Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers

Zhao Li; Hai-bin Sun; Cong-yi Li; Yong-lai Lu; Wang Qiao; Nan-ying Ning; Li-qun Zhang; Ming Tian

doi:10.1007/s10118-016-1801-9

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Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers

PAPERS | Updated：2021-05-12

- Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers
- Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers
- Chinese Journal of Polymer Science 2016年34卷第7期页码：858-872
- Affiliations：
  
  a.State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
  b.Aeolus Tyre Co., Ltd, Henan 454003, China
  c.Office of Scientific Research and Development, Beijing University of Chemical Technology, Beijing 100029, China
  d.PetroChina Sichuan Petrochemical Co. Ltd, Chengdu 611000, China
- Author bio：
  
  Nan-ying Ning(宁南英), E-mail: ningny@mail.buct.edu.cn
  Ming Tian (田明), E-mail: tian71402@126.com
- Funds：
  
  This work was financially supported by the National Science Fund for Distinguished Young Scholars of China(51525301);the National Natural Science Foundation of China(51373012);the National Basic Research Program of China(2015CB654704)
- DOI：10.1007/s10118-016-1801-9
  中图分类号：
- 收稿：2016-01-16，
  
  修回：2016-2-19，
  
  录用：2016-2-28，
  
  纸质出版：2016-07
- Accepted：
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Zhao Li, Hai-bin Sun, Cong-yi Li, 等. Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers[J]. Chinese Journal of Polymer Science, 2016,34(7):858-872.

Zhao Li, Hai-bin Sun, Cong-yi Li, et al. Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers[J]. Chinese Journal of Polymer Science, 2016, 34(7): 858-872.
Zhao Li, Hai-bin Sun, Cong-yi Li, 等. Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers[J]. Chinese Journal of Polymer Science, 2016,34(7):858-872. DOI： 10.1007/s10118-016-1801-9.

Zhao Li, Hai-bin Sun, Cong-yi Li, et al. Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers[J]. Chinese Journal of Polymer Science, 2016, 34(7): 858-872. DOI： 10.1007/s10118-016-1801-9.

摘要

Abstract

The dispersion and filler network of fibrillar silicate (FS) in elastomers were studied. The results showed that a good dispersion of FS in matrix during mechanical blending in unvulcanized composites contributed to a strong FS filler network

different from that of traditional reinforcing fillers. Meanwhile

the filler re-aggregation during vulcanization caused by the overlapping and intertwining of FS further strengthened the filler network. The factors including Mooney viscosity and molecular polarity of elastomer

type and amount of silane coupling agents used for filler modification

that may influence the filler network

were studied. Our study helps us to understand the mechanism for the formation of filler network of FS in elastomers and provides guidance for the preparation of high performance FS/elastomer composites.

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references

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