Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route

Li Yue; Li Su-qing; Zhao Jing-bo; Zhang Zhi-yuan; Zhang Jun-ying; Yang Wan-tai

doi:10.1007/s10118-016-1839-8

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Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route

PAPERS | Updated：2021-05-12

- Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route
- Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route
- Chinese Journal of Polymer Science 2016年34卷第10期页码：1220-1233
- Affiliations：
  
  Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  Jing-bo Zhao (赵京波), E-mail: zhaojb@mail.buct.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21244006 and 50873013)
- DOI：10.1007/s10118-016-1839-8
  中图分类号：
- 收稿：2016-03-18，
  
  修回：2016-6-7，
  
  录用：2016-6-9，
  
  纸质出版：2016-10-05
- Accepted：
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Li Yue, Li Su-qing, Zhao Jing-bo, 等. Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2016,34(10):1220-1233.

Li Yue, Li Su-qing, Zhao Jing-bo, et al. Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1220-1233.
Li Yue, Li Su-qing, Zhao Jing-bo, 等. Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2016,34(10):1220-1233. DOI： 10.1007/s10118-016-1839-8.

Li Yue, Li Su-qing, Zhao Jing-bo, et al. Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1220-1233. DOI： 10.1007/s10118-016-1839-8.

摘要

Abstract

A simple non-isocyanate route is developed for synthesizing crystallizable aliphatic thermoplastic poly(ester urethane) elastomers (TPEURs) with good thermal and mechanical properties. Three prepolymers of 1

6-bis(hydroxyethyloxycarbonylamino) hexane (BHCH)

i.e.

PrePBHCHs

were prepared through the self-transurethane polycondensation of BHCH. A poly(butylene adipate) prepolymer (PrePBA) with terminal HO― groups was prepared and used as a polyester glycol. A series of TPEURs were prepared by the co-polycondensation of the PrePBHCHs with PrePBA at 170 ℃ under a reduced pressure of 399 Pa. The TPEURs were characterized by gel permeation chromatography

FTIR

H-NMR

differential scanning calorimetry

thermogravimetric analysis

wide-angle X-ray diffraction

atomic force microscopy

and tensile test. The TPEURs exhibited

up to 23300 g/mol

up to 51100 g/mol

ranging from -33.8 ℃ to -3.1 ℃

from 94.3 ℃ to 111.9 ℃

initial decomposition temperature over 274.7 ℃

tensile strength up to18.8 MPa with a strain at break of 450.0%

and resilience up to 77.5%. TPU elastomers with good crystallization and mechanical properties were obtained through a non-isocyanate route.

关键词

Keywords

references

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