Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route

Yong Deng; Su-qing Li; Jing-bo Zhao; Zhi-yuan Zhang; Jun-ying Zhang; Wan-tai Yang

doi:10.1007/s10118-015-1638-7

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Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route

PAPER | Updated：2021-06-21

- Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route
- Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route
- Chinese Journal of Polymer Science 2015年33卷第6期页码：880-889
- Affiliations：
  
  Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  **Jing-bo Zhao (赵京波), E-mail: zhaojb@mail.buct.edu.cn
- Funds：
  
  National Natural Science Foundation of China(21244006;50873013)
- DOI：10.1007/s10118-015-1638-7
  中图分类号：
- 收稿：2014-10-09，
  
  修回：2014-12-29，
  
  录用：2014-12-30，
  
  纸质出版：2015-06
- Accepted：
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Yong Deng, Su-qing Li, Jing-bo Zhao, 等. Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2015,33(6):880-889.

Yong Deng, Su-qing Li, Jing-bo Zhao, et al. Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2015, 33(6): 880-889.
Yong Deng, Su-qing Li, Jing-bo Zhao, 等. Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2015,33(6):880-889. DOI： 10.1007/s10118-015-1638-7.

Yong Deng, Su-qing Li, Jing-bo Zhao, et al. Aliphatic Thermoplastic Poly(ether urethane)s Having Long PEG Sequences Synthesized through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, 2015, 33(6): 880-889. DOI： 10.1007/s10118-015-1638-7.

摘要

Abstract

A non-isocyanate route for synthesizing thermoplastic polyurethanes with excellent thermal and mechanical properties was described. Melt transurethane polycondensation of 1

6-bis(hydroxyethyloxy carbonyl amino)hexane with four poly(ethylene glycol)s (PEGs)

i.e.

PEG400

PEG600

PEG1000

or PEG1500

was conducted at different molar ratios. A series of thermoplastic poly(ether urethane)s (TPEUs) with long PEG sequences were prepared. The TPEUs were characterized

via

gel permeation chromatography

FTIR

H-NMR

differential scanning calorimetry

thermogravimetric analysis

wide-angle X-ray scattering

and tensile tests. The TPEUs exhibit

between 12.4 °C and −40.4 °C

of up to 149.8 °C

and initial decomposition temperature over 239.4 °C. The tensile strength of the TPEUs reaches 38.39 MPa with a strain at break of 852.92%.

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