Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers

Zhi-xin Dong; Tao Feng; Chao Zheng; Guo-min Li; Fang-fang Liu; Xue-peng Qiu

doi:10.1007/s10118-016-1841-1

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Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers

PAPERS | Updated：2021-05-12

- Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers
- Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers
- Chinese Journal of Polymer Science 2016年34卷第11期页码：1386-1395
- Affiliations：
  
  a.Polymer Composites Engineering Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.Academy of Space Electronic Information Technology, Xi'an 710100, China
- Author bio：
  
  Xue-peng Qiu(邱雪鹏),E-mail:xp_q@ciac.ac.cn
- Funds：
  
  the National Basic Research Program of China(2014CB643604);the National Natural Science Foundation of China(51173178)
- DOI：10.1007/s10118-016-1841-1
  中图分类号：
- 收稿：2016-05-03，
  
  修回：2016-6-14，
  
  录用：2016-7-6，
  
  纸质出版：2016-11
- Accepted：
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Zhi-xin Dong, Tao Feng, Chao Zheng, 等. Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers[J]. Chinese Journal of Polymer Science, 2016,34(11):1386-1395.

Zhi-xin Dong, Tao Feng, Chao Zheng, et al. Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1386-1395.
Zhi-xin Dong, Tao Feng, Chao Zheng, 等. Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers[J]. Chinese Journal of Polymer Science, 2016,34(11):1386-1395. DOI： 10.1007/s10118-016-1841-1.

Zhi-xin Dong, Tao Feng, Chao Zheng, et al. Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1386-1395. DOI： 10.1007/s10118-016-1841-1.

摘要

Abstract

A series of polyimide (PI)/multi-walled carbon nanotube (MWCNT) composite fibers were prepared by copolymerizing a mixture of monomers and carboxylic-functionalized MWCNTs

followed by dry-jet wet spinning

thermal imidization

and hot-drawing process. The content of the carboxylic groups of MWCNTs significantly increased when treated with mixed acid

whereas their length decreased with treatment time. Both the carboxylic content and length of MWCNTs influenced the mechanical properties of the composite fibers. Fiber added with 0.1 wt% MWCNTs treated for 4 h exhibited the best mechanical properties

i.e

1.4 GPa tensile strength and 14.30% elongation at break

which were 51% and 32% higher than those of pure PI fibers

respectively. These results indicated that a suitable MWCNT content strengthened and toughened the resultant PI composite fibers

simultaneously. Moreover

raising draw ratio resulted in the increase of tensile strength and tensile modulus of the composite fibers.

关键词

Keywords

references

S. Iijima, . . Nature , 1991 . 354 56 DOI: 10.1038/354056a0 http://doi.org/10.1038/354056a0 .

M.M.J. Treacy, , T.W. Ebbesen, , J.M. Gibson, . . Nature , 1996 . 381 678 DOI: 10.1038/381678a0 http://doi.org/10.1038/381678a0 .

S. Berber, , Y.K. Kwon, , D. Tománek, . . Phys. Rev. Lett. , 2000 . 84 ( 20 ): 4613 DOI: 10.1103/PhysRevLett.84.4613 http://doi.org/10.1103/PhysRevLett.84.4613 .

T.W. Ebbesen, , H.J. Lezec, , H. Hiura, , J.W. Bennett, , H.F. Ghaemi, , T. Thio, . . Nature , 1996 . 382 54 DOI: 10.1038/382054a0 http://doi.org/10.1038/382054a0 .

H.L. Wang, , X.G. Zhou, , H.J. Yu, , C.C. Zhou, , Z.Y. Wang, . . Mater. Rev. , 2008 . 22 .

H.H. So, , J.W. Cho, , N.G. Sahoo, . . Eur. Polym. J. , 2007 . 43 ( 9 ): 3750 DOI: 10.1016/j.eurpolymj.2007.06.025 http://doi.org/10.1016/j.eurpolymj.2007.06.025 .

C. Park, , Z. Ounaies, , K.A. Watson, , R.E. Crooks, , J.S. Jr., , S.E. Lowther, , J.W. Connell, , E.J. Siochi, , J.S. Harrison, , T.L.S. Clair, . . Chem. Phys. Lett. , 2002 . 364 ( 3-4 ): 303 DOI: 10.1016/S0009-2614(02)01326-X http://doi.org/10.1016/S0009-2614(02)01326-X .

X.W. Jiang, , Y.Z. Bin, , M. Matsuo, . . Polymer , 2005 . 46 ( 18 ): 7418 DOI: 10.1016/j.polymer.2005.05.127 http://doi.org/10.1016/j.polymer.2005.05.127 .

F.C. Yang, , Y.F. Li, , S.J. Zhang, , M. Tao, , J.J. Zhao, , C.S. Hang, . . Synth. Met. , 2010 . 160 ( 15-16 ): 1805 DOI: 10.1016/j.synthmet.2010.05.006 http://doi.org/10.1016/j.synthmet.2010.05.006 .

J.J. Ge, , D. Zhang, , Q. Li, , H.Q. Hou, , M.J. Graham, , L.M. Dai, , F.W. Harris, , S.Z.D. Cheng, . . J. Am. Chem. Soc. , 2005 . 127 ( 28 ): 9984 DOI: 10.1021/ja050924s http://doi.org/10.1021/ja050924s .

Ding, M.X., "Polyimides:chemistry, relationship between structure and properties and materials", Science Press, Beijing, 2006, p. 1

B.K. Zhu, , S.H. Xie, , Z.K. Xu, , Y.Y. Xu, . . Compos. Sci. Technol. , 2006 . 66 ( 3-4 ): 548 DOI: 10.1016/j.compscitech.2005.05.038 http://doi.org/10.1016/j.compscitech.2005.05.038 .

A.P. Yu, , H. Hu, , E. Bekyarova, , M.E. Itkis, , J. Gao, , B. Zhao, , R.C. Haddon, . . Compos. Sci. Technol. , 2006 . 66 ( 9 ): 1190 DOI: 10.1016/j.compscitech.2005.10.023 http://doi.org/10.1016/j.compscitech.2005.10.023 .

G.W. He, , L. Xie, , K.Y. Tan, , H.F. Li, . . Chin. J. Nonferrous Met. , 2011 . 21 ( 5 ): 1123 DOI: 10.1016/S1003-6326(11)60831-5 http://doi.org/10.1016/S1003-6326(11)60831-5 .

Z. Han, , S. Qi, , W. Liu, , E. Han, , Z. Wu, , D. Wu, . . Ind. Eng. Chem. Res. , 2013 . 52 ( 3 ): 1284 DOI: 10.1021/ie302274e http://doi.org/10.1021/ie302274e .

S.K. Park, , R.J. Farris, . . Polymer , 2001 . 42 ( 26 ): 10087 DOI: 10.1016/S0032-3861(01)00576-6 http://doi.org/10.1016/S0032-3861(01)00576-6 .

J. Dong, , C. Yin, , X. Zhao, , Y. Li, , Q. Zhang, . . Polymer , 2013 . 54 ( 23 ): 6415 DOI: 10.1016/j.polymer.2013.09.035 http://doi.org/10.1016/j.polymer.2013.09.035 .

C.Q. Yin, , J. Dong, , Z.T. Li, , Z.X. Zhang, , Q.H. Zhang, . . Composites Part B , 2014 . 58 430 DOI: 10.1016/j.compositesb.2013.10.074 http://doi.org/10.1016/j.compositesb.2013.10.074 .

S.M. Yuen, , C.C.M. Ma, , Y.Y. Lin, , H.C. Kuan, . . Compos. Sci. Technol. , 2007 . 67 ( 11-12 ): 2564 DOI: 10.1016/j.compscitech.2006.12.006 http://doi.org/10.1016/j.compscitech.2006.12.006 .

N.G. Sahoo, , Y.C. Jung, , H.J. Yoo, , J.W. Cho, . . Macromol. Chem. Phys. , 2006 . 207 ( 19 ): 1773 DOI: 10.1002/(ISSN)1521-3935 http://doi.org/10.1002/(ISSN)1521-3935 .

C. Gao, , C.D. Vo, , Y.Z. Jin, , W.W. Li, , S.P. Armes, . . Macromolecules , 2005 . 38 ( 21 ): 8634 DOI: 10.1021/ma050823e http://doi.org/10.1021/ma050823e .

J. Qiu, , G.J. Wang, , Z.H. Qu, , L. Chang, . . New Carbon Mater. , 2006 . 21 ( 3 ): 269 .

F. Avilés, , J.V.C. Rodríguez, , L.M. Tah, , A.M. Pat, , R.V. Coronado, . . Carbon , 2009 . 47 ( 13 ): 2970 DOI: 10.1016/j.carbon.2009.06.044 http://doi.org/10.1016/j.carbon.2009.06.044 .

Z.W. Wang, , M.D. Shirley, , S.T. Meikle, , R.L.D. Whitby, , S.V. Mikhalovsky, . . Carbon , 2009 . 47 ( 1 ): 73 DOI: 10.1016/j.carbon.2008.09.038 http://doi.org/10.1016/j.carbon.2008.09.038 .

J.T. Di, , X. Wang, , Y.J. Xing, , Y.Y. Zhang, , X.H. Zhang, , W.B. Lu, , Q.W. Li, , Y.T. Zhu, . . Small , 2014 . 10 ( 22 ): 4606 DOI: 10.1002/smll.v10.22 http://doi.org/10.1002/smll.v10.22 .

L.S. Schadler, , S.C. Giannaris, , P.M. Ajayan, . . Appl. Phys. Lett. , 1998 . 73 3842 DOI: 10.1063/1.122911 http://doi.org/10.1063/1.122911 .

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