Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification

Song Qing-long; Wen Hui-ying; de Claville Christiansen Jesper; Yu Dong-hong; Chen Chun-sheng; Jiang Shi-chun

doi:10.1007/s10118-016-1820-6

Your Location：

Home >

Browse articles >

Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification

PAPERS | Updated：2021-05-12

- Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification
- Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification
- Chinese Journal of Polymer Science 2016年34卷第9期页码：1172-1182
- Affiliations：
  
  a. College of Engineering and Technology, Northeast Forestry University, Harbin 150040, China
  b. Department of Mechanical and Manufacturing Engineering, Aalborg University, DK-9220, Aalborg, Denmark
  c. Department of Biotechnology, Chemistry, and Environmental Engineering, Aalborg University, DK-9220, Aalborg, Denmark
  d. School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
- Author bio：
  
  Hui-ying Wen(温慧颖),E-mail:hywen@nefu.edu.cn
  Shi-chun Jiang(蒋世春),E-mail:scjiang@tju.edu.cn
- Funds：
  
  the Project of Heilongjiang Province Education Department(No. 12523013);heFundamental Research Funds for the Central Universities(No. DL13CB01);the National Natural Science Foundation ofChina(No. 21404022)
- DOI：10.1007/s10118-016-1820-6
  中图分类号：
- 收稿：2016-03-02，
  
  修回：2016-3-31，
  
  录用：2016-3-31，
  
  纸质出版：2016-10-05
- Accepted：
Scan QR Code
Song Qing-long, Wen Hui-ying, de Claville Christiansen Jesper, 等. Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification[J]. Chinese Journal of Polymer Science, 2016,34(9):1172-1182.

Song Qing-long, Wen Hui-ying, de Claville Christiansen Jesper, et al. Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1172-1182.
Song Qing-long, Wen Hui-ying, de Claville Christiansen Jesper, 等. Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification[J]. Chinese Journal of Polymer Science, 2016,34(9):1172-1182. DOI： 10.1007/s10118-016-1820-6.

Song Qing-long, Wen Hui-ying, de Claville Christiansen Jesper, et al. Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1172-1182. DOI： 10.1007/s10118-016-1820-6.

摘要

Abstract

Poly(trimethylene terephthalate)/polycarbonate (PTT/PC) blends were prepared by solvent mixing to avoid transesterification during high temperature blending. The influences of compositions on the thermal behavior

crystallization morphology and structure of the blends were studied. FTIR results indicated that there was no COO linking to two phenyl groups on each side chain and DSC results supported no transesterification reaction. DSC curves showed that

and

increased to maximum range when PC contents were between 7 wt%-15 wt%

however

decreased constantly with the increase of PC contents. It was observed from POM that PTT spherulitic morphology and crystallization kinetics were obviously influenced by the change of PC contents. Structural evolutions during cooling were investigated by SAXS which showed

of PTT remained a constant with different PC contents and also fixed during crystallization

nevertheless

it revealed a maximum value of

for sample PTT

. It was concluded that PC chains could be permeated into not only amorphous crystallite structure but also amorphous lamellae structure and 7 wt% PC content was supposed to be the "proper" penetration amount into PTT lamellae structure which led to a maximum capacity of amorphous lamellar layer. Fringed-micelle crystal model was adopted to illustrate semi-crystalline physical structures of the blend in two kinds of component aggregation states.

关键词

Keywords

references

Newman, S. and Paul, D.R.,"Polymer blends", Academic Press, New York, 1978, Vols. I and II

C. Koning, , Duin, M..Pagnoulle, C Van , R. Jerome, . Prog. Polym. Sci. , 1998 . 23 707 DOI: 10.1016/S0079-6700(97)00054-3 http://doi.org/10.1016/S0079-6700(97)00054-3 .

I.M. Ward, , M.A Wilding, , H., Brody, . J. Polym. Sci. Polym. Phys. Ed. , 1976 . 14 263 .

R.M..[J].Ke, K.Z Ho, , M. Chen, . Macromolecules , 2000 . 33 7529 DOI: 10.1021/ma000210w http://doi.org/10.1021/ma000210w .

J. Zhang, . Appl. Polym. Sci. , 2004 . 91 1657 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

A. Yavari, , A. Asadinezhad, , S.H. Jafari, , H.A. Khonakdar, . Bohme, F, Hassler, R..[J].Eur. Polym. J. , 2005 . 41 2880 .

L.T Lee, , E.M. Woo, . Polym. Int. , 2004 . 53 1813 DOI: 10.1002/(ISSN)1097-0126 http://doi.org/10.1002/(ISSN)1097-0126 .

Y Kong, , J.N. Hay, . Polymer , 2002 . 43 1805 DOI: 10.1016/S0032-3861(01)00772-8 http://doi.org/10.1016/S0032-3861(01)00772-8 .

S.K. Na, , B.G. Kong, , C. Choi, , M.K. Jang, , J.W. Nah, , J.G Kim, , B.W. Jo, . Macromol. Res. , 2005 . 13 88 DOI: 10.1007/BF03219020 http://doi.org/10.1007/BF03219020 .

I. Aravind, , K. J. Eichhorn, , H. Komber, , D. Jehnichen, , N.E. Zafeiropoulos, , K.H. Ahn, , Y Grohens, , S. Thomas, . J. Phys. Chem. B , 2009 . 113 ( 6 ): 1569 DOI: 10.1021/jp805204m http://doi.org/10.1021/jp805204m .

D.H. Huang, , E.M Woo, , L.T. Lee, . Colloid Polym. Sci. , 2006 . 284 843 DOI: 10.1007/s00396-005-1443-x http://doi.org/10.1007/s00396-005-1443-x .

F.C Chiu, , M.H. Ting, . Polym. Test. , 2007 . 26 338 DOI: 10.1016/j.polymertesting.2006.12.001 http://doi.org/10.1016/j.polymertesting.2006.12.001 .

M.L. Xue, , Y.L. Yu, , J Sheng, , H.H. Chuah, . J. Macromol. Sci. Phys. , 2005 . 44 331 DOI: 10.1081/MB-200056631 http://doi.org/10.1081/MB-200056631 .

E.E. Shafee, , H.F. Naguib, , L. Li, , S Jiang, , L. An, . Polym. Eng. Sci. , 2010 . 50 ( 5 ): 1036 DOI: 10.1002/pen.21489 http://doi.org/10.1002/pen.21489 .

J. González, , I Eguiazábal, , J. Nazábal, . J. Appl. Polym. Sci. , 2008 . 108 3828 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

I. Aravind, , J Pionteck, , S. Thomas, . Polym. Test. , 2012 . 31 16 DOI: 10.1016/j.polymertesting.2011.09.004 http://doi.org/10.1016/j.polymertesting.2011.09.004 .

I. Aravind, , A. Boumod, , Y Grohens, , S. Thomas, . Ind. Eng. Chem. Res. , 2010 . 49 3873 DOI: 10.1021/ie901767y http://doi.org/10.1021/ie901767y .

Y. Zhang, , H.F. Li, , L.J An, , S.C. Jiang, . Acta Polymerica Sinica (in Chinese) , 2013 . ( 4 ): 462 .

D.A. Ivanov, , G. Bar, , M Dosiere, , H.J. Koch, . Macromolecules , 2008 . 41 9224 DOI: 10.1021/ma801604a http://doi.org/10.1021/ma801604a .

Y. Men, , J. Rieger, , P. Lindner, , H. Enderle, , D. Lilge, , M. Kristen, , S Mihan, , S. Jiang, . J. Phys. Chem. B. , 2005 . 109 16650 DOI: 10.1021/jp052723g http://doi.org/10.1021/jp052723g .

H. Bai, , F. Luo, , T. Zhou, , H. Deng, , K Wang, , Q. Fu, . Polymer , 2011 . 52 2351 DOI: 10.1016/j.polymer.2011.03.017 http://doi.org/10.1016/j.polymer.2011.03.017 .

Z.W. Cai, , Y. Zhang, , J.Q. Li, , F.F. Xue, , Y.R. Shang, , X.H. He, , J.C. Feng, , Z.H Wu, , S.C. Jiang, . Polymer , 2012 . 53 1593 DOI: 10.1016/j.polymer.2012.02.012 http://doi.org/10.1016/j.polymer.2012.02.012 .

G Adam, , J.H. Gibbs, . J. Chem. Phys. , 1965 . 43 139 DOI: 10.1063/1.1696442 http://doi.org/10.1063/1.1696442 .

C Schick, , E. Donth, . Physica Scripta. , 1991 . 43 423 DOI: 10.1088/0031-8949/43/4/010 http://doi.org/10.1088/0031-8949/43/4/010 .

G. R Strobl, , M., J. Polym. Sci. Schneider, . Part B: Polym. Phys. , 1980 . 18 1343 .

P.J. Flory, . J. Am. Chem. Soc. , 1936 . 58 ( 10 ): 1877 DOI: 10.1021/ja01301a016 http://doi.org/10.1021/ja01301a016 .

Z.Y. Fan, , Y.R Wang, , H.S. Bu, . Polym. Eng. Sci. , 2003 . 43 ( 3 ): 607 DOI: 10.1002/(ISSN)1548-2634 http://doi.org/10.1002/(ISSN)1548-2634 .

A Galeski, , M. Psarski, . Macrormol. Syrnp , 1996 . 104 183 .

J.D Hoffman, , R.L. Miller, . Macromolecules , 1988 . 21 ( 10 ): 3038 DOI: 10.1021/ma00188a024 http://doi.org/10.1021/ma00188a024 .

W.T. Chuang, , P.D Hong, , K.S. Shih, . Polymer , 2004 . 45 8583 DOI: 10.1016/j.polymer.2004.10.002 http://doi.org/10.1016/j.polymer.2004.10.002 .

I.J. Desborough, , I Hall, , J.Z. Neisser, . Polymer , 1979 . 20 545 DOI: 10.1016/0032-3861(79)90163-0 http://doi.org/10.1016/0032-3861(79)90163-0 .

B.J. Wang, , C.Y. Li, , J.S. Hanzlicek, , Z.D. Cheng, , P.H. Geil, , J Grebowicz, , R.M. Ho, . Polymer , 2001 . 42 ( 16 ): 7171 DOI: 10.1016/S0032-3861(01)00046-5 http://doi.org/10.1016/S0032-3861(01)00046-5 .

Hall, I.H., "Structure of crystalline polymers", Elsevier Applied Science, London, 1984, p. 39

P.J. Flory, . Proc. R. Soc. London Ser. A. , 1956 . 234 60 DOI: 10.1098/rspa.1956.0015 http://doi.org/10.1098/rspa.1956.0015 .

K.J., J. Polym. Sci. Muhlethaler, . Part C: Polym. Symp. , 1969 . 28 305 .

J. Minick, , A. Moet, , A Hiltner, , E. Baer, . J. Appl. Polym. Sci. , 1995 . 58 1371 DOI: 10.1002/app.1995.070580819 http://doi.org/10.1002/app.1995.070580819 .

W.C. Cheng, , C.Y. Yang, , B.Y. Kang, , M.Y Kuo, , J. Ruan, . Soft Matter , 2013 . 9 10822 DOI: 10.1039/c3sm51726h http://doi.org/10.1039/c3sm51726h .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Synthesis of Poly(isosorbide carbonate) via Melt Polycondensation Catalyzed by Ca/SBA-15 Solid Base

Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

Sequence-encoded Conformation Pathways in Viscoelastic Microphase Separation of Multiblock Copolymers