Fabrication of <italic style="font-style: italic">Trans</italic>-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism

Hua-feng Shao; Zhi-lu Li; Ai-hua He; Chen-guang Liu; Wei Yao

doi:10.1007/s10118-016-1797-1

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Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism

PAPERS | Updated：2021-05-12

- Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism
- Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism
- Chinese Journal of Polymer Science 2016年34卷第7期页码：797-804
- Affiliations：
  
  Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China
- Author bio：
  
  Ai-hua He (贺爱华), E-mail: aihuahe@iccas.ac.cn and ahhe@qust.edu.cn
- Funds：
  
  This work was financially supported by the National Basic Research Program of China (Nos. 2015CB654700 (2015CB654706)), the National Natural Science Foundation of China (No. 51473083), Special Foundation of Taishan Mountain Scholar Constructive Program, Shandong Provincial Key R & D program (No. 2015GGX102019), Shandong Provincial Natural Science Fund for Distinguished Young Scholars (No. JQ201213), and the Yellow River Delta Scholar program (Office of National University Science & Technology Park Administrative Committee (China University of Petroleum)
- DOI：10.1007/s10118-016-1797-1
  中图分类号：
- 收稿：2015-12-08，
  
  修回：2016-2-18，
  
  录用：2016-2-23，
  
  纸质出版：2016-07
- Accepted：
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Hua-feng Shao, Zhi-lu Li, Ai-hua He, 等. Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism[J]. Chinese Journal of Polymer Science, 2016,34(7):797-804. DOI: 10.1007/s10118-016-1797-1.

Hua-feng Shao, Zhi-lu Li, Ai-hua He, et al. Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism[J]. Chinese Journal of Polymer Science, 2016, 34(7): 797-804. DOI: 10.1007/s10118-016-1797-1.
Hua-feng Shao, Zhi-lu Li, Ai-hua He, 等. Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism[J]. Chinese Journal of Polymer Science, 2016,34(7):797-804. DOI: 10.1007/s10118-016-1797-1. DOI：

Hua-feng Shao, Zhi-lu Li, Ai-hua He, et al. Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism[J]. Chinese Journal of Polymer Science, 2016, 34(7): 797-804. DOI: 10.1007/s10118-016-1797-1. DOI：

摘要

Abstract

Tran

s-1

4-polyisoprene (TPI) nanofibers have been fabricated successfully through electrospinning technology. Through the control of electrospinning parameters

highly crystallized TPI fresh fibers composed mainly of

phase were produced. Morphology and diameter of TPI nanofibers can be controlled by adjusting the electrospinning conditions. The

in situ

observations of FTIR spectra revealed that the crystallinity of the TPI fibers decreased with aging. While for TPI nanofibers aging at 45 ℃ for 24 h

a decrease in crystallinity as well as

transformation was observed with aging and these changings happened in the first 50 h during aging. The mechanism for

-TPI formation during electrospinning process and the reduced crystallinity with aging were proposed.

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Keywords

references

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Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism

Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism

DOI：10.1007/s10118-016-1797-1

摘要

Abstract

关键词

Keywords

references