The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets

Yi-ren Tang; Ting Li; Hai-mu Ye; Jun Xu; Bao-hua Guo

doi:10.1007/s10118-016-1816-2

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The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets

PAPERS | Updated：2021-05-12

- The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets
- The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets
- Chinese Journal of Polymer Science 2016年34卷第8期页码：1021-1031
- Affiliations：
  
  a.Advanced Materials Laboratory of Ministry of Education, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
  b.Department of Materials Science and Engineering, China University of Petroleum, Beijing 102249, China
- Author bio：
  
  Jun Xu (徐军), E-mail: jun-xu@mail.tsinghua.edu.cn
  Bao-hua Guo (郭宝华), E-mail: bhguo@mail.tsinghua.edu.cn
- Funds：
  
  This work was financially supported by the National Basic Research Program of China(2014CB932202);the National Natural Science Foundation of China(51473085);the National Natural Science Foundation of China(21374054);the Sino-German Center for Research Promotion
- DOI：10.1007/s10118-016-1816-2
  中图分类号：
- 收稿：2016-02-14，
  
  修回：2016-3-14，
  
  录用：2016-3-14，
  
  纸质出版：2016-08
- Accepted：
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Yi-ren Tang, Ting Li, Hai-mu Ye, 等. The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets[J]. Chinese Journal of Polymer Science, 2016,34(8):1021-1031.

Yi-ren Tang, Ting Li, Hai-mu Ye, et al. The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets[J]. Chinese Journal of Polymer Science, 2016, 34(8): 1021-1031.
Yi-ren Tang, Ting Li, Hai-mu Ye, 等. The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets[J]. Chinese Journal of Polymer Science, 2016,34(8):1021-1031. DOI： 10.1007/s10118-016-1816-2.

Yi-ren Tang, Ting Li, Hai-mu Ye, et al. The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets[J]. Chinese Journal of Polymer Science, 2016, 34(8): 1021-1031. DOI： 10.1007/s10118-016-1816-2.

摘要

Abstract

Hexagonal boron nitride nanosheets (BNNSs) can work as a more efficient nucleating agent for two polyesters compared to graphene. Studies on the crystallization and dewetting processes of two polyesters

poly(butylene succinate) and poly(butylene adipate)

on the two substrate surfaces prove that the interaction between BNNSs and the polyesters is stronger than that between graphene and the polyesters. This strong interaction induces the pre-ordered conformation of molten PBA which has been identified by the

in situ

FTIR spectra. Thus BNNSs possess higher nucleation property than graphene. Finally

a new polymer-substrate interaction induced nucleation mechanism was proposed to explain the nucleation efficiency difference between graphene and BNNSs.

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references

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