Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP

Liang-jiu Bai; Wen-xiang Wang; Ming-hua Wang; Jin-ming Sun; Hou Chen

doi:10.1007/s10118-015-1676-1

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Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP

PAPER | Updated：2021-06-21

- Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP
- Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP
- Chinese Journal of Polymer Science 2015年33卷第9期页码：1260-1270
- Affiliations：
  
  School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
- Author bio：
  
  **Liang-jiu Bai (柏良久), E-mail: bailiangjiu@163.com
  Hou Chen (陈厚), E-mail: lduchenhou@126.com
- Funds：
  
  National Natural Science Foundation of China(21404051;21404052);Natural Science Foundation of Shandong Province(ZR2014BQ016;BS2014CL040);Talent Introduction Special Funds of Ludong University(2014012;2014017);Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province and Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application (Soochow University)
- DOI：10.1007/s10118-015-1676-1
  中图分类号：
- 收稿：2015-01-27，
  
  修回：2015-03-24，
  
  录用：2015-03-25，
  
  纸质出版：2015-09
- Accepted：
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Liang-jiu Bai, Wen-xiang Wang, Ming-hua Wang, 等. Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP[J]. Chinese Journal of Polymer Science, 2015,33(9):1260-1270.

Liang-jiu Bai, Wen-xiang Wang, Ming-hua Wang, et al. Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP[J]. Chinese Journal of Polymer Science, 2015, 33(9): 1260-1270.
Liang-jiu Bai, Wen-xiang Wang, Ming-hua Wang, 等. Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP[J]. Chinese Journal of Polymer Science, 2015,33(9):1260-1270. DOI： 10.1007/s10118-015-1676-1.

Liang-jiu Bai, Wen-xiang Wang, Ming-hua Wang, et al. Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP[J]. Chinese Journal of Polymer Science, 2015, 33(9): 1260-1270. DOI： 10.1007/s10118-015-1676-1.

摘要

Abstract

Triphenylphosphine (TPP) was used as reducing agent to continuously generate the Cu(I) activator in copper(II)- catalyzed activators generated by electron transfer atom transfer radical polymerization (AGET ATRP). For example

the polymers prepared with a molar ratio of [MMA]

/[EBiB]

/[CuCl

]

/[PMDETA]

/[TPP]

= 500/1/0.1/0.5/0.5 had controlled molecular weights and low molecular weight distribution (

) values (~1.2). TPP as a commercial reducing agent provides a convenient copper-catalyzed AGET ATRP procedure for the preparation of well-defined polymers.

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