Tuning Thermal Gelling Behavior of <italic style="font-style: italic">N</italic>-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

Ma Hai-li; Chen Hao; Hou Sheng-zhen; Tan Ye-bang

doi:10.1007/s10118-016-1837-x

Your Location：

Home >

Browse articles >

Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

PAPERS | Updated：2021-05-12

- Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain
- Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain
- Chinese Journal of Polymer Science 2016年34卷第10期页码：1251-1260
- Affiliations：
  
  School of Chemistry and Engineering, Shandong University, Jinan 250100, China
- Author bio：
  
  Ye-bang Tan (谭业邦), E-mail: ybtan@sdu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(21374055)
- DOI：10.1007/s10118-016-1837-x
  中图分类号：
- 收稿：2016-04-11，
  
  修回：2016-5-14，
  
  录用：2016-5-19，
  
  纸质出版：2016-10-05
- Accepted：
Scan QR Code
Ma Hai-li, Chen Hao, Hou Sheng-zhen, 等. Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain[J]. Chinese Journal of Polymer Science, 2016,34(10):1251-1260. DOI: 10.1007/s10118-016-1837-x.

Ma Hai-li, Chen Hao, Hou Sheng-zhen, et al. Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1251-1260. DOI: 10.1007/s10118-016-1837-x.
Ma Hai-li, Chen Hao, Hou Sheng-zhen, 等. Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain[J]. Chinese Journal of Polymer Science, 2016,34(10):1251-1260. DOI: 10.1007/s10118-016-1837-x. DOI：

Ma Hai-li, Chen Hao, Hou Sheng-zhen, et al. Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1251-1260. DOI: 10.1007/s10118-016-1837-x. DOI：

摘要

Abstract

Thermo-gelation polymers have attracted increasing attention over decades. However

rare facile tuning method of sol-gel transition temperature restricted the wider application. Preceding study indicated that supramolecular interactions demonstrated a powerful means to control the structure and property of polymeric materials. Here we designed an

-isopropylacrylamide (NIPAM) based thermo-sensitive copolymer with naphthyl (Np) on its side chain. Positive-charged side-chain ternary complex was formed with cucurbit[8]uril (CB[8]

) and methylviologen (MV

)

via

CB[8]-enhanced intermolecular charge-transfer (CT) interaction. Introducing the ternary complex CB[8]

/MV

/Np on side-chain altered microstructure of macromolecular chains and led to a strong tendency for thermo gelation. Altering content of CB[8] and MV

changed content of the positive-charged side-chain ternary complex and varied gelation temperature. Therefore

introducing supramolecular interaction endowed the hydrogel with tunable gelation property.

关键词

Keywords

references

S. Fujishige, . . Kubota, K, Ando, I.J. Phys. Chem. , 1989 . 93 ( 8 ): 3311 .

Kubota, K., Fujishige, S. and Ando, I., Polym. J., 1990, 22(1): 15

D. Roy, . . Brooks, W.L.A, Sumerlin, B.S.Chem. Soc. Rev. , 2013 . 42 ( 17 ): 7214 .

Temtem, M., Casimiro, T., Mano, J.F. and Aguiar-Ricardo, A., Green. Chem., 2007, 9(1): 75

D.J. Overstreet, . . Dhruv, H.D, Vernon, B.L.Biomacromolecules , 2010 . 11 ( 5 ): 1154 .

Gan, T.T., Zhang, Y.J. and Guan, Y., Biomacromolecules, 2009, 10(6): 1410

A. Alexander, , Ajazuddin , J. Khan, . . Saraf, S, Saraf, S.Eur. J. Pharm. Biopharm. , 2014 . 88 575 DOI: 10.1016/j.ejpb.2014.07.005 http://doi.org/10.1016/j.ejpb.2014.07.005 .

Stile, R.A., Burghard, W.R. and Healy, K.E., Macromolecules, 1999, 32(22): 7370

L. Li, , B. Yan, , J.Q. Yang, . . Chen, L.Y, Zeng, H.B.Adv. Mater. , 2015 . 27 ( 7 ): 1294 .

Cao, Z., Chen, T.Y., Guo, X.L., Zhou, X.J., Nie, J.J., Xu, J.T., Fan, Z.Q. and Du, B.Y., Chinese J. Polym. Sci., 2011, 29(4): 439

Z.Q. Li, , F. Wang, , S. Roy, . . Sen, C.K, Guan, J.J.Biomacromolecules , 2009 . 10 ( 12 ): 3306 DOI: 10.1021/bm900900e http://doi.org/10.1021/bm900900e .

Ayano. E. and Kanazawa, H., Anal. Sci., 2014, 30(1): 167

Y Yang. , J.B. Li, . . Adv. Colloid Interface Sci. , 2014 . 207 155 DOI: 10.1016/j.cis.2013.10.029 http://doi.org/10.1016/j.cis.2013.10.029 .

C. Alexander, . . Expert Opin. Drug Deliv. , 2006 . 3 ( 5 ): 573 DOI: 10.1517/17425247.3.5.573 http://doi.org/10.1517/17425247.3.5.573 .

V. Bulmus, , Z.L. Dind, , C.J. Long, , P.S Stayton, , A.S. Hoffman, . . Bioconjugate Chem. , 2000 . 79 ( 1 ): 78 .

K. Iwai, , K Hanasaki, , M. Yamamoto, . . J. Lumin. , 2000 . 87 1289 .

Z.W. Ma, , D.M. Nelson, , Y Hong, , W.R. Wagner, . . Biomacromolecules , 2010 . 11 ( 7 ): 1873 DOI: 10.1021/bm1004299 http://doi.org/10.1021/bm1004299 .

M.C. Hacker, , L. Klouda, , B.B. Ma, , J.D Kretlow, , A.G. Mikos, . . Biomacromolecules , 2008 . 9 ( 6 ): 1558 DOI: 10.1021/bm8000414 http://doi.org/10.1021/bm8000414 .

H.J. Liu, , Y.Y Xu, , Y. Chen, . . Chinese J. Polym. Sci. , 2016 . 34 ( 5 ): 585 DOI: 10.1007/s10118-016-1779-3 http://doi.org/10.1007/s10118-016-1779-3 .

M Kang, , V.K. Gupta, . . J. Phys. Chem. B , 2002 . 106 ( 16 ): 4127 DOI: 10.1021/jp014027w http://doi.org/10.1021/jp014027w .

Q. Ma, , H. Yang, , K Kim, , Y.B. Tan, . . Chinese J. Polym. Sci. , 2012 . 30 ( 4 ): 578 DOI: 10.1007/s10118-012-1147-x http://doi.org/10.1007/s10118-012-1147-x .

Y Chen. , Y. Liu, . . Adv. Mater. , 2015 . 27 ( 36 ): 5403 DOI: 10.1002/adma.201501216 http://doi.org/10.1002/adma.201501216 .

R.J Wojtecki, , A., J. Polym. Sci. Nelson, . . Part A: Polym. Chem. , 2016 . 54 457 DOI: 10.1002/pola.27940 http://doi.org/10.1002/pola.27940 .

H. Chen, , H.L. Ma, , Y.Y. Chieng, , S.Z. Hou, , X Li, , Y.B. Tan, . . RSC Adv. , 2015 . 5 ( 27 ): 20684 DOI: 10.1039/C4RA17140C http://doi.org/10.1039/C4RA17140C .

H.J. Kim, , J. Heo, , W.S. Jeon, , E. Lee, , J. Kim, , S. Sakamoto, , K Yamaguchi, , K. Kim, . . Angew. Chem. , 2001 . 113 1574 DOI: 10.1002/(ISSN)1521-3757 http://doi.org/10.1002/(ISSN)1521-3757 .

Y.J. Jeon, , P.K. Bharadwaj, , S. Choi, , J.W Lee. , K. Kim, . . Angew. Chem. Int. Ed. , 2002 . 41 4474 DOI: 10.1002/1521-3773(20021202)41:23<4474::AID-ANIE4474>3.0.CO;2-S http://doi.org/10.1002/1521-3773(20021202)41:23<4474::AID-ANIE4474>3.0.CO;2-S .

W.S. Jeon, , E. Kim, , Y.H. Ko, , I. Hwang, , J.W. Lee, , S.Y. Kim, , H.J Kim, , K. Kim, . . Angew. Chem. Int. Ed. , 2005 . 44 87 DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

Y.H. Ko, , K. Kim, , J.K. Kang, , H. Chun, , J.W. Lee, , S. Sakamoto, , K. Yamaguchi, , J.C Fettinger. , K. Kim, . . J. Am. Chem. Soc. , 2004 . 126 ( 7 ): 1932 DOI: 10.1021/ja031567t http://doi.org/10.1021/ja031567t .

K. Kim, , D. Kim, , J.W. Lee, , Y.H Ko, , K. Kim, . . Chem. Commun. , 2004 . 848 .

W.S. Jeon, , A.Y. Ziganshina, , J.W. Lee, , Y.H. Ko, , J.K. Kang, , C Lee, , K. Kim, . . Angew. Chem. Int. Ed. , 2003 . 115 ( 34 ): .

Y.H. Ko, , E. Kim, , I Hwang, , K. Kim, . . Chem. Commun. , 2007 . 1305 .

A. Day, , A.P. Arnold, , R.J Blanch, , B. Snushall, . . J. Org. Chem. , 2001 . 66 ( 24 ): 8094 DOI: 10.1021/jo015897c http://doi.org/10.1021/jo015897c .

E.A. Appel, , F. Biedermann, , U. Rauwald, , S.T. Jones, , J.M Zayed, , O.A. Scherman, . . J. Am. Chem. Soc. , 2010 . 132 ( 40 ): 14251 DOI: 10.1021/ja106362w http://doi.org/10.1021/ja106362w .

E.A. Appel, , X.J. Loh, , S.T. Jones, , F. Biedermann, , C.A Dreiss, , O.A. Scherman, . . J. Am. Chem. Soc. , 2012 . 134 ( 28 ): 11767 DOI: 10.1021/ja3044568 http://doi.org/10.1021/ja3044568 .

L.L. Yang, , H. Yang, , F Li, , X. Zhang, . . Langmuir , 2013 . 29 ( 40 ): 12375 DOI: 10.1021/la402973g http://doi.org/10.1021/la402973g .

H.J. Kin, , J. Heo, , W.S. Jeon, , E. Lee, , J. Kim, , S. Sakamoto, , K Yamaguchi, , K. Kim, . . Angew. Chem. Int. Ed. , 2001 . 40 ( 8 ): 1526 DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

U Rauwald, , O.A. Scherman, . . Angew. Chem. Int. Ed. , 2008 . 47 ( 21 ): 3950 DOI: 10.1002/anie.v47:21 http://doi.org/10.1002/anie.v47:21 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application

Near-Infrared-Emissive Self-assembled Polymers via the Implementation of Molecular Tweezer/Guest Complexation on a Supramolecular Coordination Complex Platform

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

Topology-regulated Co-assembly of Single Chain Polymer Nanoparticles and Block Copolymers into Hierarchical Micelle@Vesicle Composite Structures

Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

DOI：10.1007/s10118-016-1837-x

摘要

Abstract

关键词

Keywords

references