High Trans-1,4 (Co)Polymerization of -Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst

Bo Liu; Dong-tao Liu; Shi-hui Li; Guang-ping Sun; Dong-mei Cui

doi:10.1007/s10118-016-1729-0

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High Trans-1,4 (Co)Polymerization of -Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst

Updated：2021-06-21

- High Trans-1,4 (Co)Polymerization of -Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst
- High Trans-1,4 (Co)Polymerization of β-Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst
- Chinese Journal of Polymer Science 2016年34卷第1期页码：104-110
- Affiliations：
  
  a.Key Laboratory of Automobile Materials of Ministry of Education, Department of Materials Science and Engineering, Jilin University, Changchun 130022, China
  b.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  **Shi-hui Li (李世辉), E-mail: shihui-li@ciac.ac.cn
  Guang-ping Sun (孙广平), E-mail: sungp@jlu.edu.cn
- Funds：
  
  National Natural Science Foundation of China(51321062;21304088);Department of Science and Technology of Jilin Province for Project(20150204079GX)
- DOI：10.1007/s10118-016-1729-0
  中图分类号：
- 收稿：2015-07-15，
  
  修回：2015-08-06，
  
  录用：2015-08-08，
  
  纸质出版：2016-01
- Accepted：
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Bo Liu, Dong-tao Liu, Shi-hui Li, 等. High Trans-1,4 (Co)Polymerization of -Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst[J]. Chinese Journal of Polymer Science, 2016,34(1):104-110.

Bo Liu, Dong-tao Liu, Shi-hui Li, et al. High Trans-1,4 (Co)Polymerization of β-Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst[J]. Chinese Journal of Polymer Science, 2016, 34(1): 104-110. DOI: 10.1007/s10118-016-1729-0.
Bo Liu, Dong-tao Liu, Shi-hui Li, 等. High Trans-1,4 (Co)Polymerization of -Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst[J]. Chinese Journal of Polymer Science, 2016,34(1):104-110. DOI： 10.1007/s10118-016-1729-0.

Bo Liu, Dong-tao Liu, Shi-hui Li, et al. High Trans-1,4 (Co)Polymerization of β-Myrcene and Isoprene with an Iminophosphonamide Lanthanum Catalyst[J]. Chinese Journal of Polymer Science, 2016, 34(1): 104-110. DOI: 10.1007/s10118-016-1729-0. DOI：

摘要

Abstract

-Iminophosphonamide ligated lanthanum bis(benzyl) complex (NPN

Dipp

)La(CH

Ph-4-Me)

(THF) (NPN

Dipp

= Ph

P(NC

-2

)

upon activation of AlEt

and [Ph

C][B(C

)

]

exhibited high catalytic activity and high

trans

-1

4 stereoselectivity for the polymerization of bio-sourced b-myrcene (MY). Based on which

a series of novel

trans

-1

4 regulated elastomers could be generated by random/block copolymerization of MY and isoprene (IP).

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