Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit

Qing Zhao; Jing-yu Qian; Ying Liang; Zhi-cheng Zhong; Song Wang; Ke Liu; Wen-jing Tian; Zai-fang Li

doi:10.1007/s10118-016-1738-z

Your Location：

Home >

Browse articles >

Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit

Updated：2021-06-21

- Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit
- Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit
- Chinese Journal of Polymer Science 2016年34卷第1期页码：34-43
- Affiliations：
  
  a.College of Chemical Engineering and Food Science, Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang 441053, China
  b.State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China
- Author bio：
  
  Wen-jing Tian (田文晶), E-mail: wjtian@jlu.edu.cn
  **Zai-fang Li (李在房), E-mail: lizaifang@hust.edu.cn
- Funds：
  
  Research Program of 973 Program(2014CB643506);National Natural Science Foundation of China(21401053);Project of Scientific Research and Development of Xiangyang (Year of 2013);Open Foundation of Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices(HLOM141003);Opening Project of Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas Resource Effective Utilization(2014KLOG03)
- DOI：10.1007/s10118-016-1738-z
  中图分类号：
- 收稿：2015-06-18，
  
  修回：2015-09-17，
  
  录用：2015-09-21，
  
  纸质出版：2016-01
- Accepted：
Scan QR Code
Qing Zhao, Jing-yu Qian, Ying Liang, 等. Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit[J]. Chinese Journal of Polymer Science, 2016,34(1):34-43.

Qing Zhao, Jing-yu Qian, Ying Liang, et al. Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit[J]. Chinese Journal of Polymer Science, 2016, 34(1): 34-43.
Qing Zhao, Jing-yu Qian, Ying Liang, 等. Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit[J]. Chinese Journal of Polymer Science, 2016,34(1):34-43. DOI： 10.1007/s10118-016-1738-z.

Qing Zhao, Jing-yu Qian, Ying Liang, et al. Synthesis and Properties of Novel Polymers Based on PD Electron-withdrawing Unit[J]. Chinese Journal of Polymer Science, 2016, 34(1): 34-43. DOI： 10.1007/s10118-016-1738-z.

摘要

Abstract

In this article

we designed and synthesized a series of 5-(2

6-dimethyl-4H-pyran-4-ylidene)-1

3-diethyl-2-thioxodihydropyrimidine- 4

6(1H

5H)-dione (PD) unit based polymers (PFTDT

CZTDT

PHTDT and THTDT) for the first time. In these polymers

fluorene

7-carbazole

phenothiazine and thiophene are employed as electron-donating groups and PD as electron-withdrawing group. TGA measurements demonstrated that these polymers possess good thermal stability (all above 377 °C). Very broad absorption spectrum was also obtained from the polymer THTDT (300-850 nm). CV characterization found that these polymers owned low highest occupied molecular orbital (HOMO) energy levels (-5.39 eV for THTDT

-5.49 eV for CZTDT and -5.78 eV for PFTDT) except for PHTDT (-5.17 eV). The geometry and electronic properties of PFTDT

CZTDT

PHTDT and THTDT were investigated by means of theoretical calculation. All the above advantages demonstrate that PD based polymers could be candidates for electronic devices.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Real-Time Monitoring of Component Conversion during the Foaming and Curing Process of Self-expanding Polyurethane Grouts

Polymeric Hydrogels as Wound Dressing and Wound Healing Applications: A Review

Research on Improving the Thermal Conductivity of Epoxy Resin with Flexible Assisted Rigid Groups

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber