Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization

Hao Zhang; Fang Liu; Jing Cao; Li Ling; Ran-feng Sun

doi:10.1007/s10118-016-1743-2

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Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization

Updated：2021-06-21

- Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization
- Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization
- Chinese Journal of Polymer Science 2016年34卷第2期页码：242-252
- Affiliations：
  
  a.College of Chemistry & Chemical Engineering, Inner Mongolia University, Hohhot 010021, China
  b.Inner Mongolia Key Laboratory of Fine Organic Synthesis, Inner Mongolia University, Hohhot 010021, China
- Author bio：
  
  **Hao Zhang (张浩), E-mail: haozhang@imu.edu.cn
- Funds：
  
  National Natural Science Foundation of China(21364005);Startup Foundation for Outstanding Young Scientists of Inner Mongolia University(Z20080213;115110)
- DOI：10.1007/s10118-016-1743-2
  中图分类号：
- 收稿：2015-08-18，
  
  修回：2015-09-22，
  
  录用：2015-09-22，
  
  纸质出版：2016-02
- Accepted：
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Hao Zhang, Fang Liu, Jing Cao, 等. Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization[J]. Chinese Journal of Polymer Science, 2016,34(2):242-252.

Hao Zhang, Fang Liu, Jing Cao, et al. Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization[J]. Chinese Journal of Polymer Science, 2016, 34(2): 242-252.
Hao Zhang, Fang Liu, Jing Cao, 等. Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization[J]. Chinese Journal of Polymer Science, 2016,34(2):242-252. DOI： 10.1007/s10118-016-1743-2.

Hao Zhang, Fang Liu, Jing Cao, et al. Ferrocene-containing Polymers Synthesized by Acyclic Diene Metathesis (ADMET) Polymerization[J]. Chinese Journal of Polymer Science, 2016, 34(2): 242-252. DOI： 10.1007/s10118-016-1743-2.

摘要

Abstract

Herein we reported that ferrocene-containing polymers could be synthesized

via

acyclic diene metathesis (ADMET) polymerization of ferrocene-containing bis-styryl monomers. The all-

trans

-configured vinylene bonds of stilbene segment were proven by means of

C-NMR

H-NMR

MALDI-TOF mass spectrometry and FTIR. Poly(

) showed maxima for absorption at 320 nm and emission at 430 nm which are structurally very similar to

trans

-stilbene

but 24 and 16 nm red shifted respectively. CIE chromaticity diagram shows that emission color could be adjusted by controlling the molecular weight. The polymer showed excellent solubility in common organic solvents and good thermal stability evidenced by TGA and DSC. The results of CV suggested the polymer possessed noninteracting metal centers which was confirmed by a reversible one-electron redox wave observed for the polymer.

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