Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities
PAPER|Updated:2021-06-21
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Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities
Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities
Chinese Journal of Polymer Science2015年33卷第11期 页码:1503-1515
Affiliations:
a.Department of Physics, Wenzhou University, Wenzhou 325035, China
b.Department of Physics, Wenzhou Vocational and Technical College, Wenzhou 325035, China
Author bio:
**Shi-ben Li (李士本), E-mail: shibenli@wzu.edu.cn
Xiang-hong Wang (王向红), E-mail: wxh@wzvtc.cn
Funds:
National Natural Science Foundation of China(21074096;21474076;31340026);Natural Science Foundation of Zhejiang Province(Y4090174;LY12A04004;LQ12E01003;Z13F020019)
Wen-bo Jiang, Yong-yun Ji, Wen-chang Lang, 等. Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities[J]. Chinese Journal of Polymer Science, 2015,33(11):1503-1515.
Wen-bo Jiang, Yong-yun Ji, Wen-chang Lang, et al. Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities[J]. Chinese Journal of Polymer Science, 2015, 33(11): 1503-1515.
Wen-bo Jiang, Yong-yun Ji, Wen-chang Lang, 等. Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities[J]. Chinese Journal of Polymer Science, 2015,33(11):1503-1515.DOI: 10.1007/s10118-015-1706-z.
Wen-bo Jiang, Yong-yun Ji, Wen-chang Lang, et al. Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities[J]. Chinese Journal of Polymer Science, 2015, 33(11): 1503-1515.DOI: 10.1007/s10118-015-1706-z.
Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities
The morphologies and phase diagrams exhibited by symmetric ABC star triblock copolymer nanoparticles are investigated on the basis of real-space self-consistent field theory. The ABC star triblock copolymers were chosen to be tiling-forming with fixed polymer parameter and the spherical boundaries were modeled using the masking technique. We first study a number of examples where the ABC triblock copolymers confined in spherical cavities with neutral surface. Then
two types of spherical cavity distinct preferential surfaces are considered
including both A-block attractive and repulsive preferential surfaces. We aim at the effects due to various spherical cavity diameters and the degree of interactions between the polymer and the spherical surface. A variety of morphologies
such as ring-like structures
concentric sphere
and irregular cylinder
were identified in phase diagrams. The results show that both the degree of interactions and spherical diameters can influence the formation of morphologies so that ring-like structures and other novel structures could be obtained.
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