Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets

Wei-cai Wang; Kai Shi; Yan-xiong Pan; Chao Peng; Zi-liang Zhao; Wei Liu; Yong-gang Liu; Xiang-ling Ji

doi:10.1007/s10118-016-1769-5

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Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets

Updated：2021-06-21

- Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets
- Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets
- Chinese Journal of Polymer Science 2016年34卷第4期页码：475-482
- Affiliations：
  
  State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  **Xiang-ling Ji (姬相玲), E-mail: xlji@ciac.ac.cn
- Funds：
  
  National Natural Science Foundation of China(50633030;50921062)
- DOI：10.1007/s10118-016-1769-5
  中图分类号：
- 收稿：2015-10-25，
  
  修回：2015-11-18，
  
  录用：2015-11-18，
  
  纸质出版：2016-04
- Accepted：
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Wei-cai Wang, Kai Shi, Yan-xiong Pan, 等. Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets[J]. Chinese Journal of Polymer Science, 2016,34(4):475-482.

Wei-cai Wang, Kai Shi, Yan-xiong Pan, et al. Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets[J]. Chinese Journal of Polymer Science, 2016, 34(4): 475-482.
Wei-cai Wang, Kai Shi, Yan-xiong Pan, 等. Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets[J]. Chinese Journal of Polymer Science, 2016,34(4):475-482. DOI： 10.1007/s10118-016-1769-5.

Wei-cai Wang, Kai Shi, Yan-xiong Pan, et al. Fabrication of Polymersomes with Controllable Morphologies through Dewetting w/o/w Double Emulsion Droplets[J]. Chinese Journal of Polymer Science, 2016, 34(4): 475-482. DOI： 10.1007/s10118-016-1769-5.

摘要

Abstract

In this work

monodisperse giant polymersomes are fabricated by dewetting of water-in-oil-in-water double emulsion droplets which are assembled by amphiphilic block copolymer molecules in a microfluidic device. The dewetting process can be tuned by solvation between solvent and amphiphilic block copolymer to get polymersomes with controllable morphology. Good solvent (chloroform and toluene) hinders dewetting process of double emulsion droplets and gets acornlike polymersomes or patched polymersomes. On the other hand

poor solvent (hexane) accelerates the dewetting process and achieves complete separation of inner water phase from oil phase to form complete bilayer polymersomes. In addition

twin polymersomes with bilayer membrane structure are formed by this facile method. The formation mechanism for different polymersomes is discussed in detail.

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