzongbao@nbu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51273210;51003117;5140030545);Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry;Changchun Institute of Applied Chemistry, Chinese Academy of Sciences;K.C. Wong Magna Fund in Ningbo University
- DOI：10.1007/s10118-016-1843-z
  中图分类号：
- 收稿：2016-03-27，
  
  修回：2016-6-21，
  
  录用：2016-7-18，
  
  纸质出版：2016-11
- Accepted：
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Min-fang An, Hao-jun Xu, You Lv, 等. The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process[J]. Chinese Journal of Polymer Science, 2016,34(11):1373-1385.

Min-fang An, Hao-jun Xu, You Lv, et al. The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1373-1385.
Min-fang An, Hao-jun Xu, You Lv, 等. The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process[J]. Chinese Journal of Polymer Science, 2016,34(11):1373-1385. DOI： 10.1007/s10118-016-1843-z.

Min-fang An, Hao-jun Xu, You Lv, et al. The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1373-1385. DOI： 10.1007/s10118-016-1843-z.

摘要

Abstract

Ultra-high molecular weight polyethylene (UHMWPE)/chitin nanocrystal (CNC) fibers were prepared. Compared with the pure UHMWPE fibers

the ultimate tensile strength and Young's modulus of UHMWPE/CNC fibers are improved by 15.7% and 49.6%

respectively

with the addition of chitin nanocrystals (CNCs) of 1 wt%. The melting temperature (

) of UHMWPE/CNC fibers was higher than that of pure UHMWPE fibers. Pure UHMWPE fibers and UHMWPE/CNC fibers were characterized with respect to crystallinity

orientation and kebab structure by wide-angle X-ray diffraction (WAXD)

small-angle X-ray scattering (SAXS) and scanning electron microscopy (SEM). It is found that the CNCs act as the shish structure in UHMWPE/CNC fibers and the kebab crystals are grown around the CNCs. There was almost no difference between pure UHMWPE fibers and UHMWPE/CNC fibers in orientation. But the degree of crystallinity of various stages of UHMWPE/CNC fibers was respectively higher than the corresponding stage of pure UHMWPE fibers. Moreover

the addition of 1 wt% CNCs improved the thickness of kebab crystals and accelerated the transformation of kebab to shish.

关键词

Keywords

references

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