Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit

Ya-juan Su; Jian-hua Huang

doi:10.1007/s10118-016-1803-7

Your Location：

Home >

Browse articles >

Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit

PAPERS | Updated：2021-05-12

- Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit
- Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit
- Chinese Journal of Polymer Science 2016年34卷第7期页码：838-849
- Affiliations：
  
  Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, China
- Author bio：
  
  Jian-hua Huang (黄建花), E-mail: jhhuang@zstu.edu.cn
- Funds：
  
  was financially supported by the National Natural Science Foundation of China(21574117)
- DOI：10.1007/s10118-016-1803-7
  中图分类号：
- 收稿：2016-01-14，
  
  修回：2016-02-14，
  
  录用：2016-02-14，
  
  纸质出版：2016-07
- Accepted：
Scan QR Code
Ya-juan Su, Jian-hua Huang. Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit[J]. Chinese Journal of Polymer Science, 2016,34(7):838-849.

Ya-juan Su, Jian-hua Huang. Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit[J]. Chinese Journal of Polymer Science, 2016, 34(7): 838-849.
Ya-juan Su, Jian-hua Huang. Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit[J]. Chinese Journal of Polymer Science, 2016,34(7):838-849. DOI： 10.1007/s10118-016-1803-7.

Ya-juan Su, Jian-hua Huang. Self-assembly Behavior of Rod-Coil-Rod Triblock Copolymers within a Planar Slit[J]. Chinese Journal of Polymer Science, 2016, 34(7): 838-849. DOI： 10.1007/s10118-016-1803-7.

摘要

Abstract

The self-assembly behavior of sphere-forming R

triblock copolymers within a planar slit is studied by performing dissipative particle dynamics simulations. A sequence of novel structures which are not observed in bulk are formed within slits

including wetting layers

island-like structure

parallel cylinders

perpendicular cylinders and cross-cylindrical structures. Perpendicular cylinders are always formed before the increase in the layers of parallel cylinders. A phase diagram of the assembled structures with respective to the slit property and height is thus presented. The rod length is found to have a significant impact on the rod alignment

and a disordered-ordered transition of rod orientation occurs with an increase in the length of rod blocks. Some special structures

such as parallel half-cylinders and arrowhead-shaped morphology

are observed when the rod length increases to a certain extent. Our results show that the property and height of the slit and rod length all influence the self-assembly of rod-coil-rod triblock copolymers.

关键词

Keywords

references

M.W. Matsen , M. Schick . Phys. Rev. Lett. , 1994 . 72 2660 .

Z. Tuzar , P. Kratochvil . "Micelles of block- and graft-copolymers in solutions" , : New York Plenum Press. , 1993 .

J.Z. Chen , C.X. Zhang , Z.Y. Sun , L.J. An . J. Chem. Phys. , 2007 . 127 024105 .

M.W. Matsen , R.B. Thompson . J. Chem. Phys. , 1999 . 111 7139 .

Q. Wang , P.F. Nealey , J.J. de Pablo . Macromolecules , 2003 . 36 1731 .

A.H. Chai , L.X. Zhang . Chinese J. Polym. Sci. , 2011 . 29 ( 6 ): 684 .

Y. Yin , P. Sun , R. Jiang , B.H. Li . J. Chem. Phys. , 2006 . 124 184708 .

J.T. Chen , E.L. Thomas , C.K. Ober , G. Mao . Science , 1996 . 273 343 .

L.Y. Shi , Y. Pan , Q.K. Zhang , Y. Zhou , X.H. Fan , Z.H. Shen . Chinese J. Polym. Sci. , 2014 . 32 ( 11 ): 1524 .

G.G. Pereira , D.R.M. Williams . Macromolecules , 2000 . 33 3166 .

G. Yang , P. Tang , Y.L. Yang , Q. Wang . J. Phys. Chem. B , 2010 . 114 14897 .

Q. Wang . Soft Matter , 2011 . 7 3711 .

L.S. Cheng , D.P. Cao . J. Chem. Phys. , 2008 . 128 074902 .

C. Nowak , T.A. Vilgis . J. Chem. Phys. , 2006 . 124 234909 .

J.H. Huang , Z.X. Ma , M.B. Luo . Langmuir , 2014 . 30 6267 .

M. Shah , V. Ganesan . Macromolecules , 2010 . 43 543 .

V. Pryamitsyn , V. Ganesan . J. Chem. Phys. , 2004 . 120 5824 .

S. Ludwigs , G. Krausch , M. Antonietti , H. Schlaad . Macromolecules , 2005 . 38 7532 .

J.W. Park , Y.H. Cho . Langmuir , 2006 . 22 10898 .

B.D. Olsen , X. Li , J. Wang , R.A. Segalman . Macromolecules , 2007 . 40 3287 .

T. Heiser , G. Adamopoulos , M. Brinkmann , G. Hadziioannou . Thin Solid Films , 2006 . 511 219 .

Y.D. Xia , J.Z. Chen , T.F. Shi , L.J. An . Chinese J. Polym. Sci. , 2013 . 31 ( 9 ): 1242 .

J.H. Kim , M.S. Rahman , J.S. Lee , J.W. Park . Macromolecules , 2008 . 41 3181 .

H. Kim , T.G. Kim , J.W. Park . Macromol. Res. , 2013 . 21 815 .

E. Ibarboure , J. Rodríguez-Hernández . Eur. Polym. J. , 2010 . 46 891 .

J. Cui , J.T. Zhu , Z.W. Ma , W. Jiang . Chem. Phys. , 2006 . 321 1 .

Z.X. Ma , J.H. Huang , M.B. Luo . Soft Matter , 2015 . 11 4932 .

P.J. Hoogerbrugge , J.M.V.A. Koelman . Europhys. Lett. , 1992 . 19 155 .

R.D. Groot , P.B. Warren . J. Chem. Phys. , 1997 . 107 4423 .

K. Kremer , G.S. Grest . J. Chem. Phys , 1990 . 92 5057 .

A. AlSunaidi , Otter W.K. den , J.H.R. Clarke . Phil. Trans. R. Soc. London. A , 2004 . 362 1773 .

P. Petrus , M. Lisal , J.K. Brennan . Langmuir , 2010 . 26 14680 .

G.J.A. Sevink , A.V. Zvelindovsky . Macromolecules , 2009 . 42 8500 .

B. Yu , B.H. Li , Q.H. Jin , D.T. Ding , A.C. Shi . Soft Matter , 2011 . 7 10227 .

A. Horvat , A. Knoll , G. Krausch , L. Tsarkova . Macromolecules , 2007 . 40 6930 .

H.P. Huinink , H.P.M.A. van Dijk , J.C.M. Brokken-Zijp , G.J.A. Sevink . Macromolecules , 2001 . 34 5325 .

Q. Wang , P.F. Nealey , J.J. de Pablo . Macromolecules , 2001 . 34 3458 .

Y.F. Tu , X.H. Wan , H.L. Zhang , X.H. Fan , D.N. Lü , X.F. Chen , Q.F. Zhou . Chinese J. Polym. Sci. , 2003 . 21 ( 5 ): 569 .

S.H. Chou , H.K. Tsao , Y.J. Sheng . J. Chem. Phys. , 2011 . 134 034904 .

M.A. Horsch , Z. Zhang , S.C. Glotzer . Nano Lett. , 2006 . 6 2406 .

M.A. Horsch , Z. Zhang , S.C. Glotzer . Soft Matter , 2010 . 6 945 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Self-assembly Behavior of Symmetrical Linear ABCA Tetrablock Copolymer: A Self-consistent Field Theory Study

SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS

Boosting Blood-Brain Barrier Crossing with a Mannosylated Nanocarrier

Antioxidant Glycopolypeptide Micelles for Targeted Delivery of Silibinin to Hepatocellular Carcinoma Cells

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion