Morphologies and Mechanical Properties of <italic style="font-style: italic">Cis</italic>-1,4-butadiene Rubber/Polyethylene Blends

Hong Yao; Jia-li Niu; Jie Zhang; Nan-ying Ning; Xiao-qiu Yang; Ming Tian; Xiao-li Sun; Li-qun Zhang; Shou-ke Yan

doi:10.1007/s10118-016-1794-4

Your Location：

Home >

Browse articles >

Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends

PAPERS | Updated：2021-05-12

- Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends
- Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends
- Chinese Journal of Polymer Science 2016年34卷第7期页码：820-829
- Affiliations：
  
  a.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  b.Beijing National Laboratory for Molecular Sciences, Department of Polymer Science and Engineering & the Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  c.Basic Research Service, MOST, Beijing 100862, China
- Author bio：
  
  Ming Tian (田明), E-mail: tianm@mail.buct.edu.cn
  Shou-ke Yan (闫寿科), E-mail: skyan@mail.buct.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51221002);the National Natural Science Foundation of China(21174014)
- DOI：10.1007/s10118-016-1794-4
  中图分类号：
- 收稿：2016-01-02，
  
  修回：2016-2-16，
  
  录用：2016-2-16，
  
  纸质出版：2016-07
- Accepted：
Scan QR Code
Hong Yao, Jia-li Niu, Jie Zhang, 等. Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends[J]. Chinese Journal of Polymer Science, 2016,34(7):820-829. DOI: 10.1007/s10118-016-1794-4.

Hong Yao, Jia-li Niu, Jie Zhang, et al. Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends[J]. Chinese Journal of Polymer Science, 2016, 34(7): 820-829. DOI: 10.1007/s10118-016-1794-4.
Hong Yao, Jia-li Niu, Jie Zhang, 等. Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends[J]. Chinese Journal of Polymer Science, 2016,34(7):820-829. DOI: 10.1007/s10118-016-1794-4. DOI：

Hong Yao, Jia-li Niu, Jie Zhang, et al. Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends[J]. Chinese Journal of Polymer Science, 2016, 34(7): 820-829. DOI: 10.1007/s10118-016-1794-4. DOI：

摘要

Abstract

The mechanical properties and phase morphologies of

cis

-1

4-butadiene rubber (BR) blended with polyethylene (PE) at different blend ratios were studied. The tensile test results show that the PE exhibits excellent reinforcing capabilities towards BR. Blending BR with PE results in a remarkable enhancement of tensile strength

modulus and the elongation at break simultaneously. An increment of tensile strength from 1.11 MPa to 16.26 MPa was achieved by incorporation of 40 wt% PE in the blends. The modulus and elongation at break of 40/60 PE/BR blends are also about 5 times higher than those of the pure BR treated under exactly the same conditions. The tear test indicates that the tear strength also increases with the increase of PE content. It reaches 58.38 MPa for the 40/60 PE/BR blend

which is approximately 10 times higher than that of the pure BR. Morphological study demonstrates that the PE forms elongated microdomains finely dispersed in the BR matrix when its content is over 30 wt%

which corresponds to the remarkably enhanced mechanical properties. According to the results

reinforcement mechanism of PE toward BR dependent on the microstructure has been discussed and two different mechanisms have been proposed.

关键词

Keywords

references

P. Ghosh , B. Chattopadhyay , A.K. Sen . Polymer , 1994 . 35 ( 18 ): 3958 .

Y.J. Li , Y. Oono , Y.J. Kadowaki , T. Inoue , K. Nakayama , H. Shimizu . Macromolecules , 2006 . 39 4195 .

C.F. Antunes , A.V. Machado , M. van Duin . Eur. Polym. J. , 2011 . 47 1447 .

S. George , K. Ramamurthy , J.S. Anand , G. Groeninckx , K.T. Varughese , S. Thomas . Polymer , 1999 . 40 4325 .

J. George , K.T. Varughese , S. Thomas . Polymer , 2000 . 41 1507 .

Muraki, T. and Tajima, M., 1989, Eur. Pat., 324554 A1

Mukai, U., 2000, U.S. Pat., 6028143A

A. Buonerba , C. Cuomo , V. Speranza , A. Grassi . Macromolecules , 2010 . 43 367 .

S. Kumar , T. Rath , R.N. Mahaling , C.K. Das , R.B. Srivastava , S.B. Yadaw . Polym. Compos. , 2009 . 30 ( 5 ): 655 .

M. Maiti , R.V. Jasra , S.K. Kusum , T.K. Chaki . Ind. Eng. Chem. Res. , 2012 . 51 ( 32 ): 10607 .

Z. Zou , Z. Sun , L. An . Chinese J. Polym. Sci. , 2014 . 32 ( 3 ): 255 .

K. Guo , S. Xiang , J. Sun , C. Meng . Chinese J. Polym. Sci. , 2014 . 32 ( 3 ): 315 .

S. Kar , M.L. Greenfield . Polymer , 2015 . 62 129 .

W. Liu , X. Dong , F.S. Zou , J. Yang , D.J. Wang , C.C. Han . Polymer , 2014 . 55 2744 .

S.K. Rath , V.K. Aswal , C. Sharma , K. Joshi , M. Patri , G. Harikrishnan , D.V. Khakhar . Polymer , 2014 . 55 5198 .

Y. Zhang , J.E. Mark , Y.W. Zhu , R.S. Ruoff , D.W. Schaefer . Polymer , 2014 . 55 5389 .

H. Yao , J. Liu , L. Zhang , S. Yan . Chinese J. Polym. Sci. , 2015 . 33 ( 3 ): 386 .

A.N. Gent , L.Q. Zhang . J. Polym. Sci., Part B: Polym. Phys. , 2001 . 39 811 .

J. Liu , S. Wu , L. Zhang , W. Wang , D. Cao . Phys. Chem. Chem. Phys. , 2011 . 13 518 .

Z. Wang , J. Liu , S. Wu , W. Wang , L. Zhang . Phys. Chem. Chem. Phys. , 2010 . 12 3014 .

R. Minke , J.J. Blackwell . Macromol. Sci., Phys. , 1980 . B18 233 .

H.H. Kausch . “Polymer fracture” , : Berlin, Heidelberg, New York Springer-Verlag , 1978 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Phase Structure and Crystallization Behavior of Polyethylene in Its Blends with cis-1,4-Butadiene Rubber

Preparation and Characterization of DGEBA/EPN Epoxy Blends with Improved Fracture Toughness

Synthesis of PP-g-PIP and Properties of PP/PP-g-PIP Binary Blends

Crystallization Behavior of Disproportionately High and Low Molecular Weight PEO Blends

CRYSTALLIZATION BEHAVIOR OF POLYLACTIDE ON HIGHLY ORIENTED POLYETHYLENE THIN FILMS

Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends

Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends

DOI：10.1007/s10118-016-1794-4

摘要

Abstract

关键词

Keywords

references