a.Ningbo Key Laboratory of Specialty Polymers, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
b.College of Material Engineering, Ningbo University of Technology, Ningbo 315211, China
Zong-bao Wang (王宗宝), E-mail: wangzongbao@nbu.edu.cn
收稿:2015-11-14,
修回:2015-12-22,
录用:2015-12-22,
纸质出版:2016-05
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Hao-jun Xu, Min-fang An, You Lv, 等. Characterization of Structural Knot Distributions in UHMWPE Fibers[J]. Chinese Journal of Polymer Science, 2016,34(5):606-615.
Hao-jun Xu, Min-fang An, You Lv, et al. Characterization of Structural Knot Distributions in UHMWPE Fibers[J]. Chinese Journal of Polymer Science, 2016, 34(5): 606-615.
Hao-jun Xu, Min-fang An, You Lv, 等. Characterization of Structural Knot Distributions in UHMWPE Fibers[J]. Chinese Journal of Polymer Science, 2016,34(5):606-615. DOI: 10.1007/s10118-016-1774-8.
Hao-jun Xu, Min-fang An, You Lv, et al. Characterization of Structural Knot Distributions in UHMWPE Fibers[J]. Chinese Journal of Polymer Science, 2016, 34(5): 606-615. DOI: 10.1007/s10118-016-1774-8.
Microbeam wide-angle X-ray diffraction (WAXD) experiments were carried out at different structural knot positions of SIOC and M4 fibers of ultra-high molecular weight polyethylene (UHMWPE). The optical microscope images revealed that SIOC fiber had bamboo-like structural knots
and M4 fiber had chaotic distribution of structural knots. WAXD patterns showed the monoclinic unit cell in the whole M4 fiber
but different lamellar orientations in the bamboo joint of SIOC fiber. In addition
small-angle X-ray scattering (SAXS) patterns confirmed that the SIOC fiber contained uniform distribution of shish structures
and differential scanning calorimetry (DSC) measurements showed that its less branched and short chains benefited the orthorhombic-hexagonal phase transformation.
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