Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures

Wang Jian; Zhong Li; Yuan Yan; Xiao Wang; Yun-chuan Xie; Zhi-cheng Zhang

doi:10.1007/s10118-016-1782-8

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Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures

PAPERS | Updated：2021-05-12

- Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures
- Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures
- Chinese Journal of Polymer Science 2016年34卷第5期页码：649-658
- Affiliations：
  
  a.Department of Applied Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Science, Xi'an Jiaotong University, Xi'an 710049, China
  b.College of Material Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
  c.School of Electronic and Information Engineering, Xi'an Jiaotong University, Xi'an 710049, China
- Author bio：
  
  Yun-chuan Xie (解云川), E-mail: ycxie@mail.xjtu.edu.cn
  Zhi-cheng Zhang (张志成), E-mail: zhichengzhang@mail.xjtu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51103115);the National Natural Science Foundation of China(50903065);the National Natural Science Foundation of China(51573146);Fundamental Research Funds for the Central Universities(XJJ2013075);Fundamental Research Funds for the Central Universities(cxtd2015003);International Science & Technology Cooperation Program of China(2013DFR50470);Natural Science Basic Research Plan in Shaanxi Province of China(2013JZ003);Natural Science Basic Research Plan in Shaanxi Province of China(2015JZ009);National Basic Research Program of China 973(6132620101)
- DOI：10.1007/s10118-016-1782-8
  中图分类号：
- 收稿：2015-11-27，
  
  修回：2016-1-4，
  
  录用：2016-1-4，
  
  纸质出版：2016-05
- Accepted：
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Wang Jian, Zhong Li, Yuan Yan, 等. Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures[J]. Chinese Journal of Polymer Science, 2016,34(5):649-658.

Wang Jian, Zhong Li, Yuan Yan, et al. Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures[J]. Chinese Journal of Polymer Science, 2016, 34(5): 649-658.
Wang Jian, Zhong Li, Yuan Yan, 等. Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures[J]. Chinese Journal of Polymer Science, 2016,34(5):649-658. DOI： 10.1007/s10118-016-1782-8.

Wang Jian, Zhong Li, Yuan Yan, et al. Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures[J]. Chinese Journal of Polymer Science, 2016, 34(5): 649-658. DOI： 10.1007/s10118-016-1782-8.

摘要

Abstract

After annealing the solution cast P(VDF-TrFE) films at elevated temperatures

which were synthesized

via

a full hydrogenation process from P(VDF-CTFE) with a composition of VDF/TrFE=80/20 (mol%)

a series of P(VDF-TrFE) films were fabricated in present work. The crystalline and ferroelectric phases of the films were carefully characterized and their dielectric

ferroelectric and piezoelectric properties were systematically investigated. The improved crystalline and ferroelectric phases in the films induced by annealing at elevated temperatures are responsible for the significant improved electric properties of the films. The optimized annealing temperature is found to be 130 ℃ and the best performance including the highest dielectric constant of 12.5 at 1 kHz

the largest maximum polarization of 11.21 μC/cm

and remnant polarization of 7.22 μC/cm

the lowest coercive electric field of 56 MV/m

and the highest piezoelectric coefficient of-25 pC/N is observed.

关键词

Keywords

references

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