Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and - Stacking Interactions

Ke-li Zhong; Zhao-nian Chen; Bao-feng Guo; Ke-di Cai; Yong-ri Liang; Jian-rong Li; Long Yi Jin

doi:10.1007/s10118-016-1755-y

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Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and - Stacking Interactions

Updated：2021-06-21

- Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and - Stacking Interactions
- Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and π-π Stacking Interactions
- Chinese Journal of Polymer Science 2016年34卷第3期页码：307-315
- Affiliations：
  
  a.College of Chemistry and Chemical Engineering, Bohai University. Food Safety Key Lab of Liaoning Province. National & Local Joint Engineering Research Center of Storage, Processing and Safety Control Technology for Fresh Agricultural and Aquatic Products, Jinzhou 121013, China
  b.Key Laboratory for Organism Resources of the Changbai Mountain and Functional Molecules, Ministry of Education of China, Department of Chemistry, College of Science, Yanbian University, Yanji 133002, China
  c.College of Materials Science & Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
- Author bio：
  
  **Jian-rong Li (励建荣), E-mail: lijr6491@163.com
  Long Yi Jin (金龙一), E-mail: lyjin@ybu.edu.cn
- Funds：
  
  National Natural Science Foundation of China(21304009;31471639;21562043;21206083;21164013);Program for Liaoning Excellent Talents in University(LJQ2014125;LR2014033);Liaoning Provincial Science & Technology Department(2015103020)
- DOI：10.1007/s10118-016-1755-y
  中图分类号：
- 收稿：2015-08-30，
  
  修回：2015-11-07，
  
  录用：2015-11-12，
  
  纸质出版：2016-03
- Accepted：
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Ke-li Zhong, Zhao-nian Chen, Bao-feng Guo, 等. Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and - Stacking Interactions[J]. Chinese Journal of Polymer Science, 2016,34(3):307-315.

Ke-li Zhong, Zhao-nian Chen, Bao-feng Guo, et al. Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and π-π Stacking Interactions[J]. Chinese Journal of Polymer Science, 2016, 34(3): 307-315. DOI: 10.1007/s10118-016-1755-y.
Ke-li Zhong, Zhao-nian Chen, Bao-feng Guo, 等. Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and - Stacking Interactions[J]. Chinese Journal of Polymer Science, 2016,34(3):307-315. DOI： 10.1007/s10118-016-1755-y.

Ke-li Zhong, Zhao-nian Chen, Bao-feng Guo, et al. Self-assembly of Amphiphilic Linear Diblock Rod-Coil Molecules by Hydrogen Bond and π-π Stacking Interactions[J]. Chinese Journal of Polymer Science, 2016, 34(3): 307-315. DOI: 10.1007/s10118-016-1755-y. DOI：

摘要

Abstract

Aromatic amphiphilic molecules (1) consisting of three biphenyl groups linked together with ether bonds as a rigid rod segment and poly(ethylene oxide) with the number of repeating units of 17 as a coil segment were synthesized

and their self-assembly behavior in the bulk state and aqueous solution was investigated. In bulk

molecules

self-assembled into 1-D lamellar structure in the solid state or smectic A phase in the liquid crystalline phase

via

the cooperative effects of

π-π

stacking

micro-phase separation and hydrogen bond interactions. In dilute aqueous solutions

molecules

were observed to self-assemble into cylindrical micelles owned uniform diameter and length of hundreds of nanometers.

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